Catalytic conversion of ethyl lactate to 1,2-propanediol over CuO

doi:10.1016/j.cjche.2015.06.006

Chinese Journal of Chemical Engineering ›› 2016, Vol. 24 ›› Issue (1): 126-131.DOI: 10.1016/j.cjche.2015.06.006

• 第25届中国过程控制会议专栏 • 上一篇下一篇

Catalytic conversion of ethyl lactate to 1,2-propanediol over CuO

Song Zhang, Zhibao Huo, Dezhang Ren, Jiang Luo, Jun Fu, Lu Li, Fangming Jin

School of Environmental Science and Engineering, The State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China

收稿日期:2014-09-21 修回日期:2015-04-19 出版日期:2016-01-28 发布日期:2016-02-23
通讯作者: Zhibao Huo, Fangming Jin
基金资助:
Supported by the National Natural Science Foundation of China (21277091), the State Key Program of National Natural Science Foundation of China (21436007), Key Basic Research Projects of Science and Technology Commission of Shanghai Municipality (14JC1403100), the Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning (ZXDF160002), and the Project-sponsored by SRF for ROCS, SEM (BG1600002).

Catalytic conversion of ethyl lactate to 1,2-propanediol over CuO

Song Zhang, Zhibao Huo, Dezhang Ren, Jiang Luo, Jun Fu, Lu Li, Fangming Jin

School of Environmental Science and Engineering, The State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China

Received:2014-09-21 Revised:2015-04-19 Online:2016-01-28 Published:2016-02-23
Contact: Zhibao Huo, Fangming Jin
Supported by:
Supported by the National Natural Science Foundation of China (21277091), the State Key Program of National Natural Science Foundation of China (21436007), Key Basic Research Projects of Science and Technology Commission of Shanghai Municipality (14JC1403100), the Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning (ZXDF160002), and the Project-sponsored by SRF for ROCS, SEM (BG1600002).

摘要/Abstract

摘要： An efficient conversion of biomass-derived ethyl lactate to 1,2-propanediol (1,2-PDO) over CuO was investigated. Among the catalysts we tested, CuO, Cu₂O and Co showed excellent catalytic activity for the conversion of ethyl lactate to 1,2-PDO in water, and CuO was more active and gave the best result. The 1,2-PDO yield of 93.6% was achieved when Zn acted as a reductant. The results indicated that in situ formed hydrogen by the oxidation of Zn in water is more effective than gaseous hydrogen, which failed to produce the 1,2-PDO from ethyl lactate. From a practical point of view, the present method may provide a useful route for the production of 1,2-PDO from ethyl lactate.

关键词: Biomass, 1,2-propanediol, Ethyl lactate, CuO, Hydrothermal reactions

Abstract: An efficient conversion of biomass-derived ethyl lactate to 1,2-propanediol (1,2-PDO) over CuO was investigated. Among the catalysts we tested, CuO, Cu₂O and Co showed excellent catalytic activity for the conversion of ethyl lactate to 1,2-PDO in water, and CuO was more active and gave the best result. The 1,2-PDO yield of 93.6% was achieved when Zn acted as a reductant. The results indicated that in situ formed hydrogen by the oxidation of Zn in water is more effective than gaseous hydrogen, which failed to produce the 1,2-PDO from ethyl lactate. From a practical point of view, the present method may provide a useful route for the production of 1,2-PDO from ethyl lactate.

Key words: Biomass, 1,2-propanediol, Ethyl lactate, CuO, Hydrothermal reactions

Song Zhang, Zhibao Huo, Dezhang Ren, Jiang Luo, Jun Fu, Lu Li, Fangming Jin. Catalytic conversion of ethyl lactate to 1,2-propanediol over CuO[J]. Chinese Journal of Chemical Engineering, 2016, 24(1): 126-131.

Song Zhang, Zhibao Huo, Dezhang Ren, Jiang Luo, Jun Fu, Lu Li, Fangming Jin. Catalytic conversion of ethyl lactate to 1,2-propanediol over CuO[J]. Chin.J.Chem.Eng., 2016, 24(1): 126-131.

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