Simultaneous CO2 capture and thermochemical heat storage by modified carbide slag in coupled calcium looping and CaO/Ca(OH)2 cycles

doi:10.1016/j.cjche.2020.09.026

中国化学工程学报 ›› 2021, Vol. 36 ›› Issue (8): 76-85.DOI: 10.1016/j.cjche.2020.09.026

• Separation Science and Engineering • 上一篇下一篇

Simultaneous CO₂ capture and thermochemical heat storage by modified carbide slag in coupled calcium looping and CaO/Ca(OH)₂ cycles

Chunxiao Zhang¹, Yingjie Li¹, Zhiguo Bian¹, Wan Zhang¹, Zeyan Wang²

1 School of Energy and Power Engineering, Shandong University, Jinan 250061, China;
2 State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China

收稿日期:2020-08-17 修回日期:2020-09-22 出版日期:2021-08-28 发布日期:2021-09-30
通讯作者: Yingjie Li
基金资助:
This work was supported by the National Natural Science Foundation of China (51876105), and the Fundamental Research Funds of Shandong University (2018JC039).

Simultaneous CO₂ capture and thermochemical heat storage by modified carbide slag in coupled calcium looping and CaO/Ca(OH)₂ cycles

Chunxiao Zhang¹, Yingjie Li¹, Zhiguo Bian¹, Wan Zhang¹, Zeyan Wang²

1 School of Energy and Power Engineering, Shandong University, Jinan 250061, China;
2 State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China

Received:2020-08-17 Revised:2020-09-22 Online:2021-08-28 Published:2021-09-30
Contact: Yingjie Li
Supported by:
This work was supported by the National Natural Science Foundation of China (51876105), and the Fundamental Research Funds of Shandong University (2018JC039).

摘要/Abstract

摘要： The simultaneous CO₂ capture and heat storage performances of the modified carbide slag with by-product of biodiesel were investigated in the process coupled calcium looping and CaO/Ca(OH)₂ thermochemical heat storage using air as the heat transfer fluid. The modified carbide slag with by-product of biodiesel exhibits superior CO₂ capture and heat storage capacities in the coupled calcium looping and heat storage cycles. The hydration conversion and heat storage density of the modified carbide slag after 30 heat storage cycles are 0.65 mol·mol^-1 and 1.14 GJ·t^-1, respectively, which are 1.6 times as high as those of calcined carbide slag. The negative effect of CO₂ in air as the heat storage fluid on the heat storage capacity of the modified carbide slag is overcome by introducing CO₂ capture cycles. In addition, the CO₂ capture reactivity of the modified carbide slag after the multiple calcium looping cycles is enhanced by the introduction of heat storage cycles. By introducing 10 heat storage cycles after the 10th and 15th CO₂ capture cycles, the CO₂ capture capacities of the modified carbide slag are subsequently improved by 32% and 43%, respectively. The porous and loose structure of modified carbide slag reduces the diffusion resistances of CO₂ and steam in the material in the coupled process. The formed CaCO₃ in the modified carbide slag as a result of air as the heat transfer fluid in heat storage cycles decomposes to regenerate CaO in calcium looping cycles, which improves heat storage capacity. Therefore, the modified carbide slag with by-product of biodiesel seems promising in the coupled calcium looping and CaO/Ca(OH)₂ heat storage cycles.

关键词: Carbide slag, Calcium looping, CaO/Ca(OH)₂ heat storage, Modification, By-product of biodiesel, CO₂ capture

Abstract: The simultaneous CO₂ capture and heat storage performances of the modified carbide slag with by-product of biodiesel were investigated in the process coupled calcium looping and CaO/Ca(OH)₂ thermochemical heat storage using air as the heat transfer fluid. The modified carbide slag with by-product of biodiesel exhibits superior CO₂ capture and heat storage capacities in the coupled calcium looping and heat storage cycles. The hydration conversion and heat storage density of the modified carbide slag after 30 heat storage cycles are 0.65 mol·mol^-1 and 1.14 GJ·t^-1, respectively, which are 1.6 times as high as those of calcined carbide slag. The negative effect of CO₂ in air as the heat storage fluid on the heat storage capacity of the modified carbide slag is overcome by introducing CO₂ capture cycles. In addition, the CO₂ capture reactivity of the modified carbide slag after the multiple calcium looping cycles is enhanced by the introduction of heat storage cycles. By introducing 10 heat storage cycles after the 10th and 15th CO₂ capture cycles, the CO₂ capture capacities of the modified carbide slag are subsequently improved by 32% and 43%, respectively. The porous and loose structure of modified carbide slag reduces the diffusion resistances of CO₂ and steam in the material in the coupled process. The formed CaCO₃ in the modified carbide slag as a result of air as the heat transfer fluid in heat storage cycles decomposes to regenerate CaO in calcium looping cycles, which improves heat storage capacity. Therefore, the modified carbide slag with by-product of biodiesel seems promising in the coupled calcium looping and CaO/Ca(OH)₂ heat storage cycles.

Key words: Carbide slag, Calcium looping, CaO/Ca(OH)₂ heat storage, Modification, By-product of biodiesel, CO₂ capture

Chunxiao Zhang, Yingjie Li, Zhiguo Bian, Wan Zhang, Zeyan Wang. Simultaneous CO₂ capture and thermochemical heat storage by modified carbide slag in coupled calcium looping and CaO/Ca(OH)₂ cycles[J]. 中国化学工程学报, 2021, 36(8): 76-85.

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Simultaneous CO₂ capture and thermochemical heat storage by modified carbide slag in coupled calcium looping and CaO/Ca(OH)₂ cycles

Simultaneous CO₂ capture and thermochemical heat storage by modified carbide slag in coupled calcium looping and CaO/Ca(OH)₂ cycles

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