SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2020, Vol. 28 ›› Issue (5): 1459-1473.DOI: 10.1016/j.cjche.2020.03.003

• Materials and Product Engineering • 上一篇    下一篇

The study on the mechanical properties of PU/MF double shell selfhealing microcapsules

Guohao Du1, Jianfeng Hu1, Jianhui Zhou2, Guangwu Wang3, Shengli Guan3, Hailing Liu3, Man Geng3, Chuang Lü3, Yaoqiang Ming1, Jinqing Qu1   

  1. 1 School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, China;
    2 State Key Laboratory of Advanced Transmission Technology, Beijing 100000, China;
    3 Guangzhou Goaland Energy Conservation Tech. Co., Ltd., Guangzhou 510663, China
  • 收稿日期:2019-12-01 修回日期:2020-02-18 出版日期:2020-05-28 发布日期:2020-07-29
  • 通讯作者: Jianfeng Hu

The study on the mechanical properties of PU/MF double shell selfhealing microcapsules

Guohao Du1, Jianfeng Hu1, Jianhui Zhou2, Guangwu Wang3, Shengli Guan3, Hailing Liu3, Man Geng3, Chuang Lü3, Yaoqiang Ming1, Jinqing Qu1   

  1. 1 School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, China;
    2 State Key Laboratory of Advanced Transmission Technology, Beijing 100000, China;
    3 Guangzhou Goaland Energy Conservation Tech. Co., Ltd., Guangzhou 510663, China
  • Received:2019-12-01 Revised:2020-02-18 Online:2020-05-28 Published:2020-07-29
  • Contact: Jianfeng Hu

摘要: The self-healing microcapsules can be buried in the coating to improve the anticorrosive ability. In this paper, self-healing microcapsules of polyurea (PU)/melamine resin (MF) double shell were prepared by in-situ polymerization and interfacial polymerization with isocyanate as the core material. Scanning electron microscope was used to observe the microcapsule morphology. The structures of microcapsules prepared with different chain extenders were characterized by Fourier transform infrared spectroscopy. The micromanipulation system was used to loading-holding, loading-unloading and loading to rupture individual microcapsules, so as to explore the mechanical properties of microcapsules. The Young's modulus corresponding to microcapsules was calculated by mathematical model fitting. The self-healing properties of microcapsule coating were characterized by optical microscope. The experimental results showed that the microcapsule shell prepared under optimized conditions had a complete morphology and good mechanical properties. The microcapsule was in the elastic deformation stage under small deformation, and the plastic deformation stage under large deformation. The Young's modulus range of microcapsules was 9.29-14.51 MPa, and the corresponding Young's modulus could be prepared by adjusting the process. The surface crack of the coating containing microcapsule could heal itself after 48 h in a humid environment.

关键词: Microcapsules, Self-healing, Double-layered, Mechanical properties, Young's modulus

Abstract: The self-healing microcapsules can be buried in the coating to improve the anticorrosive ability. In this paper, self-healing microcapsules of polyurea (PU)/melamine resin (MF) double shell were prepared by in-situ polymerization and interfacial polymerization with isocyanate as the core material. Scanning electron microscope was used to observe the microcapsule morphology. The structures of microcapsules prepared with different chain extenders were characterized by Fourier transform infrared spectroscopy. The micromanipulation system was used to loading-holding, loading-unloading and loading to rupture individual microcapsules, so as to explore the mechanical properties of microcapsules. The Young's modulus corresponding to microcapsules was calculated by mathematical model fitting. The self-healing properties of microcapsule coating were characterized by optical microscope. The experimental results showed that the microcapsule shell prepared under optimized conditions had a complete morphology and good mechanical properties. The microcapsule was in the elastic deformation stage under small deformation, and the plastic deformation stage under large deformation. The Young's modulus range of microcapsules was 9.29-14.51 MPa, and the corresponding Young's modulus could be prepared by adjusting the process. The surface crack of the coating containing microcapsule could heal itself after 48 h in a humid environment.

Key words: Microcapsules, Self-healing, Double-layered, Mechanical properties, Young's modulus