Fabrication of superhydrophilic surface on copper substrate by electrochemical deposition and sintering process

doi:10.1016/j.cjche.2014.11.034

Chinese Journal of Chemical Engineering ›› 2015, Vol. 23 ›› Issue (7): 1200-1205.DOI: 10.1016/j.cjche.2014.11.034

• 能源、资源与环境技术 • 上一篇下一篇

Fabrication of superhydrophilic surface on copper substrate by electrochemical deposition and sintering process

Qiaopeng Liu, Yong Tang, Wenjie Luo, Ting Fu, Wei Yuan

College of Mechanical and Automotive Engineering, South China University of Technology, Guangzhou 510640, China

收稿日期:2014-04-29 修回日期:2014-11-23 出版日期:2015-07-28 发布日期:2015-08-21
通讯作者: Qiaopeng Liu, Yong Tang
基金资助:
Supported by the National Natural Science Foundation of China (51275180), the Fundamental Research Funds for the Central Universities (2013ZM0003) and the Doctorate Dissertation Funds of Guangdong Province (sybzzxm 201213).

Fabrication of superhydrophilic surface on copper substrate by electrochemical deposition and sintering process

Qiaopeng Liu, Yong Tang, Wenjie Luo, Ting Fu, Wei Yuan

College of Mechanical and Automotive Engineering, South China University of Technology, Guangzhou 510640, China

Received:2014-04-29 Revised:2014-11-23 Online:2015-07-28 Published:2015-08-21
Contact: Qiaopeng Liu, Yong Tang
Supported by:
Supported by the National Natural Science Foundation of China (51275180), the Fundamental Research Funds for the Central Universities (2013ZM0003) and the Doctorate Dissertation Funds of Guangdong Province (sybzzxm 201213).

摘要/Abstract

摘要： Superhydrophilic surfaces were fabricated on copper substrates by an electrochemical deposition and sintering process. Superhydrophobic surfaces were prepared by constructing micro/nano-structure on copper substrates through an electrochemical deposition method. Conversion fromsuperhydrophobic to superhydrophilic was obtained via a suitable sintering process. After reduction sintering, the contact angle of the superhydrophilic surfaces changed from 155° to 0°. The scanning electron microscope (SEM) images show that the morphology of superhydrophobic and superhydrophilic surfaces looks like corals and cells respectively. The chemical composition and crystal structure of these surfaceswere examined using energy dispersive spectrometry (EDS) and X-ray diffraction (XRD). The results show that the main components on superhydrophobic surfaces are Cu, Cu₂O and CuO, while the superhydrophilic surfaces are composed of Cu merely. The crystal structure is more inerratic and the grain size becomes bigger after the sintering. The interfacial strength of the superhydrophilic surfaces was investigated, showing that the interfacial strength between superhydrophilic layer and copper substrate is considerably high.

关键词: Superhydrophilic, Superhydrophobic, Copper surface, Electrochemical deposition, Sintering process

Abstract: Superhydrophilic surfaces were fabricated on copper substrates by an electrochemical deposition and sintering process. Superhydrophobic surfaces were prepared by constructing micro/nano-structure on copper substrates through an electrochemical deposition method. Conversion fromsuperhydrophobic to superhydrophilic was obtained via a suitable sintering process. After reduction sintering, the contact angle of the superhydrophilic surfaces changed from 155° to 0°. The scanning electron microscope (SEM) images show that the morphology of superhydrophobic and superhydrophilic surfaces looks like corals and cells respectively. The chemical composition and crystal structure of these surfaceswere examined using energy dispersive spectrometry (EDS) and X-ray diffraction (XRD). The results show that the main components on superhydrophobic surfaces are Cu, Cu₂O and CuO, while the superhydrophilic surfaces are composed of Cu merely. The crystal structure is more inerratic and the grain size becomes bigger after the sintering. The interfacial strength of the superhydrophilic surfaces was investigated, showing that the interfacial strength between superhydrophilic layer and copper substrate is considerably high.

Key words: Superhydrophilic, Superhydrophobic, Copper surface, Electrochemical deposition, Sintering process

Qiaopeng Liu, Yong Tang, Wenjie Luo, Ting Fu, Wei Yuan. Fabrication of superhydrophilic surface on copper substrate by electrochemical deposition and sintering process[J]. Chinese Journal of Chemical Engineering, 2015, 23(7): 1200-1205.

参考文献

[1] W. Barthlott, C. Neinhuis, Purity of the sacred lotus, or escape fromcontamination in biological surfaces, Planta 202 (1997) 1-8.

[2] R. Wang, K. Hashimoto, A. Fujishima, M. Chikuni, E. Kojima, A. Kitamura, M. Shimohigoshi, T. Watanabe, Light-induced amphiphilic surfaces, Nature 388 (1997) 431-432.

[3] D.F. Zhu, X. Li, G. Zhang, X. Zhang, X.M. Zhang, T.Q. Wang, B. Yang, Mimicking the rice leaf — from ordered binary structures to anisotropic wettability, Langmuir 26 (2010) 14276-14283.

[4] L.B. Feng, H.X. Zhang, Z.L. Wang, Y.H. Liu, Superhydrophobic aluminum alloy surface: fabrication, structure, and corrosion resistance, Colloids Surf. A 441 (2014) 319-325.

[5] J. Cui, W.Z. Li, W.H. Lam, Numerical investigation on drag reduction with superhydrophobic surfaces by lattice-Boltzmann method, Comput. Math. Appl. 61 (2011) 3678-3689.

[6] C. Neinhuis, W. Barthlott, Characterization and distribution of water-repellent, selfcleaning plant surfaces, Ann. Bot. 79 (1997) 667-677.

[7] C.L. Jiang,W. Li, A facilemethod for preparations of micro-nanotextured Co₃O₄ films with the excellent superhydrophobic and anti-icing behavior, Mater. Lett. 122 (2014) 133-138.

[8] R.A.Munoz, D. Beving, S. Yu, Hydrophilic zeolite coatings for improved heat transfer, Ind. Eng. Chem. Res. 44 (2005) 4310-4315.

[9] Y. Takata, S. Hidaka,M.Masuda, T. Ito, Pool boiling on a superhydrophilic surface, Int. J. Energy Res. 27 (2003) 111-119.

[10] A. Abdal-hay, H.R. Pant, J.K. Lim, Super-hydrophilic electrospun nylon-6/hydroxyapatite membrane for bone tissue engineering, Eur. Polym. J. 49 (2013) 1314-1321.

[11] K.S. Guan, Relationship between photocatalytic activity, hydrophilicity and selfcleaning effect of TiO₂/SiO₂ films, Surf. Coat. Technol. 191 (2005) 155-160.

[12] Esfandiar Pakdel, W.A. Daoud, X.G. Wang, Self-cleaning and superhydrophilic wool by TiO₂/SiO₂ nanocomposite, Appl. Surf. Sci. 275 (2013) 397-402.

[13] C. Byon, Y.S. Nam, S.J. Kim, Y.S. Ju, Drag reduction in Stokes flows over spheres with nanostructured superhydrophilic surfaces, J. Appl. Phys. 107 (2010) 066102-066105.

[14] R.D. Sun, A. Nakajima, A. Fujishima, T. Watanabe, K. Hashimoto, Photoinduced surface wettability conversion of ZnO and TiO₂ thin films, J. Phys. Chem. B 105 (2001) 1984-1990.

[15] S. Chutima, Y.Wittaya, I. Varol, Environmental remediation and superhydrophilicity of ultrafine antibacterial tungsten oxide-based nanofibers under visible light source, Appl. Surf. Sci. 259 (2012) 349-355.

[16] Y.H. Liu, B. Wang, E. Li, X.M. Song, H. Yan, X.X. Zhang, The preparation of a strawberry-like super-hydrophilic surface on the molybdenum substrate, Colloids Surf. A 404 (2012) 52-55.

[17] T. Behners, L. Pragerb, S. Kriehnb, J.S. Gutmanna, Super-hydrophilic surfaces by photo-induced micro-folding, Appl. Surf. Sci. 259 (2012) 847-852.

[18] M. Houmard, G. Berthomé, J.C. Joud, M. Langlet, Enhanced cleanability of superhydrophilic TiO₂-SiO₂ composite surfaces prepared via a sol-gel route, Surf. Sci. 605 (2011) 456-462.

[19] Y.M. Jeong, J.K. Lee, H.W. Jun, G.R. Kim, Y.S. Choe, Preparation of super-hydrophilic amorphous titanium dioxide thin film via PECVD process and its application to dehumidifying heat exchangers, J. Ind. Eng. Chem. 15 (2009) 202-206.

[20] F.C. Cebeci, Z.Z. Wu, L. Zhai, R.E. Cohen, M.F. Rubner, Nanoporosity-driven superhydrophilicity: A means to create multifunctional antifogging coatings, Langmuir 22 (2006) 2856-2862.

[21] J.F. Zang, C.M. Li, S.J. Bao, X.Q. Cui, Q.L. Bao, C.Q. Sun, Template-free electrochemical synthesis of superhydrophilic polypyrrole nanofiber network, Macromolecules 41 (2008) 7053-7057.

[22] Z.J. Gong, J.L. Wang, L.M. Wu, X.Y. Wang, G.C. LV, L.B. Liao, Fabrication of super hydrophobic surfaces on copper by solution-immersion, Chin. J. Chem. Eng. 21 (2013) 920-926.

[23] W.J. Xi, Z.M. Qiao, C.L. Zhu, A. Jia, M. Li, The preparation of lotus-like superhydrophobic copper surfaces by electroplating, Appl. Surf. Sci. 255 (2009) 4836-4839.

[24] N.A. Patankar, Mimicking the lotus effect: Influence of double roughness structures and slender pillars, Langmuir 20 (2004) 8209-8213.

[25] S. Herminghaus, Roughness-induced non-wetting, Europhys. Lett. 52 (2000) 165-170.

[26] A.B.D. Cassie, S. Baxter,Wettability of porous surfaces, Trans. Faraday Soc. 40 (1944) 546-551.

[27] R. David, A.W. Neumann, Energy barriers between the Cassie and Wenzel states on random, superhydrophobic surfaces, Colloids Surf. A 425 (2013) 51-58.

[28] N.A. Patankar, On the modeling of hydrophobic contact angles on rough surfaces, Langmuir 19 (2003) 1249-1253.

[29] R.N. Wenzel, Communication to the editor surface roughness and contact angle, J. Phys. Chem. 53 (1949) 1466-1467.

Fabrication of superhydrophilic surface on copper substrate by electrochemical deposition and sintering process

Fabrication of superhydrophilic surface on copper substrate by electrochemical deposition and sintering process

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 14

编辑推荐

Metrics

本文评价

[1]	Taoyan Mao, Runhui Xiao, Peng Liu, Jiale Chen, Junqiang Luo, Su Luo, Fengwei Xie, Cheng Zheng. Facile fabrication of durable superhydrophobic fabrics by silicon polyurethane membrane for oil/water separation[J]. 中国化学工程学报, 2023, 55(3): 73-83.
[2]	Zida Ma, Yuxia Li, Mengmeng Jin, Xiaoqin Liu, Linbing Sun. Fabrication of adsorbents with enhanced Cu^I stability: Creating a superhydrophobic microenvironment through grafting octadecylamine[J]. 中国化学工程学报, 2023, 55(3): 41-48.
[3]	Xiaodong Yang, Na Yang, Ziqiang Gong, Feifei Peng, Bin Jiang, Yongli Sun, Luhong Zhang. The superhydrophobic sponge decorated with Ni-Co double layered oxides with thiol modification for continuous oil/water separation[J]. 中国化学工程学报, 2023, 54(2): 296-305.
[4]	Fei Tong, Jie Gong, Liang Yu, Ming Li, Lixiong Zhang. Transparent and anti-fogging AlPO₄-5 films constructed by oblique oriented nano-flake crystals[J]. 中国化学工程学报, 2022, 44(4): 332-340.
[5]	Jie Wang, Ling Zhang, Chunzhong Li. Superhydrophobic and mechanically robust polysiloxane composite coatings containing modified silica nanoparticles and PS-grafted halloysite nanotubes[J]. 中国化学工程学报, 2022, 52(12): 56-65.
[6]	Bao Wang, Chaolang Chen, Zhaoxin Li, Jianfeng Wu, Xianglou Liu, Jiadao Wang. One-step fabrication superhydrophobic sand filter for capillary-driven separation of water-in-oil emulsions[J]. 中国化学工程学报, 2021, 33(5): 70-75.
[7]	Ruilong Zhang, Zhiping Zhou, Wenna Ge, Yi Lu, Tianshu Liu, Wenming Yang, Jiangdong Dai. Robust, fluorine-free and superhydrophobic composite melamine sponge modified with dual silanized SiO₂ microspheres for oil-water separation[J]. 中国化学工程学报, 2021, 33(5): 50-60.
[8]	Dexin Chen, Zhixin Kang, Wei Li, Fenghua Su. Simultaneously spray-assisted assembling reversible superwetting coatings for oil-water separation[J]. 中国化学工程学报, 2021, 32(4): 144-150.
[9]	Zhenqiang Zhang, Danfeng Yu, Xiubin Xu, Huayi Li, Taoyan Mao, Cheng Zheng, Jianjia Huang, Hui Yang, Zihan Niu, Xu Wu. A polypropylene melt-blown strategy for the facile and efficient membrane separation of oil-water mixtures[J]. 中国化学工程学报, 2021, 29(1): 383-390.
[10]	Tao Zhang, Zhangdi Li, Yuanfei Lü, Yu Liu, Dongya Yang, Qiurong Li, Fengxian Qiu. Recent progress and future prospects of oil-absorbing materials[J]. 中国化学工程学报, 2019, 27(6): 1282-1295.
[11]	Yanhui Yang, Qianqian Liu, Haizhi Wang, Fusheng Ding, Guoshan Jin, Chunxi Li, Hong Meng. Superhydrophobic modification of ceramic membranes for vacuum membrane distillation[J]. , 2017, 25(10): 1395-1401.
[12]	Yanhui Yang, Qianqian Liu, Haizhi Wang, Fusheng Ding, Guoshan Jin, Chunxi Li, Hong Meng. Superhydrophobic modification of ceramic membranes for vacuum membrane distillation[J]. , 2017, 25(10): 1395-1401.
[13]	Zhijia Yu, Xinghua Liu, Guozhu Kuang. Water slip flow in superhydrophobic microtubes within laminar flow region[J]. Chinese Journal of Chemical Engineering, 2015, 23(5): 763-768.
[14]	王宏智, 姚素薇, 张卫国. 电沉积Ni-W梯度镀层及其结构表征[J]. , 2003, 11(3): 348-351.