A novel green inhibitor for C-steel corrosion in 2.0 mol·L-1 hydrochloric acid solution

doi:10.1016/j.cjche.2016.08.017

摘要/Abstract

摘要： The corrosion inhibition characteristics of aqueous extract of seeds of Melia azedarach L. (MA) have been studied as eco-friendly green inhibitor for corrosion control of C-steel in 2 mol·L^-1 HCl solution by gravimetric and electrochemical methods. The results depict that, the extract inhibits efficiently the corrosion of carbon steel in hydrochloric acid. The efficiency of extract is increased with increasing the extract concentration but independent on the studied temperature. The adsorption of the extract components onto the steel surface was found to be spontaneous, and follows Langmuir adsorption isotherm. The surface morphology of C-steel, in the absence and presence ofMA extract in 2.0 mol·L^-1 hydrochloric acid solution, was studied using scanning electron microscopy (SEM).

关键词: Corrosion inhibition, C-steel, ^{Melia azedarach} L. extract

Abstract: The corrosion inhibition characteristics of aqueous extract of seeds of Melia azedarach L. (MA) have been studied as eco-friendly green inhibitor for corrosion control of C-steel in 2 mol·L^-1 HCl solution by gravimetric and electrochemical methods. The results depict that, the extract inhibits efficiently the corrosion of carbon steel in hydrochloric acid. The efficiency of extract is increased with increasing the extract concentration but independent on the studied temperature. The adsorption of the extract components onto the steel surface was found to be spontaneous, and follows Langmuir adsorption isotherm. The surface morphology of C-steel, in the absence and presence ofMA extract in 2.0 mol·L^-1 hydrochloric acid solution, was studied using scanning electron microscopy (SEM).

Key words: Corrosion inhibition, C-steel, ^{Melia azedarach} L. extract

A. Y. El-Etre, A. I. Ali. A novel green inhibitor for C-steel corrosion in 2.0 mol·L^-1 hydrochloric acid solution[J]. , 2017, 25(3): 373-380.

参考文献

[1] D. Daoud, T. Douadi, S. Issaadi, S. Chafaa, Adsorption and corrosion inhibition of new synthesized thiophene Schiff base on mild steel X52 in HCl and H2SO4 solutions, Corros. Sci. 79(2014) 50.
[2] M. Deyab, Effect of cationic surfactant and inorganic anions on the electrochemical behavior of carbon steel in formation water, Corros. Sci. 49(2007) 2315.
[3] M. Deyab, S. Keera, Cyclic voltammetric studies of carbon steel corrosion in chlorideformation water solution and effect of some inorganic salts, Egypt. J. Pet. 21(2012) 31.
[4] C.P. Kumar, K. Mohana, Corrosion inhibition efficiency and adsorption characteristics of some Schiff bases at mild steel/hydrochloric acid interface, J. Taiwan Inst. Chem. Eng. 45(2014) 1031.
[5] A.Manivel, S. Ramkumar, J.J.Wu, A.M. Asiri, S. Anandan, Exploration of (S)-4, 5, 6, 7-tetrahydrobenzo[d] thiazole-2, 6-diamine as feasible corrosion inhibitor for mild steel in acidic media, J. Environ. Chem. Eng. 2(2014) 463.
[6] B. Xu, W. Yang, Y. Liu, X. Yin, W. Gong, Y. Chen, Experimental and theoretical evaluation of two pyridinecarboxaldehyde thiosemicarbazone compounds as corrosion inhibitors for mild steel in hydrochloric acid solution, Corros. Sci. 78(2014) 260.
[7] M. Hegazya, A. El-Etre, K. Berry, Novel inhibitors for carbon steel pipelines corrosion during acidizing of oil and gas wells, J. Bas. Environ. Sci. 2(2015) 36.
[8] L. Bammou, M. Belkhaouda, R. Salghi, O. Benali, A. Zarrouk, H. Zarrok, B. Hammouti, Corrosion inhibition of steel in sulfuric acidic solution by the Chenopodium Ambrosioides Extracts, J. Assoc. Arab Univ. Bas. Appl. Sci. 16(2014) 83.
[9] N. El Hamdani, R. Fdil, M. Tourabi, C. Jama, F. Bentiss, Alkaloids extract of Retama monosperma (L.) Boiss. seeds used as novel eco-friendly inhibitor for carbon steel corrosion in 1 M HCl solution:Electrochemical and surface studies, Appl. Surf. Sci. 357(Part A) (2015) 1294.
[10] A.Y. El-Etre, Khillah extract as inhibitor for acid corrosion of SX 316 steel, Appl. Surf. Sci. 252(2006) 8521.
[11] A.Y. El-Etre, Inhibition of acid corrosion of carbon steel using aqueous extract of olive leaves, J. Colloid Interface Sci. 314(2007) 578.
[12] A.Y. El-Etre, Inhibition of C-steel corrosion in acidic solution using the aqueous extract of zallouh root, Mater. Chem. Phys. 108(2008) 278.
[13] M. Sobhi, H. El-Noamany, A. El-Etre, Inhibition of Carbon Steel corrosion in Acid mediumin by Eruca sativa Extract, J. Bas. Environ. Sci. 2(2015) 9.
[14] A. El-Etre, H. Megahed, S. Refaat, Carbon steel corrosion in HCl in the presence of aqueous extract of Melissa Officinalis, J. Bas. Environ. Sci. 2(2015) 52.
[15] M.C. Carpinella, C.G. Ferrayoli, S.M. Palacios, Antifungal synergistic effect of scopoletin, a hydroxycoumarin isolated fromMelia azedarach L. fruits, Journal of agricultural and food chemistry. 53(2005) 2922.
[16] A.V. Khan, Q.U. Ahmed, M.R. Mir, I. Shukla, A.A. Khan, Antibacterial efficacy of the seed extracts of Melia azedarach against some hospital isolated human pathogenic bacterial strains, Asian Pac. J. Trop. Biomed. 1(2011) 452.
[17] C. XiaoTao, T. GuiZhen, C. ZhanLi, Y. QingQiang, Study on chemical constituents of the seed of Melia azedarach L. Food Drug 11(2009) 30.
[18] R.M. Cornell, U. Schwertmann, The iron oxides:structure, properties, reactions, occurrences and uses, John Wiley & Sons, 2006.
[19] E.A. Flores, O. Olivares, N.V. Likhanova, M.A. Domيnguez-Aguilar, N. Nava, D. Guzman-Lucero, M. Corrales, Sodium phthalamates as corrosion inhibitors for carbon steel in aqueous hydrochloric acid solution, Corros. Sci. 53(2011) 3899.
[20] A. Khamis, M. Saleh, M. Awad, Synergistic inhibitor effect of cetylpyridinium chloride and other halides on the corrosion of mild steel in 0.5 M H₂SO₄, Corros. Sci. 66(2013) 343.
[21] R. Fuchs-Godec, V. Doleček, A effect of sodium dodecylsulfate on the corrosion of copper in sulphuric acid media, Colloids Surf. A Physicochem. Eng. Asp. 244(2004) 73.
[22] X. Li, S. Deng, H. Fu, G.Mu, Inhibition effect of 6-benzylaminopurine on the corrosion of cold rolled steel in H₂SO₄ solution, Corros. Sci. 51(2009) 620.
[23] P.B. Raja, A.K. Qureshi, A.A. Rahim, H. Osman, K. Awang, Neolamarckia cadamba alkaloids as eco-friendly corrosion inhibitors for mild steel in 1M HCl media, Corros. Sci. 69(2013) 292.
[24] H.-R. Yu, S. Cho, M.-J. Jung, Y.-S. Lee, Electrochemical and structural characteristics of activated carbon-based electrodes modified via phosphoric acid, Microporous Mesoporous Mater. 172(2013) 131.
[25] M. Behpour, S. Ghoreishi, N. Mohammadi, N. Soltani, M. Salavati-Niasari, Investigation of some Schiff base compounds containing disulfide bond as HCl corrosion inhibitors for mild steel, Corros. Sci. 52(2010) 4046.
[26] N.A. Negm, N.G. Kandile, E.A. Badr, M.A. Mohammed, Gravimetric and electrochemical evaluation of environmentally friendly nonionic corrosion inhibitors for carbon steel in 1M HCl, Corros. Sci. 65(2012) 94.
[27] F. Zhang, Y. Tang, Z. Cao, W. Jing, Z. Wu, Y. Chen, Performance and theoretical study on corrosion inhibition of 2-(4-pyridyl)-benzimidazole for mild steel in hydrochloric acid, Corros. Sci. 61(2012) 1.
[28] F. Bentiss, M. Lagrenee, M. Traisnel, J. Hornez, The corrosion inhibition of mild steel in acidic media by a new triazole derivative, Corros. Sci. 41(1999) 789.
[29] D. Schweinsberg, V. Ashworth, The inhibition of the corrosion of pure iron in 0.5 M sulphuric acid by n-alkyl quaternary ammonium iodides, Corros. Sci. 28(1988) 539.
[30] G. Banerjee, S. Malhotra, Contribution to adsorption of aromatic amines on mild steel surface from HCl solutions by impedance, UV, and Raman spectroscopy, Corrosion 48(1992) 10.
[31] F. Bentiss, M. Traisnel, M. Lagrenee, The substituted 1, 3, 4-oxadiazoles:a new class of corrosion inhibitors of mild steel in acidic media, Corros. Sci. 42(2000) 127.
[32] M. Lebrini, M. Lagrenée, M. Traisnel, L. Gengembre, H. Vezin, F. Bentiss, Enhanced corrosion resistance of mild steel in normal sulfuric acid medium by 2,5-bis(nthienyl)-1,3,4-thiadiazoles:Electrochemical, X-ray photoelectron spectroscopy and theoretical studies, Appl. Surf. Sci. 253(2007) 9267.
[33] J.M. Bockris, B. Yang, The mechanism of corrosion inhibition of iron in acid solution by acetylenic alcohols, J. Electrochem. Soc. 138(1991) 2237.

A novel green inhibitor for C-steel corrosion in 2.0 mol·L^-1 hydrochloric acid solution

A novel green inhibitor for C-steel corrosion in 2.0 mol·L^-1 hydrochloric acid solution

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