Anodic Alumina Supported Pt Catalyst for Total Oxidation of Trace Toluene

doi:10.1016/j.cjche.2014.06.011

Chinese Journal of Chemical Engineering ›› 2014, Vol. 22 ›› Issue (8): 882-887.DOI: 10.1016/j.cjche.2014.06.011

• 第四届整体式结构化催剂与反应器国际会议专栏 • 上一篇下一篇

Anodic Alumina Supported Pt Catalyst for Total Oxidation of Trace Toluene

Zebao Rui, Chunyan Chen, Yubing Lu, Hongbing Ji

Department of Chemical Engineering, School of Chemistry & Chemical Engineering, and The Key Lab of Low-carbon Chemistry & Energy Conservation of Guangdong Province, Sun Yat-sen University, Guangzhou 510275, China

收稿日期:2013-12-25 修回日期:2014-01-13 出版日期:2014-08-28 发布日期:2014-11-04
通讯作者: Hongbing Ji
基金资助:
Supported by the National Natural Science Foundation of China (21106189, 21036009), the Natural Science Foundation (S2011040001767) and the Foundation from the Educational Commission (LYM11004) of Guangdong Province.

Anodic Alumina Supported Pt Catalyst for Total Oxidation of Trace Toluene

Zebao Rui, Chunyan Chen, Yubing Lu, Hongbing Ji

Department of Chemical Engineering, School of Chemistry & Chemical Engineering, and The Key Lab of Low-carbon Chemistry & Energy Conservation of Guangdong Province, Sun Yat-sen University, Guangzhou 510275, China

Received:2013-12-25 Revised:2014-01-13 Online:2014-08-28 Published:2014-11-04
Supported by:
Supported by the National Natural Science Foundation of China (21106189, 21036009), the Natural Science Foundation (S2011040001767) and the Foundation from the Educational Commission (LYM11004) of Guangdong Province.

摘要/Abstract

摘要： Featuring an assembly of identical pores, through-pore anodic alumina (AAO) makes an ideal monolith-like catalyst support for volatile organic compound (VOC) combustion. This work employs the oxidation of toluene as a model reaction to investigate the applicability of AAOsupported Pt catalysts in VOC catalytic combustion. In order tomodify themicrostructure of AAO, some AAO sampleswere exposed to hotwater treatment (HWT) firstly. Results show that the optimum HWT time is 18 h. Pt/HWT18 gives a toluene conversion of 95% at 200℃, which is comparable to the initial activity of commercial γ-Al₂O₃ particle supported Pt catalyst. Considering its confinement effect for the supportedmetal and its monolith-like compact unit, AAO support offers potential applications in VOC catalytic combustion.

关键词: Anodic alumina, Pt, Electrochemical anodization, Catalytic combustion, Toluene

Abstract: Featuring an assembly of identical pores, through-pore anodic alumina (AAO) makes an ideal monolith-like catalyst support for volatile organic compound (VOC) combustion. This work employs the oxidation of toluene as a model reaction to investigate the applicability of AAOsupported Pt catalysts in VOC catalytic combustion. In order tomodify themicrostructure of AAO, some AAO sampleswere exposed to hotwater treatment (HWT) firstly. Results show that the optimum HWT time is 18 h. Pt/HWT18 gives a toluene conversion of 95% at 200℃, which is comparable to the initial activity of commercial γ-Al₂O₃ particle supported Pt catalyst. Considering its confinement effect for the supportedmetal and its monolith-like compact unit, AAO support offers potential applications in VOC catalytic combustion.

Key words: Anodic alumina, Pt, Electrochemical anodization, Catalytic combustion, Toluene

Zebao Rui, Chunyan Chen, Yubing Lu, Hongbing Ji. Anodic Alumina Supported Pt Catalyst for Total Oxidation of Trace Toluene[J]. Chinese Journal of Chemical Engineering, 2014, 22(8): 882-887.

Zebao Rui, Chunyan Chen, Yubing Lu, Hongbing Ji. Anodic Alumina Supported Pt Catalyst for Total Oxidation of Trace Toluene[J]. Chin.J.Chem.Eng., 2014, 22(8): 882-887.

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Anodic Alumina Supported Pt Catalyst for Total Oxidation of Trace Toluene

Anodic Alumina Supported Pt Catalyst for Total Oxidation of Trace Toluene

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