Low-temperature conversion of methane to oxygenates by supported metal catalysts: From nanoparticles to single atoms

doi:10.1016/j.cjche.2021.04.034

中国化学工程学报 ›› 2021, Vol. 38 ›› Issue (10): 18-29.DOI: 10.1016/j.cjche.2021.04.034

Low-temperature conversion of methane to oxygenates by supported metal catalysts: From nanoparticles to single atoms

Geqian Fang^1,2, Jian Lin¹, Xiaodong Wang¹

1. CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;
2. University of Chinese Academy of Sciences, Beijing 100049, China

收稿日期:2021-02-04 修回日期:2021-04-13 出版日期:2021-10-28 发布日期:2021-12-02
通讯作者: Jian Lin, Xiaodong Wang
基金资助:
This work was funded by National Natural Science Foundation of China (22022814, 21878283), Youth Innovation Promotion Association CAS (2017223), “Strategic Priority Research Program” of the Chinese academy of Sciences (XDB17020100), the National Key projects for Fundamental Research and Development of China (2016YFA0202801).

Low-temperature conversion of methane to oxygenates by supported metal catalysts: From nanoparticles to single atoms

Geqian Fang^1,2, Jian Lin¹, Xiaodong Wang¹

1. CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;
2. University of Chinese Academy of Sciences, Beijing 100049, China

Received:2021-02-04 Revised:2021-04-13 Online:2021-10-28 Published:2021-12-02
Contact: Jian Lin, Xiaodong Wang
Supported by:
This work was funded by National Natural Science Foundation of China (22022814, 21878283), Youth Innovation Promotion Association CAS (2017223), “Strategic Priority Research Program” of the Chinese academy of Sciences (XDB17020100), the National Key projects for Fundamental Research and Development of China (2016YFA0202801).

摘要/Abstract

摘要： Direct cost-effective conversion of abundant methane to high value-added oxygenates (methanol, formic acid, acetic acid, etc.) under mild conditions is prospective for optimizing the structure of energy resources. However, the CH bond of products is more reactive than that of high thermodynamic stable methane. Exploring an appropriate approach to eliminate the “seesaw effect” between methane conversion and oxygenate selectivity is significant. In this review, we briefly summarize the research progress in the past decade on low-temperature direct conversion of methane to oxygenates in gas-solid-liquid phase over various transition metal (Fe, Cu, Rh, Pd, AuPd, etc.) based nanoparticle or single-atom catalyst. Furthermore, the prospects of catalyst design and catalysis process are also discussed.

关键词: Methane, Oxygenates, Supported metal catalysts, Nanoparticle, Single-atom catalysts

Abstract: Direct cost-effective conversion of abundant methane to high value-added oxygenates (methanol, formic acid, acetic acid, etc.) under mild conditions is prospective for optimizing the structure of energy resources. However, the CH bond of products is more reactive than that of high thermodynamic stable methane. Exploring an appropriate approach to eliminate the “seesaw effect” between methane conversion and oxygenate selectivity is significant. In this review, we briefly summarize the research progress in the past decade on low-temperature direct conversion of methane to oxygenates in gas-solid-liquid phase over various transition metal (Fe, Cu, Rh, Pd, AuPd, etc.) based nanoparticle or single-atom catalyst. Furthermore, the prospects of catalyst design and catalysis process are also discussed.

Key words: Methane, Oxygenates, Supported metal catalysts, Nanoparticle, Single-atom catalysts

Geqian Fang, Jian Lin, Xiaodong Wang. Low-temperature conversion of methane to oxygenates by supported metal catalysts: From nanoparticles to single atoms[J]. 中国化学工程学报, 2021, 38(10): 18-29.

Geqian Fang, Jian Lin, Xiaodong Wang. Low-temperature conversion of methane to oxygenates by supported metal catalysts: From nanoparticles to single atoms[J]. Chinese Journal of Chemical Engineering, 2021, 38(10): 18-29.

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Low-temperature conversion of methane to oxygenates by supported metal catalysts: From nanoparticles to single atoms

Low-temperature conversion of methane to oxygenates by supported metal catalysts: From nanoparticles to single atoms

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