Solubility of CO2 in nonaqueous system of 2-(butylamino)ethanol with 2-butoxyethanol: Experimental data and model representation

doi:10.1016/j.cjche.2021.11.003

中国化学工程学报 ›› 2022, Vol. 41 ›› Issue (1): 441-448.DOI: 10.1016/j.cjche.2021.11.003

• Chemical Engineering Thermodynamics • 上一篇下一篇

Solubility of CO₂ in nonaqueous system of 2-(butylamino)ethanol with 2-butoxyethanol: Experimental data and model representation

Yu Dong, Tiantian Ping, Shufeng Shen

School of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China

收稿日期:2021-06-29 修回日期:2021-11-03 出版日期:2022-01-28 发布日期:2022-02-25
通讯作者: Shufeng Shen,E-mail address:sfshen@hebust.edu.cn
基金资助:
This work was supported by Natural Science Foundation of Hebei Province (B2018208154), Department of Education of Hebei Province, P.R. China (SLRC2019051) and Key Foundation of Hebei Provincial Department of Science and Technology, P.R. China (21373703D).

Solubility of CO₂ in nonaqueous system of 2-(butylamino)ethanol with 2-butoxyethanol: Experimental data and model representation

Yu Dong, Tiantian Ping, Shufeng Shen

School of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China

Received:2021-06-29 Revised:2021-11-03 Online:2022-01-28 Published:2022-02-25
Contact: Shufeng Shen,E-mail address:sfshen@hebust.edu.cn
Supported by:
This work was supported by Natural Science Foundation of Hebei Province (B2018208154), Department of Education of Hebei Province, P.R. China (SLRC2019051) and Key Foundation of Hebei Provincial Department of Science and Technology, P.R. China (21373703D).

摘要/Abstract

摘要： Nonaqueous amine-based system is an attractive solution to overcome high-energy-intensive CO₂ capture process using the conventional aqueous amines. Advanced nonaqueous absorbent of 2- (butylamino)ethanol (BAE) with 2-butoxyethanol (2-BE) has been recently proposed for low-energyconsumption CO₂ capture. In this work, Henry’s law constants of CO₂ in the BAE/2-BE blend were obtained by N₂O/CO₂ analogy, and correlated in the temperature range of (283–333) K. Vapor-liquid equilibrium (VLE) data for the BAE + CO₂ + 2-BE system at 65.4% (mass) BAE were also determined in a stirred equilibrium cell at temperatures of (313–393) K and CO₂ partial pressures up to 275 kPa. A single apparent equilibrium constant K_{CO_2,app} was proposed for this system and correlated as a function of temperature, carbonated degree of amine and CO₂ loading. Solubility data were well represented by the modified Kent-Eisenberg model with an average absolute relative deviation (AARD) of 13%.

关键词: Solubility, CO₂ capture, Nonaqueous absorbent, 2-(Butylamino)ethanol, 2-Butoxyethanol, Model

Abstract: Nonaqueous amine-based system is an attractive solution to overcome high-energy-intensive CO₂ capture process using the conventional aqueous amines. Advanced nonaqueous absorbent of 2- (butylamino)ethanol (BAE) with 2-butoxyethanol (2-BE) has been recently proposed for low-energyconsumption CO₂ capture. In this work, Henry’s law constants of CO₂ in the BAE/2-BE blend were obtained by N₂O/CO₂ analogy, and correlated in the temperature range of (283–333) K. Vapor-liquid equilibrium (VLE) data for the BAE + CO₂ + 2-BE system at 65.4% (mass) BAE were also determined in a stirred equilibrium cell at temperatures of (313–393) K and CO₂ partial pressures up to 275 kPa. A single apparent equilibrium constant K_{CO_2,app} was proposed for this system and correlated as a function of temperature, carbonated degree of amine and CO₂ loading. Solubility data were well represented by the modified Kent-Eisenberg model with an average absolute relative deviation (AARD) of 13%.

Key words: Solubility, CO₂ capture, Nonaqueous absorbent, 2-(Butylamino)ethanol, 2-Butoxyethanol, Model

Yu Dong, Tiantian Ping, Shufeng Shen. Solubility of CO₂ in nonaqueous system of 2-(butylamino)ethanol with 2-butoxyethanol: Experimental data and model representation[J]. 中国化学工程学报, 2022, 41(1): 441-448.

参考文献

[1] M.X. Fang, N.T. Yi, W.T. Di, T. Wang, Q.H. Wang, Emission and control of flue gas pollutants in CO₂ chemical absorption system-a review, Int. J. Greenh. Gas Control. 93(2020) 102904.
[2] K.A. Mumford, Y. Wu, K.H. Smith, G.W. Stevens, Review of solvent based carbon-dioxide capture technologies, Front. Chem. Sci. Eng. 9(2) (2015) 125–141.
[3] F. Vega, F.M. Baena-Moreno, L.M. Gallego Fernández, E. Portillo, B. Navarrete, Z. E. Zhang, Current status of CO₂ chemical absorption research applied to CCS: Towards full deployment at industrial scale, Appl. Energy 260(2020) 114313.
[4] T.N. Borhani, M.H. Wang, Role of solvents in CO₂ capture processes: The review of selection and design methods, Renew. Sustain. Energy Rev. 114(2019) 109299.
[5] J.G. Vitillo, B. Smit, L. Gagliardi, Introduction: Carbon capture and separation, Chem Rev 117(14) (2017) 9521–9523.
[6] W.M. Budzianowski, Explorative analysis of advanced solvent processes for energy efficient carbon dioxide capture by gas-liquid absorption, Int. J. Greenh. Gas Control. 49(2016) 108–120.
[7] D.J. Heldebrant, P.K. Koech, V.A. Glezakou, R. Rousseau, D. Malhotra, D.C. Cantu, Water-lean solvents for post-combustion CO₂ capture: Fundamentals, uncertainties, opportunities, and outlook, Chem. Rev. 117(14) (2017) 9594–9624.
[8] C.X. Li, X.Q. Shi, S.F. Shen, Performance evaluation of newly developed absorbents for solvent-based carbon dioxide capture, Energy Fuels 33(9) (2019) 9032–9039.
[9] F. Barzagli, C. Giorgi, F. Mani, M. Peruzzini, Comparative study of CO₂ capture by aqueous and nonaqueous 2-amino-2-methyl-1-propanol based absorbents carried out by ¹³C NMR and enthalpy analysis, Ind. Eng. Chem. Res. 58(2019) 4364–4373.
[10] H. Guo, C.X. Li, X.Q. Shi, H. Li, S.F. Shen, Nonaqueous amine-based absorbents for energy efficient CO₂ capture, Appl. Energy 239(2019) 725–734.
[11] H. Li, H. Guo, S.F. Shen, Low-energy-consumption CO₂ capture by liquid–solid phase change absorption using water-lean blends of amino acid salts and 2-alkoxyethanols, ACS Sustainable Chem. Eng. 8(34) (2020) 12956–12967.
[12] I.I.I. Alkhatib, L.M.C. Pereira, A. AlHajaj, L.F. Vega, Performance of non-aqueous amine hybrid solvents mixtures for CO₂ capture: A study using a molecularbased model, J. CO₂ Util. 35(2020) 126–144.
[13] T. Ping, Y. Dong, S. Shen, Energy-efficient CO₂ capture using nonaqueous absorbents of secondary alkanolamines with a 2-butoxyethanol cosolvent, ACS Sustain. Chem. Eng. 8(2020) 18071–18082.
[14] D.R. Lide, CRC Handbook of Chemistry and Physics, 90th ed., (CD-ROM, version 2010), CRC Press, Boca Raton (FL), 2010.
[15] Environmental Protection Agency (EPA), Petition to delist of ethylene glycol monobutyl ether, Fed. Reg. 69(2004) 69320–69325.
[16] Y.Y. Bian, S.F. Shen, CO₂ absorption into a phase change absorbent: Water-lean potassium prolinate/ethanol solution, Chin. J. Chem. Eng. 26(11) (2018) 2318–2326.
[17] H. Li, S. Shen, Kinetics of carbon dioxide absorption into water-lean potassium prolinate/ethylene glycol solutions, Ind. Eng. Chem. Res. 58(2019) 9875–9882.
[18] S.S. Laddha, J.M. Diaz, P.V. Danckwerts, The N₂O analogy: The solubilities of CO₂ and N₂O in aqueous solutions of organic compounds, Chem. Eng. Sci. 36(1) (1981) 228–229.
[19] M. Xiao, H.L. Liu, J.L. Wang, X. Luo, H.X. Gao, Z.W. Liang, An experimental and modeling study of physical N₂O solubility in 2-(ethylamino)ethanol, J. Chem. Thermodyn. 138(2019) 34–42.
[20] H. Li, H. Guo, Y.Y. Bian, Y. Zhao, S.F. Shen, Measurements and correlations of solubility of N₂O in and density, viscosity of partially CO₂ loaded water-lean amino acid salts, J. Chem. Thermodyn. 126(2018) 82–90.
[21] H. Guo, X.Q. Shi, S.F. Shen, Solubility of N₂O and CO₂ in non-aqueous systems of monoethanolamine and glycol ethers: Measurements and model representation, J. Chem. Thermodyn. 137(2019) 76–85.
[22] R.L. Kent, B. Eisenberg, Better data for amine treating, Hydrocarb. Process 55(1976) 87–90.
[23] S.F. Shen, Y. Zhao, Y.Y. Bian, Y. Wang, H. Guo, H. Li, CO₂ absorption using aqueous potassium lysinate solutions: Vapor-liquid equilibrium data and modelling, J. Chem. Thermodyn. 115(2017) 209–220.
[24] Y. Bian, S. Shen, Y. Zhao, Y. Yang, Physicochemical properties of aqueous potassium salts of basic amino acids as absorbents for CO₂ capture, J. Chem. Eng. Data 61(2016) 2391–2398.
[25] C. Zheng, B.C. Zhao, K. Wang, G.S. Luo, Determination of kinetics of CO₂ absorption in solutions of 2-amino-2-methyl-1-propanol using a microfluidic technique, AIChE J. 61(12) (2015) 4358–4366.
[26] C. Guo, S.Y. Chen, Y.C. Zhang, G.B. Wang, Solubility of CO₂ in nonaqueous absorption system of 2-(2-aminoethylamine)ethanol + benzyl alcohol, J. Chem. Eng. Data 59(6) (2014) 1796–1801.
[27] G.F. Versteeg, W.P.M. van Swaaij, Solubility and diffusivity of acid gases (carbon dioxide, nitrous oxide) in aqueous alkanolamine solutions, J. Chem. Eng. Data 33(1) (1988) 29–34.
[28] X.Q. Shi, S.F. Shen, Solubility of N₂O and CO₂ in nonaqueous blends of 2-(methylamino)ethanol and 2-methoxyethanol, J. Mol. Liq. 342(2021) 117448.
[29] T.T. Ping, Y. Dong, S.F. Shen, Densities, viscosities and spectroscopic study of partially CO₂-loaded nonaqueous blends of 2-butoxyethanol with 2-(ethylamino)ethanol and 2-(butylamino)ethanol at temperatures of (293.15 to 353.15) K, J. Mol. Liq. 312(2020) 113389.
[30] X. Luo, L. Su, H. Gao, X. Wu, R.O. Idem, P. Tontiwachwuthikul, Z. Liang, Density, viscosity, and N₂O solubility of aqueous 2-(methylamino)ethanol solution, J. Chem. Eng. Data 62(2017) 129–140.
[31] J.I. Lee, F.D. Otto, A.E. Mather, Equilibrium between carbon dioxide and aqueous monoethanolamine solutions, J. Appl. Chem. 26(1) (2007) 541–549.
[32] K.P. Shen, M.H. Li, Solubility of carbon dioxide in aqueous mixtures of monoethanolamine with methyldiethanolamine, J. Chem. Eng. Data 37(1) (1992) 96–100.
[33] U.E. Aronu, S. Gondal, E.T. Hessen, T. Haug-Warberg, A. Hartono, K.A. Hoff, H.F. Svendsen, Solubility of CO₂ in 15, 30, 45 and 60 mass% MEA from 40 to 120℃ and model representation using the extended UNIQUAC framework, Chem. Eng. Sci. 66(24) (2011) 6393–6406.
[34] H. Guo, L. Hui, S.F. Shen, Monoethanolamine+2-methoxyethanol mixtures for CO₂ capture: Density, viscosity and CO₂ solubility, J. Chem. Thermodyn. 132(2019) 155–163.
[35] C. Wohlfarth, Static dielectric constants of pure liquids and binary liquid mixtures, Springer Berlin Heidelberg, Berlin, Heidelberg, 2015.
[36] Y. Dong, T.T. Ping, X.Q. Shi, S.F. Shen, Density, viscosity and excess properties for binary mixtures of 2-(ethylamino)ethanol and 2-(butylamino)ethanol with 2-butoxyethanol at temperatures from (293.15 to 353.15) K, J. Mol. Liq. 312(2020) 113351.

Solubility of CO₂ in nonaqueous system of 2-(butylamino)ethanol with 2-butoxyethanol: Experimental data and model representation

Solubility of CO₂ in nonaqueous system of 2-(butylamino)ethanol with 2-butoxyethanol: Experimental data and model representation

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