Supported catalytic packing prepared from ceramic packing for reactive distillation of ethyl acetate

doi:10.1016/j.cjche.2022.05.016

中国化学工程学报 ›› 2022, Vol. 50 ›› Issue (10): 205-214.DOI: 10.1016/j.cjche.2022.05.016

• Catalysis, Kinetics and Reaction Engineering • 上一篇下一篇

Supported catalytic packing prepared from ceramic packing for reactive distillation of ethyl acetate

Zhiwei Wang, Jiannan Shi, Xiaonan Liu, Zhikai Cao, Yong Sha

Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

收稿日期:2022-03-13 修回日期:2022-05-14 出版日期:2022-10-28 发布日期:2023-01-04
通讯作者: Yong Sha,E-mail:ysha@xmu.edu.cn
基金资助:
The authors acknowledge financial support provided by the National Natural Science Foundation of China (No. 21978243).

Supported catalytic packing prepared from ceramic packing for reactive distillation of ethyl acetate

Zhiwei Wang, Jiannan Shi, Xiaonan Liu, Zhikai Cao, Yong Sha

Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

Received:2022-03-13 Revised:2022-05-14 Online:2022-10-28 Published:2023-01-04
Contact: Yong Sha,E-mail:ysha@xmu.edu.cn
Supported by:
The authors acknowledge financial support provided by the National Natural Science Foundation of China (No. 21978243).

摘要/Abstract

摘要： In this work, a strategy of “etching-modification filling-graft copolymerization” was proposed to load the acidic ionic polyionic liquid on the smooth ceramic surface. In this way, commercial ceramic Raschig rings were successfully transformed into the supported catalytic packing for the reactive distillation, and were further evaluated with esterification reaction of ethyl acetate by means of the fully mixed reactor, the ultrasonic destruction, the cyclic catalysis reaction and the lab-scale distillation column experiment. This catalyst coating has good adhesion with the substrate. It can withstand 24 h of ultrasound damage and shows good stability in three cycle catalytic experiments. This kind of coated catalyst has better catalytic activity than the commercial Amberlyst 15 dry. In the lab-scale reaction distillation, the supported catalyst Raschig ring can achieve a higher conversion in comparison with the tea bag catalytic packing of Amberlyst 15 dry under some conditions.

关键词: Supported catalytic packing, Ethyl acetate, Reactive distillation, Bonding strength

Abstract: In this work, a strategy of “etching-modification filling-graft copolymerization” was proposed to load the acidic ionic polyionic liquid on the smooth ceramic surface. In this way, commercial ceramic Raschig rings were successfully transformed into the supported catalytic packing for the reactive distillation, and were further evaluated with esterification reaction of ethyl acetate by means of the fully mixed reactor, the ultrasonic destruction, the cyclic catalysis reaction and the lab-scale distillation column experiment. This catalyst coating has good adhesion with the substrate. It can withstand 24 h of ultrasound damage and shows good stability in three cycle catalytic experiments. This kind of coated catalyst has better catalytic activity than the commercial Amberlyst 15 dry. In the lab-scale reaction distillation, the supported catalyst Raschig ring can achieve a higher conversion in comparison with the tea bag catalytic packing of Amberlyst 15 dry under some conditions.

Key words: Supported catalytic packing, Ethyl acetate, Reactive distillation, Bonding strength

Zhiwei Wang, Jiannan Shi, Xiaonan Liu, Zhikai Cao, Yong Sha. Supported catalytic packing prepared from ceramic packing for reactive distillation of ethyl acetate[J]. 中国化学工程学报, 2022, 50(10): 205-214.

Zhiwei Wang, Jiannan Shi, Xiaonan Liu, Zhikai Cao, Yong Sha. Supported catalytic packing prepared from ceramic packing for reactive distillation of ethyl acetate[J]. Chinese Journal of Chemical Engineering, 2022, 50(10): 205-214.

参考文献

[1] X.G. Li, H. Zhang, X. Gao, R. Zhang, H. Li, Hydrodynamic simulations of seepage catalytic packing internal for catalytic distillation column, Ind. Eng. Chem. Res. 51 (43) (2012) 14236-14246
[2] Z.G. Lei, C.N. Dai, B.H. Chen, Z.W. Ding, Special Distillation Processes (Second Edition), Elsevier, Amsterdam, 2022
[3] P.W.A.M. Wenmakers, J. van der Schaaf, B.F.M. Kuster, J.C. Schouten, Liquid-solid mass transfer for cocurrent gas-liquid upflow through solid foam packings, AIChE J. 56 (11) (2010) 2923-2933
[4] T. Keller, Chapter 8-Reactive Distillation, in:Andrzej Górak, Žarko Olujić (Eds.), Distillation, Academic Press, Beijing, 2014, pp. 261-294.
[5] Q.L. Wang, F.Y. Zhang, R. Huang, X.D. Wang, C. Yang, H.X. Wang, T. Qiu, Multiphase flow and multicomponent reactive transport study in the catalyst layer of structured catalytic packings for the direct hydration of cyclohexene, Chem. Eng. Process. Process. Intensif. 158 (2020) 108199
[6] K. Sundmacher, U. Hoffmann, Multicomponent mass and energy transport on different length scales in a packed reactive distillation column for heterogeneously catalysed fuel ether production, Chem. Eng. Sci. 49 (24) (1994) 4443-4464
[7] Y.Y. Zhuo, Y.X. Zhong, Y.L. Xu, Y. Sha, Evaluation of transfer resistances in the reactive distillation process for phenol production, Ind. Eng. Chem. Res. 55 (1) (2016) 257-266
[8] T. Deng, Y.K. Li, G.F. Zhao, Z.Q. Zhang, Y. Liu, Y. Lu, Catalytic distillation for ethyl acetate synthesis using microfibrous-structured Nafion-SiO₂/SS-fiber solid acid packings, React. Chem. Eng. 1 (4) (2016) 409-417
[9] T. Deng, J. Ding, G.F. Zhao, Y. Liu, Y. Lu, Catalytic distillation for esterification of acetic acid with ethanol:promising SS-fiber@HZSM-5 catalytic packings and experimental optimization via response surface methodology, J. Chem. Technol. Biotechnol 93 (3) (2018) 827-841
[10] T. Deng, G.F. Zhao, Y. Liu, Y. Lu, Catalytic distillation for one-step cyclohexyl acetate production and cyclohexene-cyclohexane separation via esterification of cyclohexene with acetic acid over microfibrous-structured Nafion-SiO₂/SS-fiber packings, Chem. Eng. Process. Process. Intensif. 131 (2018) 215-226
[11] Q.L. Wang, C. Yang, H.X. Wang, T. Qiu, Optimization of process-specific catalytic packing in catalytic distillation process:a multi-scale strategy, Chem. Eng. Sci. 174 (2017) 472-486
[12] K. Sundmacher, A. Kienle, Reactive Distillation, Wiely, Hoboken, 2002
[13] C.H. Ji, S.M. Xue, Z.L. Xu, X.H. Ma, Fabrication and characterization of novel hollow fiber catalytic packing of PFSA-PES-ZrO₂ (shell)-TiO₂ (core) solid superacid via wet-spinning method, Chem. Eng. Sci. 152 (2016) 1-11
[14] B.M.E. Russbueldt, W.F. Hoelderich, New sulfonic acid ion-exchange resins for the preesterification of different oils and fats with high content of free fatty acids, Appl. Catal. A Gen. 362 (1-2) (2009) 47-57
[15] A. Mehrabani, M.M. Akbarnejad, H. Hosseini, Structural catalytic packing for reaction-distillation columns, Ind. Eng. Chem. Res. 41 (23) (2002) 5842-5847
[16] Y. Li, S. Huang, S. Wu, et al, Preparation and catalytic distillation testing of an acidic zeolite film catalytic packing for synthesis of ETBE, Catal. Lett. 87 (1-2) (2003) 31-35
[17] T.J. Schildhauer, F. Kapteijn, J.A. Moulijn, Stacking of film-flow monoliths for improved performance in reactive stripping, Ind. Eng. Chem. Res. 44 (25) (2005) 9556-9560
[18] Y.L. Jiao, C.H. Jiang, Z.M. Yang, J. Liu, J.S. Zhang, Synthesis of highly accessible ZSM-5 coatings on SiC foam support for MTP reaction, Microporous Mesoporous Mater. 181 (2013) 201-207
[19] X. Gao, Q.Y. Ding, Y. Wu, Y.L. Jiao, J.S. Zhang, X.G. Li, H. Li, Kinetic study of esterification over structured ZSM-5-coated catalysts based on fluid flow situations in macrocellular foam materials, React. Chem. Eng. 5 (3) (2020) 485-494
[20] Q.F. Han, J.N. Wang, M.T. Li, X.D. Wang, Q.L. Wang, C.S. Ye, C. Yang, T. Qiu, A method to fabricate supported catalytic packing:Polydopamine as a "Double-Sided Adhesive" to prepare the fully covered seeding layer, J. Taiwan Inst. Chem. Eng. 132 (2022) 104116
[21] G.P. Dechaine, F.T.T. Ng, A new coated catalyst for the production of diacetone alcohol via catalytic distillation, Ind. Eng. Chem. Res. 47 (23) (2008) 9304-9313
[22] L.P. Han, C.Z. Wang, G.F. Zhao, Y. Liu, Y. Lu, Microstructured Al-fiber@meso-Al₂ O₃@Fe-Mn-K Fischer-Tropsch catalyst for lower olefins, AIChE J. 62 (3) (2016) 742-752
[23] W.L. Luyben, Distillation Design and Control Using Aspen^TM Simulation, John Wiley & Sons, Hoboken, 2013
[24] J.C. Ye, J. Li, Y. Sha, Y.L. Xu, D.W. Zhou, Novel reactive distillation process for phenol production with a dry cation exchange resin as the catalyst, Ind. Eng. Chem. Res. 53 (32) (2014) 12614-12621
[25] T. Keller, J. Muendges, A. Jantharasuk, C.A. Gónzalez-Rugerio, H. Moritz, P. Kreis, A. Górak, Experimental model validation for n-propyl propionate synthesis in a reactive distillation column coupled with a liquid-liquid phase separator, Chem. Eng. Sci. 66 (20) (2011) 4889-4900
[26] K. Qiao, H. Hagiwara, C. Yokoyama, Acidic ionic liquid modified silica gel as novel solid catalysts for esterification and nitration reactions, J. Mol. Catal. A Chem. 246 (1-2) (2006) 65-69
[27] P.F. Yang, X.G. Li, H. Li, H.F. Cong, A.A. Kiss, X. Gao, Unraveling the influence of residence time distribution on the performance of reactive distillation-Process optimization and experimental validation, Chem. Eng. Sci. 237 (2021) 116559
[28] Z.W. Wang, Y. Zhang, Z. Zhang, D.W. Zhou, Z.K. Cao, Y. Sha, Investigation on catalytic distillation for ethyl acetate production with different catalytic packing structures, Chin. J. Chem. Eng. (2022), https://doi.org/10.1016/j.cjche.2022.02.012

Supported catalytic packing prepared from ceramic packing for reactive distillation of ethyl acetate

Supported catalytic packing prepared from ceramic packing for reactive distillation of ethyl acetate

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Zhiwei Wang, Yu Zhang, Zhi Zhang, Daowei Zhou, Zhikai Cao, Yong Sha. Investigation on catalytic distillation for ethyl acetate production with different catalytic packing structures[J]. 中国化学工程学报, 2023, 53(1): 63-72.
[2]	Ran An, Shengxin Chen, Shun Hou, Yuting Zhu, Chunhu Li, Xinbao Zhu, Ruixia Liu, Weizhong An. Simulation and design of a heat-integrated double-effect reactive distillation process for propylene glycol methyl ether production[J]. 中国化学工程学报, 2022, 52(12): 103-114.
[3]	Jiahao Cui, Shejiang Liu, Hua Xue, Xianqin Wang, Ziquan Hao, Rui Liu, Wei Shang, Dan Zhao, Hui Ding. Catalytic ozonation of volatile organic compounds (ethyl acetate) at normal temperature[J]. 中国化学工程学报, 2021, 32(4): 159-167.
[4]	Xianming Zhang, Mengchen Li, Yufeng Hu, Zhichang Liu, Shuqin Mo. Experimental results for the vapor-liquid equilibria of (formaldehyde + 1,3,5-trioxane + methanol + salt + water) systems and comparison with predictions[J]. 中国化学工程学报, 2021, 32(4): 291-300.
[5]	Zhiheng Ren, Muhammad Naeem Younis, Hui Zhao, Chunshan Li, Xiangui Yang, Erqiang Wang, Gongying Wang. Silver modified Cu/SiO₂ catalyst for the hydrogenation of methyl acetate to ethanol[J]. 中国化学工程学报, 2020, 28(6): 1612-1622.
[6]	Yu Ji, Tengda Zhang, Xia Gui, Haijian Shi, Zhi Yun. Solventless ketalization of glycerol to solketal with acetone over the ionic liquid[P(C₄H₉)₃C₁₄H₂₉][TsO][J]. 中国化学工程学报, 2020, 28(1): 158-164.
[7]	Chunli Li, Cong Duan, Jing Fang, Hongshi Li. Process intensification and energy saving of reactive distillation for production of ester compounds[J]. 中国化学工程学报, 2019, 27(6): 1307-1323.
[8]	Lijing Zang, Kejin Huang, Ting Guo, Yang Yuan, Haisheng Chen, Liang Zhang, Xing Qian, Shaofeng Wang. Temperature inferential control of a reactive distillation column with double reactive sections[J]. 中国化学工程学报, 2019, 27(4): 896-904.
[9]	Tao Shen, Bo Ouyang, Chao Qian, Xinzhi Chen. Aminolysis of ethyl acetate in continuous flow and its reaction kinetics[J]. 中国化学工程学报, 2019, 27(12): 2948-2952.
[10]	Xiaomei Ling, Yiwei Xie, Xiaocheng Lin, Ling Li, Ting Qiu. Porous polymer microsphere functionalized with benzimidazolium based ionic liquids as effective solid catalysts for esterification[J]. 中国化学工程学报, 2019, 27(10): 2455-2466.
[11]	Hongshi Li, Tong Li, Chunli Li, Jing Fang, Lihui Dong. Reactive dividing-wall column for the co-production of ethyl acetate and n-butyl acetate[J]. Chinese Journal of Chemical Engineering, 2019, 27(1): 136-143.
[12]	Jiangwei Xie, Chunli Li, Fei Peng, Lihui Dong, Shuaiming Ma. Experimental and simulation of the reactive dividing wall column based on ethyl acetate synthesis[J]. Chinese Journal of Chemical Engineering, 2018, 26(7): 1468-1476.
[13]	Liping Lü, Lin Zhu, Huimin Liu, Hang Li, Shirui Sun. Comparison of continuous homogenous azeotropic and pressure-swing distillation for a minimum azeotropic system ethyl acetate/n-hexane separation[J]. Chinese Journal of Chemical Engineering, 2018, 26(10): 2023-2033.
[14]	Zhixian Huang, Yixiong Lin, Xiaoda Wang, Changshen Ye, Ling Li. Optimization and control of a reactive distillation process for the synthesis of dimethyl carbonate[J]. , 2017, 25(8): 1079-1090.
[15]	Liang Guo, Tiefeng Wang, Dongfeng Li, Jinfu Wang. Liquid-holdup regions research of novel reactive distillation column for C5 fraction separation[J]. , 2017, 25(4): 433-441.