Insight into solute-solute and solute-solvent interactions of semicarbazide hydrochloride in water and D-glucose/D-sucrose+water solutions at temperatures (293.15 to 318.15) K

doi:10.1016/j.cjche.2020.07.007

中国化学工程学报 ›› 2020, Vol. 28 ›› Issue (12): 3086-3095.DOI: 10.1016/j.cjche.2020.07.007

• Chemical Engineering Thermodynamics • 上一篇下一篇

Insight into solute-solute and solute-solvent interactions of semicarbazide hydrochloride in water and D-glucose/D-sucrose+water solutions at temperatures (293.15 to 318.15) K

Ankita^1,2, Dinesh Chand³, Anil Kumar Nain¹

1 Department of Chemistry, Dyal Singh College, University of Delhi, New Delhi 110003, India;
2 Department of Chemistry, University of Delhi, Delhi 110007, India;
3 Department of Chemistry, Amity University Dubai Campus, Dubai International Academic City, Dubai, UAE

收稿日期:2020-01-26 修回日期:2020-06-27 出版日期:2020-12-28 发布日期:2021-01-11
通讯作者: Anil Kumar Nain
基金资助:
The authors are thankful to the Head, Department of Chemistry (University of Delhi), Delhi, India for encouragement and providing facilities.

Insight into solute-solute and solute-solvent interactions of semicarbazide hydrochloride in water and D-glucose/D-sucrose+water solutions at temperatures (293.15 to 318.15) K

Ankita^1,2, Dinesh Chand³, Anil Kumar Nain¹

1 Department of Chemistry, Dyal Singh College, University of Delhi, New Delhi 110003, India;
2 Department of Chemistry, University of Delhi, Delhi 110007, India;
3 Department of Chemistry, Amity University Dubai Campus, Dubai International Academic City, Dubai, UAE

Received:2020-01-26 Revised:2020-06-27 Online:2020-12-28 Published:2021-01-11
Contact: Anil Kumar Nain
Supported by:
The authors are thankful to the Head, Department of Chemistry (University of Delhi), Delhi, India for encouragement and providing facilities.

摘要/Abstract

摘要： The solute-solute and solute-solvent interactions of drug semicarbazide hydrochloride with carbohydrates (D-glucose/D-sucrose) are investigated by using volumetric, viscometric and acoustic properties. The measurements of the densities ρ, ultrasonic speeds u, and viscosities η. of semicarbazide hydrochloride in 5% and 10% D-glucose/D-sucrose+water (w/w) solutions were carried out at temperatures (293.15-318.15) K and at pressure, p=101 kPa. The apparent molar volumes, V_ϕ, limiting apparent molar volumes,V_ϕ°, apparent molar compressibilities, K_{s, ϕ}, limiting apparent molar compressibilities, K_s,ϕ°, partial molar expansibilities, E_ϕ°, transfer volumes, V_ϕ,tr° and transfer compressibilities, K_s,ϕ,tr° have been calculated from the experimental data. The viscosity data were examined by using the Jones-Dole equation and the viscosity A and B coefficients were evaluated. The results are discussed in terms of solute-solute and solute-solvent interactions in these solutions. The structure making/breaking ability of semicarbazide hydrochloride is examined using the sign of temperature derivative of B-coefficient, dB/dT.

关键词: Density, Ultrasonic speed, Viscosity, Semicarbazide hydrochloride, Carbohydrates, Solute-solvent interactions

Abstract: The solute-solute and solute-solvent interactions of drug semicarbazide hydrochloride with carbohydrates (D-glucose/D-sucrose) are investigated by using volumetric, viscometric and acoustic properties. The measurements of the densities ρ, ultrasonic speeds u, and viscosities η. of semicarbazide hydrochloride in 5% and 10% D-glucose/D-sucrose+water (w/w) solutions were carried out at temperatures (293.15-318.15) K and at pressure, p=101 kPa. The apparent molar volumes, V_ϕ, limiting apparent molar volumes,V_ϕ°, apparent molar compressibilities, K_{s, ϕ}, limiting apparent molar compressibilities, K_s,ϕ°, partial molar expansibilities, E_ϕ°, transfer volumes, V_ϕ,tr° and transfer compressibilities, K_s,ϕ,tr° have been calculated from the experimental data. The viscosity data were examined by using the Jones-Dole equation and the viscosity A and B coefficients were evaluated. The results are discussed in terms of solute-solute and solute-solvent interactions in these solutions. The structure making/breaking ability of semicarbazide hydrochloride is examined using the sign of temperature derivative of B-coefficient, dB/dT.

Key words: Density, Ultrasonic speed, Viscosity, Semicarbazide hydrochloride, Carbohydrates, Solute-solvent interactions

Ankita, Dinesh Chand, Anil Kumar Nain. Insight into solute-solute and solute-solvent interactions of semicarbazide hydrochloride in water and D-glucose/D-sucrose+water solutions at temperatures (293.15 to 318.15) K[J]. 中国化学工程学报, 2020, 28(12): 3086-3095.

参考文献

[1] D.M. Bhattacharya, S.S. Dhondge, S.P. Zodape, Solvation behaviour of an antihelmintic drug in aqueous solutions of sodium chloride and glucose at different temperatures, J. Chem. Thermodyn. 101(2016) 207-220.
[2] A. Sarkar, B.K. Pandit, B. Sinha, Volumetric and transport properties of betaine hydrochloride drug in aqueous uracil solutions at T=(298.15-318.15) K, J. Chem. Thermodyn. 98(2016) 118-125.
[3] K. Rajagopal, S.S. Jayabalakrishnan, Ultrasonic studies of 4-aminobutyric acid in aqueous salbutamol sulphate solutions at different temperatures, Chin. J. Chem. Eng. 18(2010) 659-666.
[4] S.S. Dhondge, S.P. Zodape, D.V. Parwate, Volumetric and viscometric studies of some drugs in aqueous solutions at different temperatures, J. Chem. Thermodyn. 48(2012) 207-212.
[5] M.J. Iqbal, M.A. Chaudhary, Thermodynamic study of three pharmacologically significant drugs:Density, viscosity, and refractive index measurements at different temperatures, J. Chem. Thermodyn. 41(2009) 221-226.
[6] S.J. Kharat, Partial Molar Volume, Jones-dole coefficient, and limiting molar isentropic compressibility of sodium ibuprofen in water and its hydration number and hydration free energy, Thermochim. Acta 566(2013) 124-129.
[7] D.V. Jahagirdar, B.R. Arbad, A.A. Walvekar, A.G. Shankarwar, M.K. Lande, Studies in partial molar volumes, partial molar compressibilities and viscosity B-coefficients of caffeine in water at four temperatures, J. Mol. Liq. 85(2000) 361-373.
[8] S.K. Sharma, G. Singh, H. Kumar, R. Kataria, Solvation behavior of some amino acids in aqueous solutions of non-steroidal anti-inflammatory drug sodium ibuprofen at different temperatures analysed by volumetric and acoustic methods, J. Chem. Thermodyn. 98(2016) 214-230.
[9] D.K. Mishra, A. Das, A. Kamath, B. Sinha, Solution thermodynamics and taste behaviour of nicotinic acid in aqueous sodium gluconate solutions:A volumetric and rheological perspective, J. Mol. Liq. 230(2017) 662-666.
[10] S.A. Galema, H. Hoiland, Stereochemical aspects of hydration of carbohydrates in aqueous solutions. 3. Density and ultrasound measurements, J. Phys. Chem. 95(1991) 5321-5326.
[11] V. Singh, P.K. Chhotaray, R.L. Gardas, Volumetric and ultrasonic properties of ternary (sucrose +water+protic ionic liquid) solution, J. Chem. Thermodyn. 89(2015) 60-68.
[12] H. Kumar Sheetal, Densities and speeds of sound of D(+)-glucose, D(-)-fructose, D (+)-xylose and D(-)-ribose in aqueous tripotassium citrate solutions at different temperatures, J. Chem. Eng. Data 61(2016) 2244-2259.
[13] S. Chauhan, V. Sharma, M. Kaur, P. Chaudhary, Temperature-dependent aggregation of bio-surfactants in aqueous solutions of galactose and lactose:volumetric and viscometric approach, Chin. J. Chem. Eng. 26(2018) 1119-1131.
[14] A.K. Nain Ankita, Solute-solute and solute-solvent interactions of drug sodium salicylate in aqueous-glucose/sucrose solutions at temperatures from 293.15 to 318.15 K:A physicochemical study, J. Mol. Liq. 298(2020), 112006.
[15] D. Ankita, A.K. Nain Chand, Molecular interactions of drug semicarbazide hydrochloride in aqueous-D-xylose/L-arabinose solutions at different temperatures:Volumetric, acoustic and viscometric study, J. Chem. Thermodyn. 146(2020), 106106.
[16] M. Takahashi, M. Yoshida, K. Inoue, T. Morikawa, A. Nishikawa, K. Ogawa, Chronic toxicity and carcinogenicity of semicarbazide hydrochloride in Wistar Hannover GALAS rats, Food Chem. Toxicol. 73(2014) 84-94.
[17] T.S. Krishna, M. Gowrisankar, K.T.S.S. Raju, S.G. Rao, B. Munibhadrayya, Acoustic, volumetric, and optic study of binary mixture of 1-butyl-3-methylimidazoliumtetrafluoroborate with propylene glycols at T=(298.15 to 323.15) K, J. Mol. Liq. 206(2015) 350-358.
[18] D. Brahman, B. Sinha, Partial molar volumes and viscosity B-coefficients of N,N'-ethylene-bis(salicylideneiminato)cobalt(II) in binary mixtures of 1,4-dioxane+methanol at T=(298.15, 303.15, 308.15, and 313.15) K, J. Chem. Eng. Data 56(2011) 3073-3082.
[19] J. Krakowiak, Apparent molar volumes and compressibilities of tetrabutylammonium bromide in organic solvents, J. Chem. Thermodyn. 43(2011) 882-894.
[20] D. Brahman, B. Sinha, Partial molar volumes and viscosity B-coefficients for N,N/-ethylene-bis(salicylideneiminato)-diaquochromium(III) chloride in methanolic solutions of 1-butyl-2,3-dimethylimidazolium tetrafluoroborate at T=(298.15, 308.15, and 318.15) K, J. Chem. Thermodyn. 68(2014) 260-269.
[21] D.O. Masson, Solute molecular volumes in relation to solvation and ionization, Philos. Mag. 8(1929) 218-223.
[22] H. Kumar, V. Kumar, M. Sharma, I. Behal, Studies on the interactions behaviour of polyhydroxy solutes d(+)-glucose and d(-)-fructose in aqueous triammonium citrate solutions over temperature range T=(288.15-318.15) K, J. Chem. Thermodyn. 119(2018) 1-12.
[23] S.S. Dhondge, P.N. Dahasahasra, L.J. Paliwal, D.W. Deshmukh, Density and viscosity study of nicotinic acid and nicotinamide in dilute aqueous solutions at and around the temperature of the maximum density of water, J. Chem. Thermodyn. 76(2014) 16-23.
[24] M.J. Iqbal, M.A. Chaudhry, Thermodynamic studies on the interactions of phenyl salicylate in protic solvents at different temperatures, J. Mol. Liq. 143(2008) 75-80.
[25] H. Kumar, I. Sheetal, S. Sharma Behal, Temperature dependence of the volumetric and acoustic behaviour of aqueous mixtures of monosaccharides and trilithium citrate, J. Chem. Thermodyn. 113(2017) 52-63.
[26] T.S. Banipal, H. Singh, P.K. Banipal, V. Singh, Volumetric and viscometric studies on L-ascorbic acid, nicotinic acid, thiamine hydrochloride and pyridoxine hydrochloride in water at temperatures (288.15-318.15) K and at atmospheric pressure, Thermochim. Acta 553(2013) 31-39.
[27] A. Sarkar, B. Sinha, Volumetric, acoustic and transport properties of metformin hydrochloride drug in aqueous D-glucose solutions at T=(298.15-318.15) K, J. Solut. Chem. 46(2017) 424-445.
[28] B. Sinha, A. Sarkar, P. Roy, D. Brahman, Physicochemical properties of L-alanine in aqueous silver sulphate solutions at (298.15, 308.15 and 318.15) K, Int. J. Thermophys. 32(2011) 2062-2078.
[29] F.J. Millero, in:R.A. Horne (Ed.), Structure and Transport Process in Water and Aqueous Solutions, Wiley-Interscience, New York 1972, pp. 519-595.
[30] P.R. Misra, B. Das, M.L. Parmar, D.S. Banyal, Effect of temperature on the partial molar volumes of some bivalent transition metal nitrates and magnesium nitrate in DMF+water mixtures, Indian J. Chem. 44A (2005) 1582-1588.
[31] R.L. Gardas, D.H. Dagade, S. Terdale, J.A.P. Coutinho, K.J. Patil, Acoustic and volumetric properties of aqueous solutions of imidazolium based ionic liquids at 298.15 K, J. Chem. Thermodyn. 40(2008) 695-701.
[32] H. Frank, M.W. Evans, Free volume and entropy in condensed systems III. Entropy in binary liquid mixtures; partial molal entropy in dilute solutions; structure and thermodynamics in aqueous electrolytes, J. Chem. Phys. 13(1945) 507-532.
[33] F. Franks, M. Quickenden, D. Reid, B. Watson, Calorimetric and volumetric studies of dilute aqueous solutions of cyclic ether derivatives, Faraday Soc. 66(1970) 582-589.
[34] M. Nardelli, G. Fava, G. Giraldi, The crystal and molecular structure of semicarbazide hydrochloride, Acta Cryst. 19(1965) 1038-1042.
[35] C. Zhao, P. Ma, J. Li, Partial molar volumes and viscosity B-coefficients of arginine in aqueous glucose, sucrose and l-ascorbic acid solutions at T=298.15 K, J. Chem. Thermodyn. 37(2005) 37-42.
[36] G. Jones, M. Dole, The viscosity of aqueous solutions of strong electrolytes with special reference to barium chloride, J. Am. Chem. Soc. 51(1929) 2950-2964.
[37] H. Falkenhagen, M. Dole, The internal friction of electrolytic solutions and its interpretation according to the debye theory, Z. Phys. 30(1929) 611-616.
[38] H. Falkenhagen, E.L. Vernon, The viscosity of strong electrolyte solutions according to electrostatic theory, Z. Phys. 33(1932) 140-145.
[39] H.J. Bakker, Structural dynamics of aqueous salt solutions, Chem. Rev. 108(2008) 1456-1473.
[40] E. Nightingale Jr., B. Conway, R. Barradas, Chemical Physics of Ionic Solutions, John Wiley, New York, 1966.

Insight into solute-solute and solute-solvent interactions of semicarbazide hydrochloride in water and D-glucose/D-sucrose+water solutions at temperatures (293.15 to 318.15) K

Insight into solute-solute and solute-solvent interactions of semicarbazide hydrochloride in water and D-glucose/D-sucrose+water solutions at temperatures (293.15 to 318.15) K

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Hae-Kyun Park, Dong-Hyuk Park, Bum-Jin Chung. Influence of the electrolyte conductivity on the critical current density and the breakdown voltage[J]. 中国化学工程学报, 2023, 59(7): 169-175.
[2]	Tinghao Jia, Yunbo Yu, Qing Liu, Yao Yang, Ji-Jun Zou, Xiangwen Zhang, Lun Pan. Theoretical and experimental study on the inhibition of jet fuel oxidation by diarylamine[J]. 中国化学工程学报, 2023, 56(4): 225-232.
[3]	Songsong Wang, Hong Li, Changyuan Tao, Renlong Liu, Yundong Wang, Zuohua Liu. Study on cavern evolution and performance of three mixers in agitation of yield-pseudoplastic fluids[J]. 中国化学工程学报, 2023, 55(3): 111-122.
[4]	Xianglin Liu, Minjie Xu, Chenxi Cao, Zixu Yang, Jing Xu. Effects of zinc on χ-Fe₅C₂ for carbon dioxide hydrogenation to olefins: Insights from experimental and density function theory calculations[J]. 中国化学工程学报, 2023, 54(2): 206-214.
[5]	Yifeng Chen, Hang Yu, Jingjing Chen, Xiaohua Lu, Xiaoyan Ji. Viscous behavior of 1-hexyl-methylimidazolium bis(trifluoromethylsulfonyl)imide/titanium dioxide/polyethylene glycol[J]. 中国化学工程学报, 2023, 54(2): 280-287.
[6]	Baodong Zhao, Yinglei Wang, Fulei Gao, Yajing Liu, Weixiao Liu, Feng Ding. Understanding the alkyl effect of geminal dinitropropyl ester energetic plasticizers on hydroxyl terminated polybutadiene (HTPB): Simultaneous tuning on low temperature behavior and processability[J]. 中国化学工程学报, 2023, 54(2): 364-371.
[7]	Yang Liu, Qiu Han, Guiliang Li, Haibo Lin, Fu Liu, Gang Deng, Dingfeng Lv, Weijie Sun. Purifying chylous plasma by precluding triglyceride via carboxylated polyethersulfone microfiltration membrane[J]. 中国化学工程学报, 2022, 49(9): 130-139.
[8]	Fenfen You, Qing-Hong Shi. In situ investigation of lysozyme adsorption into polyelectrolyte brushes by quartz crystal microbalance with dissipation[J]. 中国化学工程学报, 2022, 48(8): 106-115.
[9]	Yaqi Ren, Shuqian Xia. Synthesis and mechanism analysis of a new oil soluble viscosity reducer for flow improvement of Chenping heavy oil[J]. 中国化学工程学报, 2022, 45(5): 58-67.
[10]	Anil Kumar Nain. Study of intermolecular interactions in binary mixtures of methyl acrylate with benzene and methyl substituted benzenes at different temperatures: An experimental and theoretical approach[J]. 中国化学工程学报, 2022, 44(4): 212-238.
[11]	Liuting Zhang, Haijie Yu, Zhiyu Lu, Changhao Zhao, Jiaguang Zheng, Tao Wei, Fuying Wu, Beibei Xiao. The effect of different Co phase structure (FCC/HCP) on the catalytic action towards the hydrogen storage performance of MgH₂[J]. 中国化学工程学报, 2022, 43(3): 343-352.
[12]	Li Ma, Yongjin Cui, Lin Sheng, Chencan Du, Jian Deng, Guangsheng Luo. Determination of interfacial tension and viscosity under dripping flow in a step T-junction microdevice[J]. 中国化学工程学报, 2022, 42(2): 210-218.
[13]	Qingjun Zhang, Pengyuan Shi, Xigang Yuan, Youguang Ma, Aiwu Zeng. Direct carboxylation of thiophene with CO₂ in the solvent-free carboxylate-carbonate molten medium: Experimental and mechanistic insights[J]. 中国化学工程学报, 2022, 50(10): 264-282.
[14]	Wei-Qi Yan, Yi-An Zhu, Xing-Gui Zhou, Wei-Kang Yuan. Rational design of heterogeneous catalysts by breaking and rebuilding scaling relations[J]. 中国化学工程学报, 2022, 41(1): 22-28.
[15]	Jipeng Li, Huan Xu, Jingqi Wang, Yujun Wang, Diannan Lu, Jichang Liu, Jianzhong Wu. Theoretical insights on the hydration of quinones as catholytes in aqueous redox flow batteries[J]. 中国化学工程学报, 2021, 37(9): 72-78.