SCI和EI收录∣中国化工学会会刊

›› 2017, Vol. 25 ›› Issue (6): 768-774.DOI: 10.1016/j.cjche.2016.11.011

• Separation Science and Engineering • 上一篇    下一篇

Reversible adsorption of metalworking fluids (MWFs) on Cu-BTC metal organic framework

Kwannapat Sorachoti1,2, Bhuckchanya Pangkumhang3, Visanu Tanboonchuy3, Sarttrawut Tulaphol4, Nurak Grisdanurak4,5   

  1. 1. International Program in Hazardous Substance and Environmental Management, Graduate School, Chulalongkorn University, Bangkok, Thailand;
    2. Center of Excellence on Hazardous Substance Management(HSM), Chulalongkorn University, Bangkok, Thailand;
    3. Department of Environmental Engineering, Faculty of Engineering, Khon Kaen University, Khon Kaen, Thailand;
    4. Department of Chemical Engineering, Faculty of Engineering, Thammasat University, Pathumthani, Thailand;
    5. Center of Excellence in Environmental Catalysis and Adsorption, Thammasat University, Pathumthani, Thailand
  • 收稿日期:2016-06-26 修回日期:2016-11-23 出版日期:2017-06-28 发布日期:2017-08-02
  • 通讯作者: Nurak Grisdanurak,E-mail address:gnurak@engr.tu.ac.th

Reversible adsorption of metalworking fluids (MWFs) on Cu-BTC metal organic framework

Kwannapat Sorachoti1,2, Bhuckchanya Pangkumhang3, Visanu Tanboonchuy3, Sarttrawut Tulaphol4, Nurak Grisdanurak4,5   

  1. 1. International Program in Hazardous Substance and Environmental Management, Graduate School, Chulalongkorn University, Bangkok, Thailand;
    2. Center of Excellence on Hazardous Substance Management(HSM), Chulalongkorn University, Bangkok, Thailand;
    3. Department of Environmental Engineering, Faculty of Engineering, Khon Kaen University, Khon Kaen, Thailand;
    4. Department of Chemical Engineering, Faculty of Engineering, Thammasat University, Pathumthani, Thailand;
    5. Center of Excellence in Environmental Catalysis and Adsorption, Thammasat University, Pathumthani, Thailand
  • Received:2016-06-26 Revised:2016-11-23 Online:2017-06-28 Published:2017-08-02

摘要: Metalworking fluids (MWFs) are classified as hazardous substances. Due to the characteristics of the stable oil-water emulsions, it requires more costly and complicate treatment techniques to remove oil from spent MWFs. Metal organic frameworks (MOFs) are a porous network material used to remove contaminants from environment. One of the most prominent of MOFs is HKUST-1 or Cu-BTC. In this study, the Cu-BTCs were prepared by solvothermal method in various conditions and used as absorbent for removing oil micelles in MWF emulsion. The particle size of all synthesized Cu-BTCs ranged from ≈80 to 400 nm. The ability of all synthesized Cu-BTCs to remove oil micelle was greater than 95% in 60 min, while the capacity of GAC was obtained the result for only 6.8%. The maximum adsorption capacity (qmax) of oil micelles on Cu-BTCs was 1666.7 mg·g-1. The highest removal capacity of oil micelles in MWF emulsion is greater than 99% in 24 h by using Cu-BTCs washed with either butanol or ethanol.

关键词: Metalworking fluids, Cutting fluids, Metal organic frameworks

Abstract: Metalworking fluids (MWFs) are classified as hazardous substances. Due to the characteristics of the stable oil-water emulsions, it requires more costly and complicate treatment techniques to remove oil from spent MWFs. Metal organic frameworks (MOFs) are a porous network material used to remove contaminants from environment. One of the most prominent of MOFs is HKUST-1 or Cu-BTC. In this study, the Cu-BTCs were prepared by solvothermal method in various conditions and used as absorbent for removing oil micelles in MWF emulsion. The particle size of all synthesized Cu-BTCs ranged from ≈80 to 400 nm. The ability of all synthesized Cu-BTCs to remove oil micelle was greater than 95% in 60 min, while the capacity of GAC was obtained the result for only 6.8%. The maximum adsorption capacity (qmax) of oil micelles on Cu-BTCs was 1666.7 mg·g-1. The highest removal capacity of oil micelles in MWF emulsion is greater than 99% in 24 h by using Cu-BTCs washed with either butanol or ethanol.

Key words: Metalworking fluids, Cutting fluids, Metal organic frameworks