Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T

doi:10.1016/S1004-9541(14)60016-1

Chinese Journal of Chemical Engineering ›› 2014, Vol. 22 ›› Issue (1): 89-97.DOI: 10.1016/S1004-9541(14)60016-1

Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T

李杰^1,2,3, 林晓^1,2, 宁朋歌^1,2, 曹宏斌^1,2, 张懿^1,2, John C. Crittenden⁴

1 Research Center for Process Pollution Control, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2 Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
3 Graduate University of Chinese Academy of Sciences, Beijing 100049, China;
4 Brook Byers Institute for Sustainable Systems, Georgia Institute of Technology, Atlanta, GA 30332, USA

收稿日期:2012-10-26 修回日期:2013-01-15 出版日期:2014-01-05 发布日期:2014-01-04
通讯作者: NING Pengge
基金资助:
Supported by the National Natural Science Foundation of China (51178446, 21206168).

Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T

LI Jie^1,2,3, LIN Xiao^1,2, NING Pengge^1,2, CAO Hongbin^1,2, ZHANG Yi^1,2, John C. Crittenden⁴

1 Research Center for Process Pollution Control, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2 Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
3 Graduate University of Chinese Academy of Sciences, Beijing 100049, China;
4 Brook Byers Institute for Sustainable Systems, Georgia Institute of Technology, Atlanta, GA 30332, USA

Received:2012-10-26 Revised:2013-01-15 Online:2014-01-05 Published:2014-01-04
Contact: NING Pengge
Supported by:
Supported by the National Natural Science Foundation of China (51178446, 21206168).

摘要/Abstract

摘要： The primary aliphatic amine Primene JM-T was investigated as a potential absorbent for H₂S removal. The solubility of H₂S in JM-T was measured at 298, 313, 333, 353, and 368 K with H₂S partial pressures from 20 to 760 kPa and H₂S loading from 0.02 to 0.8 mol H₂S per mol JM-T. Relevant physical properties, such as density, viscosity and dielectric constant, of the material were measured. The thermodynamic model with two-suffix Margules equation was used to correlate the experimental vapor-liquid equilibrium data. Furthermore, the absorption mechanism in non-aqueous system is suggested and the difference between non-aqueous and aqueous absorption system is pointed out.

关键词: Primene JM-T, H₂S removal, absorption, thermodynamic model

Abstract: The primary aliphatic amine Primene JM-T was investigated as a potential absorbent for H₂S removal. The solubility of H₂S in JM-T was measured at 298, 313, 333, 353, and 368 K with H₂S partial pressures from 20 to 760 kPa and H₂S loading from 0.02 to 0.8 mol H₂S per mol JM-T. Relevant physical properties, such as density, viscosity and dielectric constant, of the material were measured. The thermodynamic model with two-suffix Margules equation was used to correlate the experimental vapor-liquid equilibrium data. Furthermore, the absorption mechanism in non-aqueous system is suggested and the difference between non-aqueous and aqueous absorption system is pointed out.

Key words: Primene JM-T, H₂S removal, absorption, thermodynamic model

李杰, 林晓, 宁朋歌, 曹宏斌, 张懿, John C. Crittenden. Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T[J]. Chinese Journal of Chemical Engineering, 2014, 22(1): 89-97.

LI Jie, LIN Xiao, NING Pengge, CAO Hongbin, ZHANG Yi, John C. Crittenden. Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T[J]. Chin.J.Chem.Eng., 2014, 22(1): 89-97.

参考文献

1 Ahmed, M.S., Attia, Y.A., "Multi-metal oxide aerogel for capture of pollution gases from air", Appl. Therm. Eng., 18, 787-797 (1998).

2 Lu, J.G., Zheng, Y.F., He, D.L., "Selective absorption of H₂S from gas mixtures into aqueous solutions of blended amines of methyldiethanolamine and 2-tertiarybutylamino-2-ethoxyethanol in a packed column", Sep. Purif. Technol., 52 (2), 209-217 (2006).

3 Lu, Y.X., Schaefer, L., "A solid oxide fuel cell system fed with hydrogen sulfide and natural gas ", J. Power Sources, 135, 184-191 (2004).

4 Lee, J.I., Otto, F.D., Mather, A.E., "Measurement and prediction of solubility of mixtures of carbon dioxide and hydrogen sulfide in a 2.5 N monoethanolamine solution ", Can. J. Chem. Eng., 54 (3), 214-219 (1976).

5 Lee, J., Otto, F.D., Mather, A.E., "Solubility of hydrogen sulfide in aqueous diethanolamine solutions at high pressures", J. Chem. Eng. Data, 18 (1), 71-73 (1973).

6 Vallee, G., Mougin, P., Jullian, S., Furst, W., "Representation of CO₂ and H₂S absorption by aqueous solutions of diethanolamine using an electrolyte equation of state", Ind. Eng. Chem. Res., 38 (9), 3473-3480 (1999).

7 Xia, J.Z., Kamps, A.P.S., Maurer, G., "Solubility of H₂S in (H₂O plus piperazine) and in (H₂O plus MDEA plus piperazine)", Fluid Phase Equilibr., 207, 23-34 (2003).

8 Speyer, D., Maurer, G., "Solubility of hydrogen sulfide in aqueous solutions of piperazine in the low gas-loading region", J. Chem. Eng. Data, 56 (4), 763-767 (2011).

9 Li, Y.G., Mather, A.E., "Correlation and prediction of the solubility of CO₂ and H₂S in aqueous solutions of triethanolamine", Ind. Eng. Chem. Res., 35 (12), 4804-4809 (1996).

10 Jou, F.Y., Carroll, J.J., Mather, A.E., Otto, F.D., "Solubility of mixtures of hydrogen sulfide and carbon dioxide in aqueous N-methyldiethanolamine solutions", J. Chem. Eng. Data, 38 (1), 75-77 (1993).

11 Savage, D.W., Funk, E.W., Yu, W.C., Astarita, G., "Selective absorption of H₂S and CO₂ into aqueous solutions of methyldiethanolamine", Ind. Eng. Chem. Fundam., 25 (3), 326-330 (1986).

12 Li, Y.G., Mather, A.E., "Correlation and prediction of the solubility of CO₂ and H₂S in aqueous solutions of methyldiethanolamine", Ind. Eng. Chem. Res., 36 (7), 2760-2765 (1997).

13 Mandal, B., Bandyopadhyay, S.S., "Simultaneous absorption of CO₂ and H₂S into aqueous blends of N-methyldiethanolamine and diethanolamine", Environ. Sci. Technol., 40 (19), 6076-6084 (2006).

14 Li, M.H., Shen, K.P., "Solubility of hydrogen sulfide in aqueous mixtures of monoethanolamine with N-methyldiethanolamine", J. Chem. Eng. Data, 38 (1), 105-108 (1993).

15 Sidi-Boumedine, R., Horstmann, S., Fischer, K., Provost, E., Furst, W., Gmehling, J., "Experimental determination of hydrogen sulfide solubility data in aqueous alkanolamine solutions", Fluid Phase Equilibr., 218 (1), 149-155 (2004).

16 Duan, Z.H., Sun, R., Liu, R., Zhu, C., "Accurate thermodynamic model for the calculation of H₂S solubility in pure water and brines", Energ. Fuel, 21 (4), 2056-2065 (2007).

17 Xia, J.Z., Kamps, A.P.S., Rumpf, B., Maurer, G., "Solubility of hydrogen sulfide in aqueous solutions of the single salts sodium sulfate, ammonium sulfate, sodium chloride, and ammonium chloride at temperatures from 313 to 393 K and total pressures up to 10 MPa ", Ind. Eng. Chem. Res., 39 (4), 1064-1073 (2000).

18 Aaron, D., Tsouris, C., "Separation of CO₂ from flue gas: A review", Separ. Sci. Technol., 40, 321-348 (2005).

19 Goodrich, B.F., de la Fuente, J.C., Gurkan, B.E., Zadigian, D.J., Price, E.A., Huang, Y., Brennecke, J.F., "Experimental measurements of amine-functionalized anion-tethered ionic liquids with carbon dioxide ", Ind. Eng. Chem. Res., 50 (1), 111-118 (2011).

20 Bates, E.D., Mayton, R.D., Ntai, I., Davis, J.H., "CO₂ capture by a task-specific ionic liquid", J. Am. Chem. Soc., 124 (6), 926-927 (2002).

21 Rohm and Haas Co., Primene 81R and Primene JMT t-Alkyl Primary Amines, Philadelphia (1992).

22 Kent, R.L., Eisenberg, B., "Better data for amine treating", Hydrocarb. Process., 55 (2), 87-90 (1976).

23 Austgen, D.M., Rochelle, G.T., Peng, X., Chen, C.C., "Model of vapor liquid equilibria for aqueous acid gas alkanolamine systems using the electrolyte NRTL equation ", Ind. Eng. Chem. Res., 28 (7), 1060-1073 (1989).

24 Li, Y.G., Mather, A.E., "Correlation and prediction of the solubility of carbon dioxide in a mixed alkanolamine solution", Ind. Eng. Chem. Res., 33 (8), 2006-2015 (1994).

25 Kuranov, G., Rumpf, B., Smirnova, N.A., Maurer, G., "Solubility of single gases carbon dioxide and hydrogen sulfide in aqueous solutions of N-methyldiethanolamine in the temperature range 313-413 K at pressures up to 5 MPa", Ind. Eng. Chem. Res., 35 (6), 1959-1966 (1996).

26 Clegg, S.L., Pitzer, K.S., "Thermodynamics of multicomponent, miscible, ionic-solutions generalized equations for symmetrical electrolytes", J. Phys. Chem., 96 (8), 3513-3520 (1992).

27 Li, C.X., Furst, W., "Representation of CO₂ and H₂S solubility in aqueous MDEA solutions using an electrolyte equation of state", Chem. Eng. Sci., 55 (15), 2975-2988 (2000).

28 Peng, D., Robinson, D.B., "A new two-constant equation of state", Ind. Eng. Chem. Fundam., 15 (1), 59-64 (1976).

29 Maddox, R.N., Bhairi, A.H., Diers, J.R., Thomas, P.A., "Equilibrium solubility of carbon dioxide or hydrogen sulfide in aqueous solutions of monoethanolamine, diglycolamine, diethanolamine and methyldiethanolamine", Research Report RR-104, Gas Processors Association (1987).

30 Jou, F.Y., Mather, A.E., Otto, F.D., "Solubility of H₂S and CO₂ in aqueous methyldiethanolamine solutions", Ind. Eng. Chem. Proc. Des. Dev., 21 (4), 539-544 (1982).

31 Strus, B., Sobczynska, A., Wisniewski, M., "Solubility of water and association phenomena in gasoline modified with hydrophilic additives and selected surfactants", Fuel, 87 (6), 957-963 (2008).

32 Prausnitz, J.M., Lichtenthaler, R.N., de Azevedo, E.G., Molecular Thermodynamics of Fluid-Phase Equilibria, 3rd ed., Prentice-Hall PTR (1999).

33 Li, Y.G., Thermodynamics of Metal Solvent Extraction, Tsinghua Univ. Press, Beijing (1988). (in Chinese)

34 Pitzer, K.S., Activity Coefficient in Electrolyte Solutions, 2nd edition, CRC Press, Boca Raton, FL (1991).

[1]	Yutong Jiang, Yifeng Chen, Fuliu Yang, Jixue Fan, Jun Li, Zhuhong Yang, Xiaoyan Ji. Efficient SO₂ removal using aqueous ionic liquid at low partial pressure[J]. 中国化学工程学报, 2023, 58(6): 355-363.
[2]	Feng Pan, Sugang Ma, Yu Ge, Chuanlin Fan, Qingshan Zhu. Fluidization thermal decomposition of sodium fluosilicate[J]. 中国化学工程学报, 2023, 57(5): 329-337.
[3]	Chao Yang, Zhelin Su, Yeshuang Wang, Huiling Fan, Meisheng Liang, Zhaohui Chen. Insight into the effect of gel drying temperature on the structure and desulfurization performance of ZnO/SiO₂ adsorbents[J]. 中国化学工程学报, 2023, 56(4): 233-241.
[4]	Wen Tian, Junyi Ji, Hongjiao Li, Changjun Liu, Lei Song, Kui Ma, Siyang Tang, Shan Zhong, Hairong Yue, Bin Liang. Measurements of the effective mass transfer areas for the gas–liquid rotating packed bed[J]. 中国化学工程学报, 2023, 55(3): 13-19.
[5]	Yuandong Cui, Bin He, Yu Lei, Yu Liang, Wanting Zhao, Jian Sun, Xiaomin Liu. Lignin derived absorbent for efficient and sustainable CO₂ capture[J]. 中国化学工程学报, 2023, 54(2): 89-97.
[6]	Yilin Song, Yize Zhang, Hao Zhou. Experimental study on the desulfurization and evaporation characteristics of Ca(OH)₂ droplets[J]. 中国化学工程学报, 2023, 54(2): 127-135.
[7]	Xiaodong Yang, Na Yang, Ziqiang Gong, Feifei Peng, Bin Jiang, Yongli Sun, Luhong Zhang. The superhydrophobic sponge decorated with Ni-Co double layered oxides with thiol modification for continuous oil/water separation[J]. 中国化学工程学报, 2023, 54(2): 296-305.
[8]	Jing Gao, Zhijun Ma, Fuli Liu, Cunxin Chen. Synthesis of carbon-coated cobalt ferrite core–shell structure composite: A method for enhancing electromagnetic wave absorption properties by adjusting impedance matching[J]. 中国化学工程学报, 2022, 47(7): 206-217.
[9]	Yaran Yin, Xianming Zhang, Chunying Zhu, Taotao Fu, Youguang Ma. Formation characteristics of Taylor bubbles in a T-junction microchannel with chemical absorption[J]. 中国化学工程学报, 2022, 46(6): 214-222.
[10]	Liwang Wang, Hualin Wang, Liang Ma, Zhanghuang Yang, Erwen Chen. Gas cyclone-liquid jet absorption separator used for treatment of tail gas containing HCl in titanium dioxide industry[J]. 中国化学工程学报, 2022, 44(4): 435-446.
[11]	Xiaomeng Zhao, Xingyu Li, Changjun Liu, Shan Zhong, Houfang Lu, Hairong Yue, Kui Ma, Lei Song, Siyang Tang, Bin Liang. The quasi-activity coefficients of non-electrolytes in aqueous solution with organic ions and its application on the phase splitting behaviors prediction for CO₂ absorption[J]. 中国化学工程学报, 2022, 43(3): 316-323.
[12]	Yan Zhang, Jiaguang Zheng, Zhiyu Lu, Mengchen Song, Jiahuan He, Fuying Wu, Liuting Zhang. Boosting the hydrogen storage performance of magnesium hydride with metal organic framework-derived Cobalt@Nickel oxide bimetallic catalyst[J]. 中国化学工程学报, 2022, 52(12): 161-171.
[13]	Longyun Zheng, Kai Guo, Hongwei Cai, Bo Zhang, Hui Liu, Chunjiang Liu. Investigation of mass transfer model of CO₂ absorption with Rayleigh convection using multi-relaxation time lattice Boltzmann method[J]. 中国化学工程学报, 2022, 50(10): 130-142.
[14]	Jingpeng Chen, Ge Song, Zhuo Liu, Lijing Xie, Shoushun Zhang, Chengmeng Chen. Design of core-shell nickel oxide/silicon carbide whiskers towards excellent microwave absorption property[J]. 中国化学工程学报, 2021, 37(9): 208-216.
[15]	Hanxiao Du, Lixin Xie, Jie Liu, Shichang Xu. Concentration of mixed acid by electrodialysis for the intensification of absorption process in acrylic acid production[J]. 中国化学工程学报, 2021, 36(8): 10-18.

Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T

Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价