SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2022, Vol. 50 ›› Issue (10): 310-316.DOI: 10.1016/j.cjche.2022.08.001

• Catalysis, Kinetics and Reaction Engineering • 上一篇    下一篇

Role of different types of water in bentonite clay on hydrate formation and decomposition

Yu Zhang1,2,3, Lei Zhang1,2,3, Chang Chen1,2,3, Hao-Peng Zeng1,2,3, Xiao-Sen Li1,2,3, Bo Yang4   

  1. 1 Key Laboratory of Gas Hydrate, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou, Guangdong 510640, China;
    2 Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou, Guangdong 510640, China;
    3 University of Chinese Academy of Sciences, Beijing 10083, China;
    4 Guangzhou Special Pressure Equipment Inspection and Research Institute, Guangzhou 510663, China
  • 收稿日期:2022-03-25 修回日期:2022-07-29 出版日期:2022-10-28 发布日期:2023-01-04
  • 通讯作者: Xiao-Sen Li,E-mail:lixs@ms.giec.ac.cn
  • 基金资助:
    This work is supported by the National Natural Science Foundation of China (52076208, 51736009), the Guangdong Special Support Program (2019BT02L278), the Special project for marine economy development of Guangdong Province (GDME-2020D044), the Science and Technology Program of Guangzhou (20202102080159), and Guangdong Basic and Applied Basic Research Foundation (2022A1515010835), which are gratefully acknowledged.

Role of different types of water in bentonite clay on hydrate formation and decomposition

Yu Zhang1,2,3, Lei Zhang1,2,3, Chang Chen1,2,3, Hao-Peng Zeng1,2,3, Xiao-Sen Li1,2,3, Bo Yang4   

  1. 1 Key Laboratory of Gas Hydrate, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou, Guangdong 510640, China;
    2 Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou, Guangdong 510640, China;
    3 University of Chinese Academy of Sciences, Beijing 10083, China;
    4 Guangzhou Special Pressure Equipment Inspection and Research Institute, Guangzhou 510663, China
  • Received:2022-03-25 Revised:2022-07-29 Online:2022-10-28 Published:2023-01-04
  • Contact: Xiao-Sen Li,E-mail:lixs@ms.giec.ac.cn
  • Supported by:
    This work is supported by the National Natural Science Foundation of China (52076208, 51736009), the Guangdong Special Support Program (2019BT02L278), the Special project for marine economy development of Guangdong Province (GDME-2020D044), the Science and Technology Program of Guangzhou (20202102080159), and Guangdong Basic and Applied Basic Research Foundation (2022A1515010835), which are gratefully acknowledged.

摘要: The equilibrium and kinetic of hydrate in sediments can be affected by the presence of external components like bentonite with a relatively large surface area. To investigate the hydrate formation and decomposition behaviors in bentonite clay, the experiments of methane hydrate formation and decomposition using the multi-step decomposition method in bentonite with different water contents of 20%, 40% and 60% (mass) were carried out. The contents of bound, capillary and gravity water in bentonite clay and their roles during hydrate formation and decomposition were analyzed. In bentonite with water content of 20% (mass), the hydrate formation rate keeps fast during the whole formation process, and the final gas consumption under different initial formation pressures is similar. In bentonite with the water contents of 40% and 60% (mass), the hydrate formation rate declines significantly at the later stage of the hydrate formation. The final gas consumption of bentonite with the water contents of 40% and 60% (mass) is significantly higher than that with the water content of 20% (mass). During the decomposition process, the stable pressure increases with the decrease of the water content. Hydrate mainly forms in free water in bentonite clay. In bentonite clay with the water contents of 20% and 40% (mass), the hydrate forms in capillary water. In bentonite clay with the water content of 60% (mass), the hydrate forms both in capillary water and gravity water. The bound water of dry bentonite clay is about 3.93% (mass) and the content of capillary water ranges from 42.37% to 48.21% (mass) of the dry bentonite clay.

关键词: Methane hydrate, Bentonite, Formation and decomposition, Bound water, Capillary water

Abstract: The equilibrium and kinetic of hydrate in sediments can be affected by the presence of external components like bentonite with a relatively large surface area. To investigate the hydrate formation and decomposition behaviors in bentonite clay, the experiments of methane hydrate formation and decomposition using the multi-step decomposition method in bentonite with different water contents of 20%, 40% and 60% (mass) were carried out. The contents of bound, capillary and gravity water in bentonite clay and their roles during hydrate formation and decomposition were analyzed. In bentonite with water content of 20% (mass), the hydrate formation rate keeps fast during the whole formation process, and the final gas consumption under different initial formation pressures is similar. In bentonite with the water contents of 40% and 60% (mass), the hydrate formation rate declines significantly at the later stage of the hydrate formation. The final gas consumption of bentonite with the water contents of 40% and 60% (mass) is significantly higher than that with the water content of 20% (mass). During the decomposition process, the stable pressure increases with the decrease of the water content. Hydrate mainly forms in free water in bentonite clay. In bentonite clay with the water contents of 20% and 40% (mass), the hydrate forms in capillary water. In bentonite clay with the water content of 60% (mass), the hydrate forms both in capillary water and gravity water. The bound water of dry bentonite clay is about 3.93% (mass) and the content of capillary water ranges from 42.37% to 48.21% (mass) of the dry bentonite clay.

Key words: Methane hydrate, Bentonite, Formation and decomposition, Bound water, Capillary water