Effects of Colloidal Silica Binder on Catalytic Activity and Adhesion of HZSM-5 Coatings for Structured Reactors

doi:10.1016/j.cjche.2014.06.010

Chinese Journal of Chemical Engineering ›› 2014, Vol. 22 ›› Issue (8): 875-881.DOI: 10.1016/j.cjche.2014.06.010

• 第四届整体式结构化催剂与反应器国际会议专栏 • 上一篇下一篇

Effects of Colloidal Silica Binder on Catalytic Activity and Adhesion of HZSM-5 Coatings for Structured Reactors

Guozhu Liu¹, Jinhua Guo¹, Fanxu Meng², Xiangwen Zhang¹, Li Wang¹

1. Key Laboratory of Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;
2. Department of Chemical Engineering, Texas A&M University, College Station, TX 77843, USA

收稿日期:2013-12-24 修回日期:2014-01-06 出版日期:2014-08-28 发布日期:2014-11-04
通讯作者: Li Wang
基金资助:
Supported by the National Natural Science Foundation of China (91116001).

Effects of Colloidal Silica Binder on Catalytic Activity and Adhesion of HZSM-5 Coatings for Structured Reactors

Guozhu Liu¹, Jinhua Guo¹, Fanxu Meng², Xiangwen Zhang¹, Li Wang¹

1. Key Laboratory of Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;
2. Department of Chemical Engineering, Texas A&M University, College Station, TX 77843, USA

Received:2013-12-24 Revised:2014-01-06 Online:2014-08-28 Published:2014-11-04
Supported by:
Supported by the National Natural Science Foundation of China (91116001).

摘要/Abstract

摘要： HZSM-5 coating using three colloidal silica binders, acidic colloidal silica (ACS), neutral colloidal silica (NCS) and basic colloidal silica (BCS), was prepared to study the effect of binders on their adhesion and catalytic activity. Scanning electron microscopy characterization indicated that the zeolite coating using BCS shows the smoothest surface with higher homogeneity and adherence strength. The specific surface area, relative crystallization and acid site strength of zeolites are also dependent on the binder used. Catalytic cracking of supercritical n-dodecane over the series of zeolite coating with various binders indicated that HZSM-5 coating with BCS exhibits the highest and the most stable catalytic activity compared with other kinds of binders, and also exhibits a stable catalytic activity ascribed to its proper acid property and microstructure.

关键词: HZSM-5 coating, Colloidal silica binder, Catalytic activity, Structured reactor

Abstract: HZSM-5 coating using three colloidal silica binders, acidic colloidal silica (ACS), neutral colloidal silica (NCS) and basic colloidal silica (BCS), was prepared to study the effect of binders on their adhesion and catalytic activity. Scanning electron microscopy characterization indicated that the zeolite coating using BCS shows the smoothest surface with higher homogeneity and adherence strength. The specific surface area, relative crystallization and acid site strength of zeolites are also dependent on the binder used. Catalytic cracking of supercritical n-dodecane over the series of zeolite coating with various binders indicated that HZSM-5 coating with BCS exhibits the highest and the most stable catalytic activity compared with other kinds of binders, and also exhibits a stable catalytic activity ascribed to its proper acid property and microstructure.

Key words: HZSM-5 coating, Colloidal silica binder, Catalytic activity, Structured reactor

Guozhu Liu, Jinhua Guo, Fanxu Meng, Xiangwen Zhang, Li Wang. Effects of Colloidal Silica Binder on Catalytic Activity and Adhesion of HZSM-5 Coatings for Structured Reactors[J]. Chinese Journal of Chemical Engineering, 2014, 22(8): 875-881.

参考文献

[1] T. Edwards, Cracking and deposition behavior of supercritical hydrocarbon aviationfuels, Combust. Sci. Technol. 178 (2006) 307-334.

[2] D.R. Sobel, L.J. Spadaccini, Hydrocarbon fuel cooling technologies for advancedpropulsion, J. Eng. Gas Turbines Power 119 (1997) 344-351.

[3] H. Huang, L.J. Spadaccini, D.R. Sobel, Fuel-cooled thermal management for advancedaero-engines, J. Eng. Gas Turbines Power 126 (2004) 284-293.

[4] F.X. Meng, G.Z. Liu, L. Wang, S.D. Qu, X.W. Zhang, Z.T. Mi, Effect of HZSM-5 coatingthickness upon catalytic cracking of n-dodecane under supercritical condition,Energy Fuels 24 (2010) 2848-2856.

[5] F.X. Meng, G.Z. Liu, S.D. Qu, L. Wang, X.W. Zhang, Z.T. Mi, Catalytic cracking andcoking of supercritical n-dodecane in microchannel coated with HZSM-5 zeolites,Ind. Eng. Chem. Res. 49 (2010) 8977-8983.

[6] S.D. Qu, G.Z. Liu, F.X. Meng, L. Wang, X.W. Zhang, Catalytic cracking of supercriticaln-dodecane over wall-coated HZSM-5 with different Si/Al ratios, Energy Fuels 25(2011) 2808-2814.

[7] B.Mitra, D. Kunzru, Washcoating of different zeolites on cordierite monoliths, J. Am.Ceram. Soc. 91 (2008) 64-70.

[8] J.M. Zamaro, M.A. Ulla, E.E. Miro, Zeolite washcoating onto cordierite honeycombreactors for environmental applications, Chem. Eng. J. 106 (2005) 25-33.

[9] J.M. Zamaro, M.A. Ulla, E.E. Miro, The effect of different slurry compositions andsolvents upon the properties of ZSM5-washcoated cordierite honeycombs for theSCR of NO_x with methane, Catal. Today 107-108 (2005) 86-93.

[10] B.T. Holland, V. Subramani, S.K. Gangwal, Utilizing colloidal silica and aluminumdopedcolloidal silica as a binder in FCC catalysts: effects on porosity, acidity, andmicroactivity, Ind. Eng. Chem. Res. 46 (2007) 4486-4496.

[11] H. Sun, B. Shen, J. Liu, N-paraffins adsorption with 5A zeolites: the effect of binder onadsorption equilibria, Sep. Purif. Technol. 64 (2008) 135-139.

[12] R.V. Jasra, B. Tyagi, Y.M. Badheka, V.N. Choudary, T.S.G. Bhat, Effect of clay binder onsorption and catalytic properties of zeolite pellets, Ind. Eng. Chem. Res. 42 (2003)3263-3272.

[13] T.A. Peters, J. van der Tuin, C. Houssin,M.A.G. Vorstman, N.E. Benes, Z.A.E. Vroon, P.A.Holmen, J.T.F. Keurentjes, Preparation of zeolite-coated pervaporation membranesfor the integration of reaction and separation, Catal. Today 104 (2005)288-295.

[14] A.V. Boix, J.M. Zamaro, E.A. Lombardo, E.E. Miro, The beneficial effect of silica on theactivity and thermal stability of PtCoFerrierite-washcoated cordierite monoliths forthe SCR of NO_x with CH₄, Appl. Catal. B Environ. 46 (2003) 121-132.

[15] Z.Q. You, G.Z. Liu, L. Wang, X.W. Zhang, Binderless nano-HZSM-5 zeolite coatingsprepared through combining washcoating and dry-gel conversion (DGC) methods,Microporous Mesoporous Mater. 170 (2013) 235-242.

[16] G.Z. Liu, G.L. Zhao, F.X. Meng, S.D. Qu, L. Wang, X.W. Zhang, Catalytic cracking ofsupercritical n-dodecane over wall-coated HZSM-5 zeolites with micro- and nanocrystalsizes, Energy Fuels 26 (2012) 1220-1229.

[17] J. Zhu, Y.Q. Fan, N.P. Xu, Preparation and characterization of alumina membranes oncapillary supports: effect of film-coating on crack-free membrane preparation, Chin.J. Chem. Eng. 18 (2010) 377-383.

Effects of Colloidal Silica Binder on Catalytic Activity and Adhesion of HZSM-5 Coatings for Structured Reactors

Effects of Colloidal Silica Binder on Catalytic Activity and Adhesion of HZSM-5 Coatings for Structured Reactors

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 9

编辑推荐

Metrics

本文评价

[1]	Fei Li, Xuemei Wang, Pengze Zhang, Qinqin Wang, Mingyuan Zhu, Bin Dai. Nitrogen and phosphorus co-doped activated carbon induces high density Cu⁺ active center for acetylene hydrochlorination[J]. 中国化学工程学报, 2023, 59(7): 193-199.
[2]	Yincong Liu, Lingjun Zhu, Xiaoliu Wang, Shi Yin, Furong Leng, Fan Zhang, Haizhou Lin, Shurong Wang. Catalytic methanation of syngas over Ni-based catalysts with different supports[J]. , 2017, 25(5): 602-608.
[3]	袁海宽, 刘旭汝, 任杰, 慎炼. Surface Acidity of Aluminum Phosphate and Its Catalytic Performance in Benzene Alkylation with Long Chain Olefin[J]. Chinese Journal of Chemical Engineering, 2013, 21(6): 627-632.
[4]	江红果, 杨祖金, 周贤太, 方岩雄, 纪红兵. Immobilization of β-Cyclodextrin as Insoluble β-Cyclodextrin Polymer and Its Catalytic Performance[J]. Chinese Journal of Chemical Engineering, 2012, 20(4): 784-792.
[5]	程媛, 谢伟淼, 姚国新, 胡素绢, 李国华. Electrocatalytic Activity of Tungsten Carbide and Natural Zeolite Composite in Aqueous Solution[J]. Chinese Journal of Chemical Engineering, 2012, 20(2): 254-261.
[6]	童少平, 张铁明, 马淳安. Oxygen Evolution Behavior of PTFE-F-PbO₂ Electrode in H₂SO₄ Solution[J]. , 2008, 16(6): 885-889.
[7]	周亚松. TiO₂及TiO₂-SiO₂复合氧化物特性及其降解水中有机污染物的光催化活性[J]. , 2003, 11(6): 665-670.
[8]	李小年, 刘化章, 岑亚青, 胡樟能. 维氏体铁基氨合成催化剂动力学分析[J]. , 2003, 11(1): 19-26.
[9]	张继炎, 徐力生, 李玉敏, 张鎏. A SHORT-CUT OF EXPLORING THE OPTIMUM ACTIVITY FOR COMMERCIAL METHANATION CATALYST Ni/Al_2O_3 [J]. , 1992, 7(1): 93-102.