Platanus orientalis leaves based hierarchical porous carbon microspheres as high efficiency adsorbents for organic dyes removal

doi:10.1016/j.cjche.2019.03.030

摘要/Abstract

摘要： Water contamination caused by hazardous organic dyes has drawn considerable attention, among all of the techniques released, adsorption has been widely used, which however to a large degree is dependent on the development of high efficiency adsorbents. Waste biomass based porous carbon is becoming the new star class of adsorbents, and thus contribute more to the sustainable development of the society. In this work, for the first time to the best of our knowledge, abundant waste fallen Platanus orientalis leaves are employed as the raw material for hierarchical activated porous carbon (APC) microspheres via a mild hydrothermal carbonization (210℃, 12.0 h) followed by one-step calcination (750℃, 1.0 h). The APC microspheres exhibit a specific surface area of 1355.53 m²·g^-1 and abundant functional groups such as O—H and C=O. Furthermore, the APC microspheres are used as the adsorbents for removal of RhB and MO, with the maximum adsorption capabilities of 557.06 mg·g^-1 and 327.49 mg·g^-1, respectively, higher than those of the most porous carbon originated from biomass. The adsorption rates rapidly approach to 98.2% (RhB) and 95.4% (MO) within 10 min. The adsorption data can be well fitted by Langmuir isotherm model and the pseudo-second-order kinetic model, meanwhile the intra-particle diffusion and Boyd models simultaneously indicate that the diffusion within the pores is the main rate-limiting step. Besides, the APC microspheres also demonstrate good recyclability, and may also be applied to other areas such as heterogeneous catalysis and energy storage.

关键词: Porous carbon microspheres, Biomass, Hydrothermal carbonization, Platanus orientalis, Organic dye, Adsorption

Abstract: Water contamination caused by hazardous organic dyes has drawn considerable attention, among all of the techniques released, adsorption has been widely used, which however to a large degree is dependent on the development of high efficiency adsorbents. Waste biomass based porous carbon is becoming the new star class of adsorbents, and thus contribute more to the sustainable development of the society. In this work, for the first time to the best of our knowledge, abundant waste fallen Platanus orientalis leaves are employed as the raw material for hierarchical activated porous carbon (APC) microspheres via a mild hydrothermal carbonization (210℃, 12.0 h) followed by one-step calcination (750℃, 1.0 h). The APC microspheres exhibit a specific surface area of 1355.53 m²·g^-1 and abundant functional groups such as O—H and C=O. Furthermore, the APC microspheres are used as the adsorbents for removal of RhB and MO, with the maximum adsorption capabilities of 557.06 mg·g^-1 and 327.49 mg·g^-1, respectively, higher than those of the most porous carbon originated from biomass. The adsorption rates rapidly approach to 98.2% (RhB) and 95.4% (MO) within 10 min. The adsorption data can be well fitted by Langmuir isotherm model and the pseudo-second-order kinetic model, meanwhile the intra-particle diffusion and Boyd models simultaneously indicate that the diffusion within the pores is the main rate-limiting step. Besides, the APC microspheres also demonstrate good recyclability, and may also be applied to other areas such as heterogeneous catalysis and energy storage.

Key words: Porous carbon microspheres, Biomass, Hydrothermal carbonization, Platanus orientalis, Organic dye, Adsorption

Xuezhen Jiang, Panpan Sun, Lin Xu, Yingru Xue, Heng Zhang, Wancheng Zhu. Platanus orientalis leaves based hierarchical porous carbon microspheres as high efficiency adsorbents for organic dyes removal[J]. 中国化学工程学报, 2020, 28(1): 254-265.

参考文献

[1] R. Mallampati, X.J. Li, A. Adin, et al., Fruit peels as efficient renewable adsorbents for removal of dissolved heavy metals and dyes from water, ACS Sustain. Chem. Eng. 3(6) (2015) 1117-1124.
[2] J. Chen, S. Ye, Y.H. Song, et al., Multi-morphology mesoporous silica nanoparticles for dye adsorption and multicolor luminescence applications, ACS Sustain. Chem. Eng. 6(3) (2018) 3533-3545.
[3] L. Liu, Z.Y. Gao, X.P. Su, et al., Adsorption removal of dyes from single and binary solutions using a cellulose-based bioadsorbent, ACS Sustain. Chem. Eng. 3(3) (2015) 432-442.
[4] P.P. Sun, L. Xu, J. Li, et al., Hydrothermal synthesis of mesoporous Mg₃Si₂O₅(OH)₄ microspheres as high-performance adsorbents for dye removal, Chem. Eng. J. 334(2018) 377-388.
[5] S.Y. Lim, C.S. Law, M. Markovic, et al., Engineering the slow photon effect in photoactive nanoporous anodic alumina gradient-index filters for photocatalysis, ACS Appl. Mater. Interfaces 10(28) (2018) 24124-24136.
[6] Y. Peng, Z. Yu, F. Li, et al., A novel reduced graphene oxide-based composite membrane prepared via a facile deposition method for multifunctional applications:oil/water separation and cationic dyes removal, Sep. Purif. Technol. 200(2018) 130-140.
[7] N. Ghaemi, P. Safari, Nano-porous SAPO-34 enhanced thin-film nanocomposite polymeric membrane:simultaneously high water permeation and complete removal of cationic/anionic dyes from water, J. Hazard. Mater. 358(2018) 376-388.
[8] W.E. Thung, S.A. Ong, L.N. Ho, et al., Biodegradation of acid orange 7 in a combined anaerobic-aerobic up-flow membrane-less microbial fuel cell:mechanism of biodegradation and electron transfer, Chem. Eng. J. 336(2018) 397-405.
[9] M. Jayapal, H. Jagadeesan, M. Shanmugam, et al., Sequential anaerobic-aerobic treatment using plant microbe integrated system for degradation of azo dyes and their aromatic amines by-products, J. Hazard. Mater. 354(2018) 231-243.
[10] A. Aichour, H. Zaghouane-Boudiaf, C.V. Iborra, et al., Bioadsorbent beads prepared from activated biomass/alginate for enhanced removal of cationic dye from water medium:kinetics, equilibrium and thermodynamic studies, J. Hazard. Mater. 256(2018) 533-540.
[11] C. Tang, B. Wang, H.F. Wang, et al., Defect engineering toward atomic Co-N_x-C in hierarchical graphene for rechargeable flexible solid Zn-air batteries, Adv. Mater. 29(2017), 1703185.
[12] Y. Zhong, X. Xia, S. Deng, et al., Popcorn inspired porous macrocellular carbon:rapid puffing fabrication from rice and it's applications in lithium-sulfur batteries, Adv. Energy Mater. 8(2018), 1701110.
[13] J.H. Kim, J.Y. Oh, J.M. Lee, et al., Macroscopically interconnected hierarchically porous carbon monolith by metal-phenolic coordination as an sorbent for multi-scale molecules, Carbon. 126(2018) 190-196.
[14] W. Xin, Y. Song, J. Peng, et al., Synthesis of biomass-derived mesoporous carbon with super adsorption performance by an aqueous cooperative assemble route, ACS Sustain. Chem. Eng. 5(3) (2017) 2312-2319.
[15] Z.Q. Hao, J.P. Cao, Y. Wu, et al., Preparation of porous carbon sphere from waste sugar solution for electric double-layer capacitor, J. Power Sources 361(2017) 249-258.
[16] R. Zambare, X. Song, S. Bhuvana, et al., Ultrafast dye removal using ionic liquidgraphene oxide sponge, ACS Sustain. Chem. Eng. 5(7) (2017) 6026-6035.
[17] S.K. Park, S.H. Yang, Y.C. Kang, Rational design of metal-organic framework-templated hollow NiCo₂O₄ polyhedrons decorated on macroporous CNT microspheres for improved lithium-ion storage properties, Chem. Eng. J. 349(2018) 214-222.
[18] M. Chethana, L.G. Sorokhaibam, V.M. Bhandari, et al., Green approach to dye wastewater treatment using biocoagulants, ACS Sustain. Chem. Eng. 4(5) (2016) 2495-2507.
[19] T. Maneerung, J. Liew, Y. Dai, et al., Activated carbon derived from carbon residue from biomass gasification and its application for dye adsorption:kinetics, isotherms and thermodynamic studies, Bioresour. Technol. 200(2016) 350-359.
[20] J.X. Yu, B.H. Li, X.M. Sun, et al., Polymer modified biomass of baker's yeast for enhancement adsorption of methylene blue, rhodamine B and basic magenta, J. Hazard. Mater. 168(2-3) (2009) 1147-1154.
[21] L. Ding, B. Zou, W. Gao, Q. Liu, Z. Wang, Y. Guo, X. Wang, Y. Liu, Adsorption of rhodamine-B from aqueous solution using treated rice husk-based activated carbon, Colloids Surf. A Physicochem. Eng. Asp. 446(2014) 1-7.
[22] L. Wang, J. Zhang, R. Zhao, et al., Adsorption of basic dyes on activated carbon prepared from polygonum orientale linn:Equilibrium, kinetic and thermodynamic studies, Desalination 254(1-3) (2010) 68-74.
[23] C. Fang, M. Tan, H. Zhuang, et al., Longan seed and mangosteen skin based activated carbons for removal of Pb(II) ions and rhodamine-B dye from aqueous solutions, Desalin. Water Treat. 88(2017) 154-161.
[24] A.H. Mahvi, R. Nabizadeh, F. Gholami, et al., Adsorption of chromium from wastewater by Platanus orientalis leaves, Iran. J. Environ. Health Sci. Eng. 4(2007) 191-196.
[25] Ş. Sert, C. Kütahyali, S. İnan, et al., Biosorption of lanthanum and cerium from aqueous solutions by Platanus orientalis leaf powder, Hydrometallurgy 90(1) (2008) 13-18.
[26] A.H. Mahvi, J. Nouri, G.A. Omrani, et al., Application of Platanus orientalis leaves in removal of cadmium from aqueous solution, World Appl. Sci. J. 2(1) (2007) 40-44.
[27] M. Peydayesh, A. Rahbar-Kelishami, Adsorption of methylene blue onto Platanus orientalis leaf powder:Kinetic, equilibrium and thermodynamic studies, J. Ind. Eng. Chem. 21(2015) 1014-1019.
[28] J.I. Morán, V.A. Alvarez, V.P. Cyras, et al., Extraction of cellulose and preparation of nanocellulose from sisal fibers, Cellulose 15(1) (2007) 149-159.
[29] Z. Jia, Z. Li, T. Ni, et al., Adsorption of low-cost absorption materials based on biomass (cortaderia selloana flower spikes) for dye removal:Kinetics, isotherms and thermodynamic studies, J. Mol. Liq. 229(2017) 285-292.
[30] J.R. Garcia, U. Sedran, M.A.A. Zaini, et al., Preparation, characterization, and dye removal study of activated carbon prepared from palm kernel shell, Environ. Sci. Pollut. Res. 25(6) (2018) 5076-5085.
[31] K.Y. Foo, B.H. Hameed, Coconut husk derived activated carbon via microwave induced activation:Effects of activation agents, preparation parameters and adsorption performance, Chem. Eng. J. 184(2012) 57-65.
[32] K.Y. Foo, B.H. Hameed, Preparation of activated carbon from date stones by microwave induced chemical activation:Application for methylene blue adsorption, Chem. Eng. J. 170(1) (2011) 338-341.
[33] E. Hao, W. Liu, S. Liu, et al., Rich sulfur doped porous carbon materials derived from ginkgo leaves for multiple electrochemical energy storage devices, J. Mater. Chem. A 5(5) (2017) 2204-2214.
[34] X. Zhou, P. Wang, Y. Zhang, et al., Biomass based nitrogen-doped structure-tunable versatile porous carbon materials, J. Mater. Chem. A 5(25) (2017) 12958-12968.
[35] J. Yu, L.Z. Gao, X.L. Li, et al., Porous carbons produced by the pyrolysis of green onion leaves and their capacitive behavior, New Carbon Mater. 31(5) (2016) 475-484.
[36] C. Wang, J. Huang, H. Qi, et al., Controlling pseudographtic domain dimension of dandelion derived biomass carbon for excellent sodium-ion storage, J. Power Sources 358(2017) 85-92.
[37] E. Raymundo Piñero, M. Cadek, F. Béguin, Tuning carbon materials for supercapacitors by direct pyrolysis of seaweeds, Adv. Funct. Mater. 19(7) (2009) 1032-1039.
[38] Z. Geng, Q. Xiao, D. Wang, et al., Improved electrochemical performance of biomassderived nanoporous carbon/sulfur composites cathode for lithium-sulfur batteries by nitrogen doping, Electrochim. Acta 202(2016) 131-139.
[39] G. Pari, S. Darmawan, B. Prihandoko, Porous carbon spheres from hydrothermal carbonization and KOH activation on cassava and tapioca flour raw material, Procedia Environ. Sci. 20(2014) 342-351.
[40] A.M. Abioye, F.N. Ani, Recent development in the production of activated carbon electrodes from agricultural waste biomass for supercapacitors:A review, Renew. Sust. Energ. Rev. 52(2015) 1282-1293.
[41] H.M. Coromina, D.A. Walsh, R. Mokaya, Biomass-derived activated carbon with simultaneously enhanced CO₂ uptake for both pre and post combustion capture applications, J. Mater. Chem. A 4(1) (2016) 280-289.
[42] X. Gu, Y. Wang, C. Lai, et al., Microporous bamboo biochar for lithium-sulfur batteries, Nano Res. 8(1) (2014) 129-139.
[43] K. Sharma, A.K. Dalai, R.K. Vyas, Removal of synthetic dyes from multicomponent industrial wastewaters, Rev. Chem. Eng. 34(1) (2017) 107-134.
[44] H. Mittal, S.B. Mishra, Gum ghatti and Fe₃O₄ magnetic nanoparticles based nanocomposites for the effective adsorption of rhodamine B, Carbohydr. Polym. 101(2014) 1255-1264.
[45] Z. Sun, X. Duan, C. Srinivasakannan, et al., Preparation of magnesium silicate/carbon composite for adsorption of rhodamine B, RSC Adv. 8(14) (2018) 7873-7882.
[46] L. Wang, F. Sun, J. Gao, et al., Adjusting the porosity of coal-based activated carbons based on a catalytic physical activation process for gas and liquid adsorption, Energy Fuel 32(2) (2018) 1255-1264.
[47] H. Lata, S. Mor, V.K. Garg, et al., Removal of a dye from simulated wastewater by adsorption using treated parthenium biomass, J. Hazard. Mater. 153(1-2) (2008) 213-220.
[48] B. Li, Q. Wang, J.Z. Guo, et al., Sorption of methyl orange from aqueous solution by protonated amine modified hydrochar, Bioresour. Technol. 268(2018) 454-459.
[49] H. Li, Z. Sun, L. Zhang, et al., A cost-effective porous carbon derived from pomelo peel for the removal of methyl orange from aqueous solution, Colloids Surf. A Physicochem. Eng. Asp. 489(2016) 191-199.
[50] P. Hou, G. Xing, D. Han, et al., Preparation of zeolite imidazolate framework/graphene hybrid aerogels and their application as highly efficient adsorbent, J. Solid State Chem. 265(2018) 184-192.
[51] J. Wang, M. Cao, C. Jiang, et al., Adsorption and coadsorption mechanisms of Hg²⁺ and methyl orange by branched polyethyleneimine modified magnetic straw, Mater. Lett. 229(2018) 160-163.
[52] H. Mittal, V. Kumar, S.M. Alhassan, et al., Modification of gum ghatti via grafting with acrylamide and analysis of its flocculation, adsorption, and biodegradation properties, Int. J. Biol. Macromol. 114(2018) 283-294.
[53] L.S. Silva, F.J.L. Ferreira, M.S. Silva, et al., Potential of amino-functionalized cellulose as an alternative sorbent intended to remove anionic dyes from aqueous solutions, Int. J. Biol. Macromol. 116(2018) 1282-1295.
[54] H.M. Jang, S. Yoo, Y.K. Choi, et al., Adsorption isotherm, kinetic modeling and mechanism of tetracycline on Pinus taeda-derived activated biochar, Bioresour. Technol. 259(2018) 24-31.
[55] Y. Gao, K. Liu, R. Kang, et al., A comparative study of rigid and flexible MOFs for the adsorption of pharmaceuticals:Kinetics, isotherms and mechanisms, J. Hazard. Mater. 359(2018) 248-257.
[56] L. Yang, Y. Zhang, X. Liu, et al., The investigation of synergistic and competitive interaction between dye red and methyl blue on magnetic MnFe₂O₄, Chem. Eng. J. 246(2014) 88-96.
[57] S. Mortazavian, H. An, D. Chun, et al., Activated carbon impregnated by zero-valent iron nanoparticles (AC/nZVI) optimized for simultaneous adsorption and reduction of aqueous hexavalent chromium:material characterizations and kinetic studies, Chem. Eng. J. 353(2018) 781-795.
[58] M.Y. Sobhy, Removal of the hazardous, volatile, and organic compound benzene from aqueous solution using phosphoric acid activated carbon from rice husk, Chem. Cent. J. 8(1) (2014) 52-59.
[59] B. El-Gammal, S.S. Metwally, H.F. Aly, et al., Verification of double-shell model for sorption of cesium, cobalt, and europium ions on poly-acrylonitrile-based Ce(IV) phosphate from aqueous solutions, Desalin. Water Treat. 46(1-3) (2012) 124-138.