Determination and Correlation of Solubility of Nonivamide in Different Solvents

doi:10.1016/j.cjche.2013.05.001

›› 2014, Vol. 22 ›› Issue (10): 1141-1144.DOI: 10.1016/j.cjche.2013.05.001

Determination and Correlation of Solubility of Nonivamide in Different Solvents

Yifeng Cao, Qiwei Yang, Huabin Xing, Zongbi Bao, Baogen Su, Yiwen Yang, Qilong Ren

Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China

收稿日期:2012-12-20 修回日期:2013-05-06 出版日期:2014-10-28 发布日期:2014-12-01
通讯作者: Huabin Xing

Determination and Correlation of Solubility of Nonivamide in Different Solvents

Yifeng Cao, Qiwei Yang, Huabin Xing, Zongbi Bao, Baogen Su, Yiwen Yang, Qilong Ren

Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China

Received:2012-12-20 Revised:2013-05-06 Online:2014-10-28 Published:2014-12-01

摘要/Abstract

摘要： The solubility of nonivamide in dimethyl sulfoxide,methanol, acetone, ethyl acetate,methyl tert-butyl ether, acetonitrile, n-hexane and water over the temperature range of 293.2 K to 323.2 K wasmeasured. The results reveal that the solubility of nonivamide is greatly influenced by the hydrogen-bond basicity of solvent and increases with temperature. The experimental data were correlated with the modified Apelblat equation. The dissolution enthalpy and entropy of nonivamide in different solvents were obtained from the correlation of lnx with 1/T using the van't Hoff equation. The calculated nonivamide solubility is in good agreement with experimental data for most of the solvents.

关键词: Solubility, Nonivamide, Hydrogen-bonding interaction, Modified Apelblat equation, van't Hoff plotting

Abstract: The solubility of nonivamide in dimethyl sulfoxide,methanol, acetone, ethyl acetate,methyl tert-butyl ether, acetonitrile, n-hexane and water over the temperature range of 293.2 K to 323.2 K wasmeasured. The results reveal that the solubility of nonivamide is greatly influenced by the hydrogen-bond basicity of solvent and increases with temperature. The experimental data were correlated with the modified Apelblat equation. The dissolution enthalpy and entropy of nonivamide in different solvents were obtained from the correlation of lnx with 1/T using the van't Hoff equation. The calculated nonivamide solubility is in good agreement with experimental data for most of the solvents.

Key words: Solubility, Nonivamide, Hydrogen-bonding interaction, Modified Apelblat equation, van't Hoff plotting

Yifeng Cao, Qiwei Yang, Huabin Xing, Zongbi Bao, Baogen Su, Yiwen Yang, Qilong Ren. Determination and Correlation of Solubility of Nonivamide in Different Solvents[J]. , 2014, 22(10): 1141-1144.

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Determination and Correlation of Solubility of Nonivamide in Different Solvents

Determination and Correlation of Solubility of Nonivamide in Different Solvents

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