Transparent and anti-fogging AlPO4-5 films constructed by oblique oriented nano-flake crystals

doi:10.1016/j.cjche.2021.02.004

中国化学工程学报 ›› 2022, Vol. 44 ›› Issue (4): 332-340.DOI: 10.1016/j.cjche.2021.02.004

Transparent and anti-fogging AlPO₄-5 films constructed by oblique oriented nano-flake crystals

Fei Tong^1,2, Jie Gong¹, Liang Yu³, Ming Li², Lixiong Zhang²

1 School of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, China;
2 State Key Laboratory of Materials-Oriented Chemical Engineering and College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China;
3 Chemical Technology, Luleå University of Technology, SE-971 87 Luleå, Sweden

收稿日期:2021-01-06 修回日期:2021-02-10 出版日期:2022-04-28 发布日期:2022-06-18
通讯作者: Lixiong Zhang,E-mail:lixzhang@njtech.edu.cn
基金资助:
We are grateful for financial support from the Key University Science Research Project of Jiangsu Province (16KJA430007), Opening Topic of Key Laboratory of Attapulgite Resources Utilization in Jiangsu Province (HPK201804), Opening Topic of National Local Joint Engineering Research Center for Deep Utilization of Mineral and Salt Resources (SF201804).

Transparent and anti-fogging AlPO₄-5 films constructed by oblique oriented nano-flake crystals

Fei Tong^1,2, Jie Gong¹, Liang Yu³, Ming Li², Lixiong Zhang²

1 School of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, China;
2 State Key Laboratory of Materials-Oriented Chemical Engineering and College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China;
3 Chemical Technology, Luleå University of Technology, SE-971 87 Luleå, Sweden

Received:2021-01-06 Revised:2021-02-10 Online:2022-04-28 Published:2022-06-18
Contact: Lixiong Zhang,E-mail:lixzhang@njtech.edu.cn
Supported by:
We are grateful for financial support from the Key University Science Research Project of Jiangsu Province (16KJA430007), Opening Topic of Key Laboratory of Attapulgite Resources Utilization in Jiangsu Province (HPK201804), Opening Topic of National Local Joint Engineering Research Center for Deep Utilization of Mineral and Salt Resources (SF201804).

摘要/Abstract

摘要： In the present work, transparent and anti-fogging AlPO₄-5 films were prepared on glass substrates using a novel developed process. The process entails a simple in-situ sol–gel followed by vapor phase transport. The in-situ sol–gel process was implemented by coating the precursor sols for the synthesis of AlPO₄-5 on the glass substrates successively using the spin-coating method. The films and powders scribed from the films were characterized by X-Ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), atomic force microscope (AFM), X-ray photoelectron spectroscopy and transmission electron microscope (TEM). The unique films were composed of oblique oriented nano-flake AlPO₄-5 crystals with the thickness of about 20 nm. The formation of nano-flake crystals can be ascribed to the high concentration of the precursors, resulting in the formation of a supersaturation system. The obtained films showed high antifogging performance due to the superhydrophilicity with a water contact angle of lower than 1.0°. The silicone oil contact angle was also low about 8.2°. In addition, heteroatom-substituted AlPO₄-5 films showing different colors can be obtained easily by simply adding transition metal ions in the phosphate acid solution during the preparation that can extend the application of the method for different coating demand.

关键词: AlPO₄-5 thin film, Oriented film, Transparent, Superhydrophilicity, Anti-fogging

Abstract: In the present work, transparent and anti-fogging AlPO₄-5 films were prepared on glass substrates using a novel developed process. The process entails a simple in-situ sol–gel followed by vapor phase transport. The in-situ sol–gel process was implemented by coating the precursor sols for the synthesis of AlPO₄-5 on the glass substrates successively using the spin-coating method. The films and powders scribed from the films were characterized by X-Ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), atomic force microscope (AFM), X-ray photoelectron spectroscopy and transmission electron microscope (TEM). The unique films were composed of oblique oriented nano-flake AlPO₄-5 crystals with the thickness of about 20 nm. The formation of nano-flake crystals can be ascribed to the high concentration of the precursors, resulting in the formation of a supersaturation system. The obtained films showed high antifogging performance due to the superhydrophilicity with a water contact angle of lower than 1.0°. The silicone oil contact angle was also low about 8.2°. In addition, heteroatom-substituted AlPO₄-5 films showing different colors can be obtained easily by simply adding transition metal ions in the phosphate acid solution during the preparation that can extend the application of the method for different coating demand.

Key words: AlPO₄-5 thin film, Oriented film, Transparent, Superhydrophilicity, Anti-fogging

Fei Tong, Jie Gong, Liang Yu, Ming Li, Lixiong Zhang. Transparent and anti-fogging AlPO₄-5 films constructed by oblique oriented nano-flake crystals[J]. 中国化学工程学报, 2022, 44(4): 332-340.

Fei Tong, Jie Gong, Liang Yu, Ming Li, Lixiong Zhang. Transparent and anti-fogging AlPO₄-5 films constructed by oblique oriented nano-flake crystals[J]. Chinese Journal of Chemical Engineering, 2022, 44(4): 332-340.

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Transparent and anti-fogging AlPO₄-5 films constructed by oblique oriented nano-flake crystals

Transparent and anti-fogging AlPO₄-5 films constructed by oblique oriented nano-flake crystals

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