SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2019, Vol. 27 ›› Issue (6): 1449-1457.DOI: 10.1016/j.cjche.2019.05.004

• Special Issue: Separation Process Intensification of Chemical Engineering • 上一篇    

Recent advances in acid-resistant zeolite T membranes for dehydration of organics

Yiwei Luo1, Waseem Raza1, Jianhua Yang1, Liangqing Li2, Ying Lu1   

  1. 1 State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China;
    2 Collaborative Innovation Center of Fine Chemical and Materials Technology, School of Chemistry and Chemical Engineering, Huangshan University, Huangshan 245041, China
  • 收稿日期:2018-12-28 修回日期:2019-05-06 出版日期:2019-06-28 发布日期:2019-08-19
  • 通讯作者: Jianhua Yang
  • 基金资助:
    Supported by the Fundamental Research Funds of Panjin Industrial Technology Institute (PJYJY2016A004), the National Natural Science Foundation of China (No. 21776032), Natural Science Foundation of Anhui Province (1808085QB51), the Key Research and Development Plan of Anhui Province (1804a09020072), and the Natural Science Research Project of Anhui Colleges and Universities (KJ2017A397).

Recent advances in acid-resistant zeolite T membranes for dehydration of organics

Yiwei Luo1, Waseem Raza1, Jianhua Yang1, Liangqing Li2, Ying Lu1   

  1. 1 State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China;
    2 Collaborative Innovation Center of Fine Chemical and Materials Technology, School of Chemistry and Chemical Engineering, Huangshan University, Huangshan 245041, China
  • Received:2018-12-28 Revised:2019-05-06 Online:2019-06-28 Published:2019-08-19
  • Contact: Jianhua Yang
  • Supported by:
    Supported by the Fundamental Research Funds of Panjin Industrial Technology Institute (PJYJY2016A004), the National Natural Science Foundation of China (No. 21776032), Natural Science Foundation of Anhui Province (1808085QB51), the Key Research and Development Plan of Anhui Province (1804a09020072), and the Natural Science Research Project of Anhui Colleges and Universities (KJ2017A397).

摘要: Zeolite membranes offer outstanding potentials in separation of many molecular mixtures due to their molecular sieving selectivity and the high thermal and mechanical stability that allow them to operate at harsh conditions. Development of durable and high separation performance membranes with lower fabrication and operation cost are highly demanded for industrial applications. Zeolite T membrane possesses good acid-resistance with excellent hydrophilic properties as compared to NaA zeolite membrane and can be extended to industrial organic dehydrations under an acidic environment. In the present review the research advances in development of zeolite T membranes for the dehydration of organic mixtures in acidic conditions are summarized. Especially the low temperature synthesis, and epitaxial growth of the zeolite membrane with high performance are well addressed, besides emphasis is particularly placed on ensemble synthesis of hollow fiber zeolite T membrane module and its future prospects for industrial separations.

关键词: Dehydration of organics, Epitaxial growth, Zeolite T membrane, Membrane pervaporation

Abstract: Zeolite membranes offer outstanding potentials in separation of many molecular mixtures due to their molecular sieving selectivity and the high thermal and mechanical stability that allow them to operate at harsh conditions. Development of durable and high separation performance membranes with lower fabrication and operation cost are highly demanded for industrial applications. Zeolite T membrane possesses good acid-resistance with excellent hydrophilic properties as compared to NaA zeolite membrane and can be extended to industrial organic dehydrations under an acidic environment. In the present review the research advances in development of zeolite T membranes for the dehydration of organic mixtures in acidic conditions are summarized. Especially the low temperature synthesis, and epitaxial growth of the zeolite membrane with high performance are well addressed, besides emphasis is particularly placed on ensemble synthesis of hollow fiber zeolite T membrane module and its future prospects for industrial separations.

Key words: Dehydration of organics, Epitaxial growth, Zeolite T membrane, Membrane pervaporation