SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2013, Vol. 21 ›› Issue (11): 1284-1290.DOI: 10.1016/S1004-9541(13)60622-9

• 化工热力学 • 上一篇    下一篇

Densities and Viscosities of 1-butyl-3-methylimidazolium Hexafluorophosphate [bmim][PF6]+CO2 Binary System:Determination and Correlation

乔燕1,2, 闫方友2, 夏淑倩2, 马沛生2   

  1. 1 Mineral Resources Comprehensive Utilization Institute, School of Mining, Taiyuan University of Technology, Taiyuan 030024, China;
    2 Key Laboratory for Green Chemical Technology of the State Education Ministry, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
  • 收稿日期:2012-06-13 修回日期:2013-01-10 出版日期:2013-11-28 发布日期:2013-11-26
  • 通讯作者: QIAO Yan
  • 基金资助:

    Supported by the Programme of Introducing Talents of Disciplineto Universities (B060006), the National Natural Science Foundation of China (20706040), and the Special/Youth Foundation of Taiyuan University of Technology (2012L025).

Densities and Viscosities of 1-butyl-3-methylimidazolium Hexafluorophosphate [bmim][PF6]+CO2 Binary System:Determination and Correlation

QIAO Yan1,2, YAN Fangyou2, XIA Shuqian2, MA Peisheng2   

  1. 1 Mineral Resources Comprehensive Utilization Institute, School of Mining, Taiyuan University of Technology, Taiyuan 030024, China;
    2 Key Laboratory for Green Chemical Technology of the State Education Ministry, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
  • Received:2012-06-13 Revised:2013-01-10 Online:2013-11-28 Published:2013-11-26
  • Contact: QIAO Yan
  • Supported by:

    Supported by the Programme of Introducing Talents of Disciplineto Universities (B060006), the National Natural Science Foundation of China (20706040), and the Special/Youth Foundation of Taiyuan University of Technology (2012L025).

摘要: A gas-dissolving device was designed and connected to the falling-body viscometer, which was used to determine the viscosities of liquids in our lab before. The equipment can be used to determine the gas composition, the densities and viscosities of the solution at the same time. The densities and viscosities of [bmim][PF6] + CO2 binary system were determined in the temperature range of 313.2 to 413.2 K and pressure range of 5.0 to 25.0 MPa by the equipment. Then the viscosities of [bmim][PF6] + CO2 binary system at constant temperature, constant pressure, and different temperature and pressure were correlated, respectively. For the correlation at different temperature and different pressure for different concentration mixtures the average relative deviation ARD is 0.037.

关键词: viscosity, falling-body viscometer, [bmim][PF6], ionic liquid, carbon dioxide

Abstract: A gas-dissolving device was designed and connected to the falling-body viscometer, which was used to determine the viscosities of liquids in our lab before. The equipment can be used to determine the gas composition, the densities and viscosities of the solution at the same time. The densities and viscosities of [bmim][PF6] + CO2 binary system were determined in the temperature range of 313.2 to 413.2 K and pressure range of 5.0 to 25.0 MPa by the equipment. Then the viscosities of [bmim][PF6] + CO2 binary system at constant temperature, constant pressure, and different temperature and pressure were correlated, respectively. For the correlation at different temperature and different pressure for different concentration mixtures the average relative deviation ARD is 0.037.

Key words: viscosity, falling-body viscometer, [bmim][PF6], ionic liquid, carbon dioxide