Additive manufacturing of sodalite monolith for continuous heavy metal removal from water sources

doi:10.1016/j.cjche.2021.12.016

中国化学工程学报 ›› 2022, Vol. 42 ›› Issue (2): 82-90.DOI: 10.1016/j.cjche.2021.12.016

• Recent Advances in Adsorptive Separation Materials and Technologies • 上一篇下一篇

Additive manufacturing of sodalite monolith for continuous heavy metal removal from water sources

Hengyu Shen^1,2, Run Zou^1,3, Yangtao Zhou¹, Xing Guo⁴, Yanan Guan^1,2, Duo Na^1,2, Jinsong Zhang¹, Xiaolei Fan³, Yilai Jiao¹

1. Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China;
2. School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China;
3. Department of Chemical Engineering, The University of Manchester, Oxford Road, Manchester M139PL, United Kingdom;
4. Science and Technology on Vacuum Technology and Physics Laboratory, Lanzhou Institute of Physics, Lanzhou 730010, China

收稿日期:2021-06-22 修回日期:2021-12-21 出版日期:2022-02-28 发布日期:2022-03-30
通讯作者: Jinsong Zhang,E-mail:jshzhang@imr.ac.cn;Xiaolei Fan,E-mail:xiaolei.fan@manchester.ac.uk;Yilai Jiao,E-mail:yljiao@imr.ac.cn
基金资助:
We acknowledge the Key Project on Intergovernmental International Science, Technology and Innovation (STI) Cooperation/STI Cooperation with Hong Kong, Macao and Taiwan of China’s National Key Research & Development Programme (2019YFE0123200), the National Natural Science Foundation of China (22078348). This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement (No. 872102).

Additive manufacturing of sodalite monolith for continuous heavy metal removal from water sources

Hengyu Shen^1,2, Run Zou^1,3, Yangtao Zhou¹, Xing Guo⁴, Yanan Guan^1,2, Duo Na^1,2, Jinsong Zhang¹, Xiaolei Fan³, Yilai Jiao¹

1. Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China;
2. School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China;
3. Department of Chemical Engineering, The University of Manchester, Oxford Road, Manchester M139PL, United Kingdom;
4. Science and Technology on Vacuum Technology and Physics Laboratory, Lanzhou Institute of Physics, Lanzhou 730010, China

Received:2021-06-22 Revised:2021-12-21 Online:2022-02-28 Published:2022-03-30
Contact: Jinsong Zhang,E-mail:jshzhang@imr.ac.cn;Xiaolei Fan,E-mail:xiaolei.fan@manchester.ac.uk;Yilai Jiao,E-mail:yljiao@imr.ac.cn
Supported by:
We acknowledge the Key Project on Intergovernmental International Science, Technology and Innovation (STI) Cooperation/STI Cooperation with Hong Kong, Macao and Taiwan of China’s National Key Research & Development Programme (2019YFE0123200), the National Natural Science Foundation of China (22078348). This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement (No. 872102).

摘要/Abstract

摘要： Herein, we present a simple strategy for preparing monolithic sodalite adsorbents via sequential additive manufacturing and post-treatments. In detail, the method includes (i) 3D printing of cylindrical monoliths using clay as the base material; (ii) thermal activation of the 3D-printed clay monoliths by calcination (to produce reactive alumina and silica species and enable mechanical stabilization); (iii) conversion of the activated clay monoliths to hierarchical porous sodalite monoliths via hydrothermal alkaline treatment. Parametric studies on the effect of calcination temperature, alkaline concentration and hydrothermal treatment time on the property of the resulting materials (such as phase composition and morphology) at different stages of preparation was conducted. Under the optimal conditions (i.e., calcination temperature of 850℃, NaOH concentration of 3.3 mol·L^-1, reaction temperature of 150℃, and reaction time of 6 h), a high-quality pure sodalite monolith was obtained, which possesses a relatively high BET surface area (58 m²·g^-1) and hierarchically micro-meso-macroporous structure. In the proposed application of continuous removal of heavy metals (chromium ion as the model) from wastewater, the developed 3D-printed sodalite monolith showed excellent Cr³⁺ removal performance and fast kinetics (~98% removal efficiency within 25 cycles), which outperformed the packed bed using sodalite pellets (made by extrusion).

关键词: Additive manufacturing, Clay, Sodalite monolith, Heavy metal removal

Abstract: Herein, we present a simple strategy for preparing monolithic sodalite adsorbents via sequential additive manufacturing and post-treatments. In detail, the method includes (i) 3D printing of cylindrical monoliths using clay as the base material; (ii) thermal activation of the 3D-printed clay monoliths by calcination (to produce reactive alumina and silica species and enable mechanical stabilization); (iii) conversion of the activated clay monoliths to hierarchical porous sodalite monoliths via hydrothermal alkaline treatment. Parametric studies on the effect of calcination temperature, alkaline concentration and hydrothermal treatment time on the property of the resulting materials (such as phase composition and morphology) at different stages of preparation was conducted. Under the optimal conditions (i.e., calcination temperature of 850℃, NaOH concentration of 3.3 mol·L^-1, reaction temperature of 150℃, and reaction time of 6 h), a high-quality pure sodalite monolith was obtained, which possesses a relatively high BET surface area (58 m²·g^-1) and hierarchically micro-meso-macroporous structure. In the proposed application of continuous removal of heavy metals (chromium ion as the model) from wastewater, the developed 3D-printed sodalite monolith showed excellent Cr³⁺ removal performance and fast kinetics (~98% removal efficiency within 25 cycles), which outperformed the packed bed using sodalite pellets (made by extrusion).

Key words: Additive manufacturing, Clay, Sodalite monolith, Heavy metal removal

Hengyu Shen, Run Zou, Yangtao Zhou, Xing Guo, Yanan Guan, Duo Na, Jinsong Zhang, Xiaolei Fan, Yilai Jiao. Additive manufacturing of sodalite monolith for continuous heavy metal removal from water sources[J]. 中国化学工程学报, 2022, 42(2): 82-90.

参考文献

[1] H. Ali, E. Khan, I. Ilahi, Environmental chemistry and ecotoxicology of hazardous heavy metals:environmental persistence, toxicity, and bioaccumulation, J. Chem. 2019 (2019) 1-14
[2] H. Patel, Batch and continuous fixed bed adsorption of heavy metals removal using activated charcoal from neem (Azadirachta indica) leaf powder, Sci Rep 10 (1) (2020) 16895
[3] G.A. Ozin, A. Kuperman, A. Stein, Advanced zeolite, materials science, Angew. Chem. Int. Ed. Engl. 28 (3) (1989) 359-376
[4] K. Ojha, N.C. Pradhan, A.N. Samanta, Zeolite from fly ash:synthesis and characterization, Bull. Mater. Sci. 27 (6) (2004) 555-564
[5] V. van Speybroeck, K. Hemelsoet, L. Joos, M. Waroquier, R.G. Bell, C.R. Catlow, Advances in theory and their application within the field of zeolite chemistry, Chem Soc Rev 44 (20) (2015) 7044-7111
[6] Y.L. Jiao, L. Forster, S.J. Xu, H.H. Chen, J.F. Han, X.Q. Liu, Y.T. Zhou, J.M. Liu, J.S. Zhang, J.H. Yu, C. D'Agostino, X.L. Fan, Creation of Al-enriched mesoporous ZSM-5 nanoboxes with high catalytic activity:converting tetrahedral extra-framework Al into framework sites by post treatment, Angew Chem Int Ed Engl 59 (44) (2020) 19478-19486
[7] Y.L. Jiao, A.L. Adedigba, N.F. Dummer, J.M. Liu, Y.T. Zhou, Y.N. Guan, H.Y. Shen, M. Perdjon, G.J. Hutchings, The effect of T-atom ratio and TPAOH concentration on the pore structure and titanium position in MFI-Type titanosilicate during dissolution-recrystallization process, Microporous Mesoporous Mater. 305 (2020) 110397
[8] Y.N. Zhao, Review of the natural, modified, and synthetic zeolites for heavy metals removal from wastewater, Environ. Eng. Sci. 33 (7) (2016) 443-454
[9] E. Erdem, N. Karapinar, R. Donat, The removal of heavy metal cations by natural zeolites, J. Colloid Interface Sci. 280 (2) (2004) 309-314
[10] Y. Taamneh, S. Sharadqah, The removal of heavy metals from aqueous solution using natural Jordanian zeolite, Appl. Water Sci. 7 (4) (2017) 2021-2028
[11] S. Guida, C. Potter, B. Jefferson, A. Soares, Preparation and evaluation of zeolites for ammonium removal from municipal wastewater through ion exchange process, Sci Rep 10 (1) (2020) 12426
[12] E. Kendrick, S. Dann, Erratum to "Synthesis, properties and structure of ion exchanged hydrosodalite, J. Solid State Chem. 178 (6) (2005) 2176
[13] S. Golbad, P. Khoshnoud, N. Abu-Zahra, Hydrothermal synthesis of hydroxy sodalite from fly ash for the removal of lead ions from water, Int. J. Environ. Sci. Technol. 14 (1) (2017) 135-142
[14] S.M. Kamyab, S. Modabberi, C.D. Williams, A. Badiei, Synthesis of sodalite from sepiolite by alkali fusion method and its application to remove Fe³⁺, Cr³⁺, and Cd²⁺ from aqueous solutions, Environ. Eng. Sci. 37 (10) (2020) 689-701
[15] A.Á.B. Maia, R.F. Neves, R.S. Angélica, H. Pöllmann, Synthesis of sodalite from Brazilian Kaolin wastes, Clay Miner. 50 (5) (2015) 663-675
[16] X.Y. Li, Y. Jiang, X.Q. Liu, L.Y. Shi, D.Y. Zhang, L.B. Sun, Direct synthesis of zeolites from a natural clay, attapulgite, ACS Sustain. Chem. Eng. 5 (7) (2017) 6124-6130
[17] E.B. Drag, A. Miecznikowski, F. Abo-Lemon, M. Rutkowski, Synthesis of A, X and Y zeolites from clay minerals, Stud. Surf. Sci. Catal. 24 (1985) 147-154
[18] O. Eterigho-Ikelegbe, S. Bada, M.O. Daramola, R. Falcon, Synthesis of high purity hydroxy sodalite nanoparticles via pore-plugging hydrothermal method for inorganic membrane development:Effect of synthesis variables on crystallinity, crystal size and morphology, Mater. Today:Proc. 38 (2021) 675-681
[19] V.J. Inglezakis, H. Grigoropoulou, Effects of operating conditions on the removal of heavy metals by zeolite in fixed bed reactors, J Hazard Mater 112 (1-2) (2004) 37-43
[20] S. Mohan, G. Sreelakshmi, Fixed bed column study for heavy metal removal using phosphate treated rice husk, J Hazard Mater 153 (1-2) (2008) 75-82
[21] H. Yu, J. Shen, J. Li, X. Sun, W. Han, X. Liu, L. Wang, Preparation, characterization and adsorption properties of sodalite pellets, Mater. Lett. 132 (2014) 259-262
[22] X.X. Ou, F. Pilitsis, N.H. Xu, S.F.R. Taylor, J. Warren, A. Garforth, J.S. Zhang, C. Hardacre, Y.L. Jiao, X.L. Fan, On developing ferrisilicate catalysts supported on silicon carbide (SiC) foam catalysts for continuous catalytic wet peroxide oxidation (CWPO) reactions, Catal. Today 356 (2020) 631-640
[23] Y.L. Jiao, X.X. Ou, J.S. Zhang, X.L. Fan, Structured ZSM-5 coated SiC foam catalysts for process intensification in catalytic cracking of n-hexane, React. Chem. Eng. 4 (2) (2019) 427-435
[24] X.X. Ou, F. Pilitsis, Y.L. Jiao, Y. Zhang, S.J. Xu, M. Jennings, Y. Yang, S.F.R. Taylor, A. Garforth, H.P. Zhang, C. Hardacre, Y. Yan, X.L. Fan, Hierarchical Fe-ZSM-5/SiC foam catalyst as the foam bed catalytic reactor (FBCR) for catalytic wet peroxide oxidation (CWPO), Chem. Eng. J. 362 (2019) 53-62
[25] P. Yan, X.G. Li, H. Li, X. Gao, Hydrodynamics and flow mechanism of foam column Trays:Contact angle effect, Chem. Eng. Sci. 176 (2018) 220-232
[26] M.J. Regufe, A.F.P. Ferreira, J.M. Loureiro, A. Rodrigues, A.M. Ribeiro, Electrical conductive 3D-printed monolith adsorbent for CO₂ capture, Microporous Mesoporous Mater. 278 (2019) 403-413
[27] Z. Zhao, H. Li, X. Li, A.N. Pavlenko, X. Gao, Flow pattern of miscellaneous liquids with varied flow rates on structured corrugation SiC foam packing, J. Eng. Thermophys. 28 (3) (2019) 305-312
[28] H. Li, Z.Q. Hao, J. Murphy, X.G. Li, X. Gao, Experimental study of liquid renewal on the sheet of structured corrugation SiC foam packing and its dispersion coefficients, Chem. Eng. Sci. 180 (2018) 11-19
[29] H.H. Chen, Y. Shao, Y.B. Mu, H. Xiang, R.X. Zhang, Y.B. Chang, C. Hardacre, C. Wattanakit, Y.L. Jiao, X.L. Fan, Structured silicalite-1 encapsulated Ni catalyst supported on SiC foam for dry reforming of methane, AIChE J. 67(4) (2020) e17126
[30] R.X. Zhang, H.H. Chen, Y.B. Mu, S. Chansai, X.X. Ou, C. Hardacre, Y.L. Jiao, X.L. Fan, Structured Ni@NaA zeolite supported on silicon carbide foam catalysts for catalytic carbon dioxide methanation, AIChE J. 66(11) (2020) e17007
[31] X. Gao, Q.Y. Ding, Y. Wu, Y.L. Jiao, J.S. Zhang, X.G. Li, H. Li, Kinetic study of esterification over structured ZSM-5-coated catalysts based on fluid flow situations in macrocellular foam materials, React. Chem. Eng. 5 (3) (2020) 485-494
[32] P. Yan, X.G. Li, H. Li, Y.Y. Shao, H. Zhang, X. Gao, Hydrodynamics and mechanism of hydrophobic foam column tray:Contact angle hysteresis effect, AIChE J 66 (1) (2020) e16793
[33] C. Parra-Cabrera, C. Achille, S. Kuhn, R. Ameloot, 3D printing in chemical engineering and catalytic technology:structured catalysts, mixers and reactors, Chem Soc Rev 47 (1) (2018) 209-230
[34] S. Couck, J. Cousin-Saint-remi, S. van der Perre, G.V. Baron, C. Minas, P. Ruch, J.F.M. Denayer, 3D-printed SAPO-34 monoliths for gas separation, Microporous Mesoporous Mater. 255 (2018) 185-191
[35] F. Putz, S. Scherer, M. Ober, R. Morak, O. Paris, N. Hüsing, 3D printing of hierarchical porous silica and α-quartz, Adv. Mater. Technol. 3 (7) (2018) 1800060
[36] X. Li, A.A. Alwakwak, F. Rezaei, A.A. Rownaghi, Synthesis of cr, Cu, ni, and Y-doped 3D-printed ZSM-5 monoliths and their catalytic performance for n-hexane cracking, ACS Appl. Energy Mater. 1 (6) (2018) 2740-2748
[37] S. Lawson, A.A. Alwakwak, A.A. Rownaghi, F. Rezaei, Gel-print-grow:a new way of 3D printing metal-organic frameworks, ACS Appl Mater Interfaces 12 (50) (2020) 56108-56117
[38] D.X. Zhang, J.F. Xiao, Q.Q. Guo, J. Yang, 3D-printed highly porous and reusable chitosan monoliths for Cu(II) removal, J. Mater. Sci. 54 (8) (2019) 6728-6741
[39] H. Thakkar, S. Eastman, A. Hajari, A.A. Rownaghi, J.C. Knox, F. Rezaei, 3D-printed zeolite monoliths for CO₂ removal from enclosed environments, ACS Appl Mater Interfaces 8 (41) (2016) 27753-27761
[40] S. Wang, P. Bai, M.Z. Sun, W. Liu, D.D. Li, W.Z. Wu, W.F. Yan, J. Shang, J.H. Yu, Fabricating mechanically robust binder-free structured zeolites by 3D printing coupled with zeolite soldering:a superior configuration for CO₂ capture, Adv. Sci. 6 (17) (2019) 1901317
[41] G.J.H. Lim, Y. Wu, B.B. Shah, J.J. Koh, C.K. Liu, D. Zhao, A.K. Cheetham, J. Wang, J. Ding, 3D-printing of pure metal-organic framework monoliths, ACS Mater. Lett. 1 (1) (2019) 147-153
[42] P. Aprea, D. Caputo, N. Gargiulo, B. Gennaro, F. Iucolano, B. Liguori, C. Colella, Ion exchange kinetics and thermodynamics of hydrosodalite, a narrow pore zeolite, J. Porous Mater. 21 (5) (2014) 643-651
[43] R.C. Andrades, R.F. Neves, F.R.V. Díaz, A.H.M. Júnior, Influence of alkalinity on the synthesis of zeolite A and hydroxysodalite from metakaolin, J. Nano Res. 61 (2020) 51-60
[44] E.B.G. Johnson, S.E. Arshad, Hydrothermally synthesized zeolites based on kaolinite:a review, Appl. Clay Sci. 97-98 (2014) 215-221
[45] G. Kakali, T. Perraki, S. Tsivilis, E. Badogiannis, Thermal treatment of kaolin:the effect of mineralogy on the pozzolanic activity, Appl. Clay Sci. 20 (1-2) (2001) 73-80
[46] R.M. Barrer, Hydrothermal Chemistry of Zeolites, Academic Press, New York, 1982
[47] V. Berkgaut, A. Singer, High capacity cation exchanger by hydrothermal zeolitization of coal fly ash, Appl. Clay Sci. 10 (5) (1996) 369-378
[48] A. Michot, D.S. Smith, S. Degot, C. Gault, Thermal conductivity and specific heat of kaolinite:Evolution with thermal treatment, J. Eur. Ceram. Soc. 28 (14) (2008) 2639-2644
[49] S.O. Otieno, F.O. Kengara, J.C. Kemmegne-Mbouguen, H.W. Langmi, C.B.O. Kowenje, R. Mokaya, The effects of metakaolinization and fused-metakaolinization on zeolites synthesized from quartz rich natural clays, Microporous Mesoporous Mater. 290 (2019) 109668
[50] X.L. Fan, Y.L. Jiao, Porous materials for catalysis. Sustainable Nanoscale Engineering. Elsevier Amsterdam (2020) 115-137.
[51] C. Rosales-Landeros, C.E. Barrera-Díaz, B. Bilyeu, V.V. Guerrero, F.U. Núñez, A review on Cr(VI) adsorption using inorganic materials, Am. J. Anal. Chem. 4 (7) (2013) 8-16

Additive manufacturing of sodalite monolith for continuous heavy metal removal from water sources

Additive manufacturing of sodalite monolith for continuous heavy metal removal from water sources

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 9

编辑推荐

Metrics

本文评价

[1]	Shaimaa T. Kadhum, Ghayda Yassen Alkindi, Talib M. Albayati. Eco friendly adsorbents for removal of phenol from aqueous solution employing nanoparticle zero-valent iron synthesized from modified green tea bio-waste and supported on silty clay[J]. 中国化学工程学报, 2021, 36(8): 19-28.
[2]	Abdul Samad, Muhammad Imran Din, Mahmood Ahmed, Saghir Ahmad. Synthesis of zinc oxide nanoparticles reinforced clay and their applications for removal of Pb (II) ions from aqueous media[J]. 中国化学工程学报, 2021, 32(4): 454-461.
[3]	Islem Chaari, Atef Touil, Mounir Medhioub. Adsorption-desorption of phenolic compounds from olive mills wastewater using Tunisian natural clay[J]. 中国化学工程学报, 2021, 40(12): 287-292.
[4]	Zhaoru Fan, Shouyong Zhou, Ailian Xue, Meisheng Li, Yan Zhang, Yijiang Zhao, Weihong Xing. Preparation and properties of a low-cost porous ceramic support from low-grade palygorskite clay and silicon-carbide with vanadium pentoxide additives[J]. 中国化学工程学报, 2021, 29(1): 417-425.
[5]	Rui Shan, Yueyue Shi, Jing Gu, Yazhuo Wang, Haoran Yuan. Single and competitive adsorption affinity of heavy metals toward peanut shell-derived biochar and its mechanisms in aqueous systems[J]. 中国化学工程学报, 2020, 28(5): 1375-1383.
[6]	Abdul Samad, Muhammad Imran Din, Mahmood Ahmed. Studies on batch adsorptive removal of cadmium and nickel from synthetic waste water using silty clay originated from Balochistan- Pakistan[J]. 中国化学工程学报, 2020, 28(4): 1171-1176.
[7]	常菁, 仲兆祥, 徐虹, 姚忠, 陈日志. Fabrication of Poly(γ-glutamic acid)-coated Fe₃O₄ Magnetic Nanoparticles and Their Application in Heavy Metal Removal[J]. Chinese Journal of Chemical Engineering, 2013, 21(11): 1244-1250.
[8]	柯扬船. 一种新型聚对苯二甲酸丁二醇酯-层状硅酸盐纳米复合材料的制备与性能[J]. , 2003, 11(6): 701-708.
[9]	虞启明, Jose T.Matheickal, Jozef Latten. Heavy Metal Adsorption Properties of Marine Algae Durvilliea Potatorum, Ecklonia Radiata and Laminaria Japonica[J]. , 1998, 6(1): 68-72.