PtCo-based nanocatalyst for oxygen reduction reaction: Recent highlights on synthesis strategy and catalytic mechanism

doi:10.1016/j.cjche.2022.03.024

中国化学工程学报 ›› 2023, Vol. 53 ›› Issue (1): 101-123.DOI: 10.1016/j.cjche.2022.03.024

PtCo-based nanocatalyst for oxygen reduction reaction: Recent highlights on synthesis strategy and catalytic mechanism

Wenjuan Yan¹, Puhua Sun¹, Chen Luo², Xingfan Xia¹, Zhifei Liu¹, Yuming Zhao¹, Shuxia Zhang¹, Liang Sun¹, Feng Du¹

1. State Key Laboratory of Heavy Oil Processing, Center for Chemical Engineering Experimental Teaching, Oil Industry Training Center, China University of Petroleum, Qingdao 266580, China;
2. Petrochemical Research Institute, PetroChina, Beijing 102200, China

收稿日期:2021-12-16 修回日期:2022-03-03 出版日期:2023-01-28 发布日期:2023-04-08
通讯作者: Wenjuan Yan,E-mail:wenjuanyan@upc.edu.cn
基金资助:
This study was supported by the National Natural Science Foundation of China (22008262), and Natural Science Foundation of Shandong Province (ZR2020QB187).

PtCo-based nanocatalyst for oxygen reduction reaction: Recent highlights on synthesis strategy and catalytic mechanism

Wenjuan Yan¹, Puhua Sun¹, Chen Luo², Xingfan Xia¹, Zhifei Liu¹, Yuming Zhao¹, Shuxia Zhang¹, Liang Sun¹, Feng Du¹

1. State Key Laboratory of Heavy Oil Processing, Center for Chemical Engineering Experimental Teaching, Oil Industry Training Center, China University of Petroleum, Qingdao 266580, China;
2. Petrochemical Research Institute, PetroChina, Beijing 102200, China

Received:2021-12-16 Revised:2022-03-03 Online:2023-01-28 Published:2023-04-08
Contact: Wenjuan Yan,E-mail:wenjuanyan@upc.edu.cn
Supported by:
This study was supported by the National Natural Science Foundation of China (22008262), and Natural Science Foundation of Shandong Province (ZR2020QB187).

摘要/Abstract

摘要： Oxygen reduction reaction over Pt-based catalyst is one of the most significant cathode reactions in fuel cells. However, low reserves and high price of Pt have motivated researchers worldwide seeking enhanced utilization efficiency and durability by doping non-noble metals to form Pt-based alloy catalysts. Alloying Pt with Co has been recognized as one of the most effective approaches to achieve this goal. PtCo bimetal combination is one of the most promising candidates to synthesize highly efficient catalysts for oxygen reduction reaction (ORR) applications, owing to its relatively more suitable oxygen binding energy for four-electron transfer reactions. Recently, impressive strategies have been developed to fabricate more active and stable PtCo-based multimetallic alloys with tailorable size and morphology. This paper aims to summarize the most recent highlights on the study of the relationship between preparation strategies, morphologies, electroactivities of the PtCo-based catalyst at atomic level and further the relevant reaction mechanism. The challenges and opportunities on the further development of electrocatalysts for fuel cells are included to provide reference for the practical application.

关键词: Electrochemistry, Catalysis, Oxygen reduction reaction, Fuel cells, PtCo nanoalloy, Multimetallic

Abstract: Oxygen reduction reaction over Pt-based catalyst is one of the most significant cathode reactions in fuel cells. However, low reserves and high price of Pt have motivated researchers worldwide seeking enhanced utilization efficiency and durability by doping non-noble metals to form Pt-based alloy catalysts. Alloying Pt with Co has been recognized as one of the most effective approaches to achieve this goal. PtCo bimetal combination is one of the most promising candidates to synthesize highly efficient catalysts for oxygen reduction reaction (ORR) applications, owing to its relatively more suitable oxygen binding energy for four-electron transfer reactions. Recently, impressive strategies have been developed to fabricate more active and stable PtCo-based multimetallic alloys with tailorable size and morphology. This paper aims to summarize the most recent highlights on the study of the relationship between preparation strategies, morphologies, electroactivities of the PtCo-based catalyst at atomic level and further the relevant reaction mechanism. The challenges and opportunities on the further development of electrocatalysts for fuel cells are included to provide reference for the practical application.

Key words: Electrochemistry, Catalysis, Oxygen reduction reaction, Fuel cells, PtCo nanoalloy, Multimetallic

Wenjuan Yan, Puhua Sun, Chen Luo, Xingfan Xia, Zhifei Liu, Yuming Zhao, Shuxia Zhang, Liang Sun, Feng Du. PtCo-based nanocatalyst for oxygen reduction reaction: Recent highlights on synthesis strategy and catalytic mechanism[J]. 中国化学工程学报, 2023, 53(1): 101-123.

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PtCo-based nanocatalyst for oxygen reduction reaction: Recent highlights on synthesis strategy and catalytic mechanism

PtCo-based nanocatalyst for oxygen reduction reaction: Recent highlights on synthesis strategy and catalytic mechanism

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