Determination and Correlation of Solubility for D-Xylose in Volatile Fatty Acid Solvents

doi:10.1016/S1004-9541(14)60061-6

Chinese Journal of Chemical Engineering ›› 2014, Vol. 22 ›› Issue (4): 429-434.DOI: 10.1016/S1004-9541(14)60061-6

• 催化、动力学与反应工程 • 上一篇下一篇

Determination and Correlation of Solubility for D-Xylose in Volatile Fatty Acid Solvents

李涛, 陈飞雄, 江振西, 任保增

School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, China

收稿日期:2012-07-20 修回日期:2013-01-30 出版日期:2014-04-28 发布日期:2014-04-04
通讯作者: REN Baozeng
基金资助:
Supported by Science and Technology Breakthrough Major Project in Henan Province (112101210200).

Determination and Correlation of Solubility for D-Xylose in Volatile Fatty Acid Solvents

LI Tao, CHEN Feixiong, JIANG Zhenxi, REN Baozeng

School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, China

Received:2012-07-20 Revised:2013-01-30 Online:2014-04-28 Published:2014-04-04
Supported by:
Supported by Science and Technology Breakthrough Major Project in Henan Province (112101210200).

摘要/Abstract

摘要： The solubility of D-xylose in formic acid and binary solvents of formic acid with formic acid and acetic acid, propionic acid, n-butyric acid or isobutyric acid was measured in the temperature range from 300.35 to 325.05 K using the synthetic method by a laser monitoring technique at atmospheric pressure. The solid-liquid equilibrium data will provide essential support for industrial design and further theoretical study. The experimental data show that the solubility of D-xylose in formic acid and in the mixtures of formic acid + acetic acid (1:1), formic acid + propionic acid (1:1), formic acid + n-butyric acid (1:1), and formic acid + isobutyric acid (1:1) increases with temperature. The Apelblat equation, the λh model, and the ideal solution equation correlate the solubility data well.

关键词: solid-liquid equilibrium, solubility, D-xylose

Abstract: The solubility of D-xylose in formic acid and binary solvents of formic acid with formic acid and acetic acid, propionic acid, n-butyric acid or isobutyric acid was measured in the temperature range from 300.35 to 325.05 K using the synthetic method by a laser monitoring technique at atmospheric pressure. The solid-liquid equilibrium data will provide essential support for industrial design and further theoretical study. The experimental data show that the solubility of D-xylose in formic acid and in the mixtures of formic acid + acetic acid (1:1), formic acid + propionic acid (1:1), formic acid + n-butyric acid (1:1), and formic acid + isobutyric acid (1:1) increases with temperature. The Apelblat equation, the λh model, and the ideal solution equation correlate the solubility data well.

Key words: solid-liquid equilibrium, solubility, D-xylose

李涛, 陈飞雄, 江振西, 任保增. Determination and Correlation of Solubility for D-Xylose in Volatile Fatty Acid Solvents[J]. Chinese Journal of Chemical Engineering, 2014, 22(4): 429-434.

LI Tao, CHEN Feixiong, JIANG Zhenxi, REN Baozeng. Determination and Correlation of Solubility for D-Xylose in Volatile Fatty Acid Solvents[J]. Chin.J.Chem.Eng., 2014, 22(4): 429-434.

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Determination and Correlation of Solubility for D-Xylose in Volatile Fatty Acid Solvents

Determination and Correlation of Solubility for D-Xylose in Volatile Fatty Acid Solvents

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