Engineering the efficient three-dimension hollow cubic carbon from vacuum residuum with enhanced mass transfer ability towards H2O2 production

doi:10.1016/j.cjche.2020.08.040

中国化学工程学报 ›› 2021, Vol. 38 ›› Issue (10): 98-105.DOI: 10.1016/j.cjche.2020.08.040

• Catalysis, Kinetics and Reaction Engineering • 上一篇下一篇

Engineering the efficient three-dimension hollow cubic carbon from vacuum residuum with enhanced mass transfer ability towards H₂O₂ production

Zhaohui Chen¹, Yasi Mo¹, Dong Lin¹, Yongxiao Tuo¹, Xiang Feng¹, Yibin Liu¹, Xiaobo Chen¹, De Chen², Chaohe Yang¹

1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao 266580, China;
2. Department of Chemical Engineering, Norwegian University of Science and Technology, Trondheim 7491, Norway

收稿日期:2020-06-29 修回日期:2020-08-14 出版日期:2021-10-28 发布日期:2021-12-02
通讯作者: Xiang Feng, Chaohe Yang
基金资助:
This work was supported by the National Natural Science Foundation of China (21978325).

Engineering the efficient three-dimension hollow cubic carbon from vacuum residuum with enhanced mass transfer ability towards H₂O₂ production

Zhaohui Chen¹, Yasi Mo¹, Dong Lin¹, Yongxiao Tuo¹, Xiang Feng¹, Yibin Liu¹, Xiaobo Chen¹, De Chen², Chaohe Yang¹

1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao 266580, China;
2. Department of Chemical Engineering, Norwegian University of Science and Technology, Trondheim 7491, Norway

Received:2020-06-29 Revised:2020-08-14 Online:2021-10-28 Published:2021-12-02
Contact: Xiang Feng, Chaohe Yang
Supported by:
This work was supported by the National Natural Science Foundation of China (21978325).

摘要/Abstract

摘要： Constructing efficient carbon material with enhanced mass transfer ability from vacuum residuum (VR) is of prime industrial and scientific significance. Herein, we demonstrated a one-pot synthesis of metal-free and highly symmetric hollow carbon cubes (HCCs) using cost-efficient vacuum residuum (VR) as a C/N/S source. By multi-techniques such as TEM, SEM, Raman, XPS, and XRD, it is found that the CTAB surfactant plays an important role in emulsifying and forming oil-in-water suspension particles. Subsequently, high aromatics contents in VR favor the formation of HCCs shell by graphitization on the surface of NaCl template. Notably, heavy metals (e.g., V, Ni) are not enriched in carbon skeleton due to the unique graphitization mechanism. This metal-free HCCs catalyst showed good catalytic stability and high selectivity towards direct and local electrochemical production of hydrogen peroxide (H₂O₂) through two-electron O₂ reduction due to enhanced mass transfer ability. The results provide a novel avenue to synthesize metal-free cubic carbon material from low-cost and plentiful VR, which are essential to the design of more efficient catalysts for O₂ reduction to H₂O₂.

关键词: Electrochemistry, Hydrogen peroxide, Hollow carbon cube, Vacuum residuum, Catalyst, Selectivity

Abstract: Constructing efficient carbon material with enhanced mass transfer ability from vacuum residuum (VR) is of prime industrial and scientific significance. Herein, we demonstrated a one-pot synthesis of metal-free and highly symmetric hollow carbon cubes (HCCs) using cost-efficient vacuum residuum (VR) as a C/N/S source. By multi-techniques such as TEM, SEM, Raman, XPS, and XRD, it is found that the CTAB surfactant plays an important role in emulsifying and forming oil-in-water suspension particles. Subsequently, high aromatics contents in VR favor the formation of HCCs shell by graphitization on the surface of NaCl template. Notably, heavy metals (e.g., V, Ni) are not enriched in carbon skeleton due to the unique graphitization mechanism. This metal-free HCCs catalyst showed good catalytic stability and high selectivity towards direct and local electrochemical production of hydrogen peroxide (H₂O₂) through two-electron O₂ reduction due to enhanced mass transfer ability. The results provide a novel avenue to synthesize metal-free cubic carbon material from low-cost and plentiful VR, which are essential to the design of more efficient catalysts for O₂ reduction to H₂O₂.

Key words: Electrochemistry, Hydrogen peroxide, Hollow carbon cube, Vacuum residuum, Catalyst, Selectivity

Zhaohui Chen, Yasi Mo, Dong Lin, Yongxiao Tuo, Xiang Feng, Yibin Liu, Xiaobo Chen, De Chen, Chaohe Yang. Engineering the efficient three-dimension hollow cubic carbon from vacuum residuum with enhanced mass transfer ability towards H₂O₂ production[J]. 中国化学工程学报, 2021, 38(10): 98-105.

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Engineering the efficient three-dimension hollow cubic carbon from vacuum residuum with enhanced mass transfer ability towards H₂O₂ production

Engineering the efficient three-dimension hollow cubic carbon from vacuum residuum with enhanced mass transfer ability towards H₂O₂ production

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