2,5-Diformylfuran production by photocatalytic selective oxidation of 5-hydroxymethylfurfural in water using MoS2/CdIn2S4 flower-like heterojunctions

doi:10.1016/j.cjche.2022.04.018

中国化学工程学报 ›› 2023, Vol. 54 ›› Issue (2): 180-191.DOI: 10.1016/j.cjche.2022.04.018

• Full Length Article • 上一篇下一篇

2,5-Diformylfuran production by photocatalytic selective oxidation of 5-hydroxymethylfurfural in water using MoS₂/CdIn₂S₄ flower-like heterojunctions

Qian Zhu¹, Yan Zhuang¹, Hongqing Zhao¹, Peng Zhan¹, Cong Ren¹, Changsheng Su¹, Wenqiang Ren³, Jiawen Zhang¹, Di Cai¹, Peiyong Qin²

1. National Energy R&D Center for Biorefinery, Beijing University of Chemical Technology, Beijing 100029, China;
2. Collage of Life Science and Technology, Beijing University of Chemical Technology, Beijing 100029, China;
3. Research Center for Eco-environmental Sciences, Chinese Academy of Science, Beijing 100085, China

收稿日期:2022-01-18 修回日期:2022-03-07 出版日期:2023-02-28 发布日期:2023-05-11
通讯作者: Di Cai,E-mail:caidibuct@163.com;Peiyong Qin,E-mail:qinpeiyong@tsinghua.org.cn
基金资助:
This work was funded by the National Key Research and Development Program of China (2018YFB1501704), the National Natural Science Foundation of China (22078018), and the Beijing Natural Science Foundation (2222016).

2,5-Diformylfuran production by photocatalytic selective oxidation of 5-hydroxymethylfurfural in water using MoS₂/CdIn₂S₄ flower-like heterojunctions

Qian Zhu¹, Yan Zhuang¹, Hongqing Zhao¹, Peng Zhan¹, Cong Ren¹, Changsheng Su¹, Wenqiang Ren³, Jiawen Zhang¹, Di Cai¹, Peiyong Qin²

1. National Energy R&D Center for Biorefinery, Beijing University of Chemical Technology, Beijing 100029, China;
2. Collage of Life Science and Technology, Beijing University of Chemical Technology, Beijing 100029, China;
3. Research Center for Eco-environmental Sciences, Chinese Academy of Science, Beijing 100085, China

Received:2022-01-18 Revised:2022-03-07 Online:2023-02-28 Published:2023-05-11
Contact: Di Cai,E-mail:caidibuct@163.com;Peiyong Qin,E-mail:qinpeiyong@tsinghua.org.cn
Supported by:
This work was funded by the National Key Research and Development Program of China (2018YFB1501704), the National Natural Science Foundation of China (22078018), and the Beijing Natural Science Foundation (2222016).

摘要/Abstract

摘要： The selective oxidation of 5-hydroxymethylfurfural (HMF) into 2,5-diformylfuran (DFF) is an important reaction for renewable biomass building blocks. Compared with thermal catalytic processes, photocatalytic production of DFF from HMF has attracted tremendous attention. Herein, the MoS₂/CdIn₂S₄ (MC) flower-like heterojunctions were prepared and considered as photocatalysts for selective oxidation of HMF into DFF under visible-light irradiation in aqueous solution. Results demonstrated MoS₂ in MC heterojunction could promote the separation of photoexcited electron-hole pairs, while the amount of MoS₂ dropping was proved influenced on the photocatalytic performance. 80.93% of DFF selectivity was realized when using 12.5% MC as photocatalyst. In addition, the MC catalyst also showed great potential in transformation of other biomass derived benzyl- and furyl-alcohols. The catalytic mechanism suggested that ·O₂^- was the decisive active radical for HMF oxidation. Therefore, the MC heterojunction could be applied in photocatalytic conversion of biomass to valuable chemicals under ambient condition.

关键词: 2,5-Diformylfuran (DFF), Photocatalysis, MoS₂/CdIn₂S₄ (MC), Selective oxidation, Visible light irradiation

Abstract: The selective oxidation of 5-hydroxymethylfurfural (HMF) into 2,5-diformylfuran (DFF) is an important reaction for renewable biomass building blocks. Compared with thermal catalytic processes, photocatalytic production of DFF from HMF has attracted tremendous attention. Herein, the MoS₂/CdIn₂S₄ (MC) flower-like heterojunctions were prepared and considered as photocatalysts for selective oxidation of HMF into DFF under visible-light irradiation in aqueous solution. Results demonstrated MoS₂ in MC heterojunction could promote the separation of photoexcited electron-hole pairs, while the amount of MoS₂ dropping was proved influenced on the photocatalytic performance. 80.93% of DFF selectivity was realized when using 12.5% MC as photocatalyst. In addition, the MC catalyst also showed great potential in transformation of other biomass derived benzyl- and furyl-alcohols. The catalytic mechanism suggested that ·O₂^- was the decisive active radical for HMF oxidation. Therefore, the MC heterojunction could be applied in photocatalytic conversion of biomass to valuable chemicals under ambient condition.

Key words: 2,5-Diformylfuran (DFF), Photocatalysis, MoS₂/CdIn₂S₄ (MC), Selective oxidation, Visible light irradiation

Qian Zhu, Yan Zhuang, Hongqing Zhao, Peng Zhan, Cong Ren, Changsheng Su, Wenqiang Ren, Jiawen Zhang, Di Cai, Peiyong Qin. 2,5-Diformylfuran production by photocatalytic selective oxidation of 5-hydroxymethylfurfural in water using MoS₂/CdIn₂S₄ flower-like heterojunctions[J]. 中国化学工程学报, 2023, 54(2): 180-191.

参考文献

[1] G. Han, Y.H. Jin, R.A. Burgess, N.E. Dickenson, X.M. Cao, Y. Sun, Visible-light-driven valorization of biomass intermediates integrated with H₂ production catalyzed by ultrathin Ni/CdS nanosheets, J. Am. Chem. Soc. 139 (44) (2017) 15584–15587. https://pubmed.ncbi.nlm.nih.gov/29020768/
[2] S. Xu, P. Zhou, Z.H. Zhang, C.J. Yang, B.G. Zhang, K.J. Deng, S. Bottle, H.Y. Zhu, Selective oxidation of 5-hydroxymethylfurfural to 2, 5-furandicarboxylic acid using O₂ and a photocatalyst of co-thioporphyrazine bonded to g-C₃N₄, J. Am. Chem. Soc. 139 (41) (2017) 14775–14782. https://doi.org/10.1021/jacs.7b08861
[3] S.G. Meng, H.H. Wu, Y.J. Cui, X.Z. Zheng, H. Wang, S.F. Chen, Y.X. Wang, X.L. Fu, One-step synthesis of 2D/2D-3D NiS/Zn₃In₂S₆ hierarchical structure toward solar-to-chemical energy transformation of biomass-relevant alcohols, Appl. Catal. B Environ. 266 (2020) 118617. http://dx.doi.org/10.1016/j.apcatb.2020.118617
[4] M. Zhang, Z. Li, X. Xin, J.H. Zhang, Y.Q. Feng, H.J. Lv, Selective valorization of 5-hydroxymethylfurfural to 2, 5-diformylfuran using atmospheric O₂ and MAPbBr₃ perovskite under visible light, ACS Catal. 10 (24) (2020) 14793–14800. https://doi.org/10.1021/acscatal.0c04330
[5] W.Y. Liang, R. Zhu, X.L. Li, J. Deng, Y. Fu, Heterogeneous photocatalyzed acceptorless dehydrogenation of 5-hydroxymethylfurfural upon visible-light illumination, Green Chem. 23 (17) (2021) 6604–6613. https://doi.org/10.1039/d1gc01286j
[6] H.C. Zhou, J.L. Song, Q.L. Meng, Z.H. He, Z.W. Jiang, B.W. Zhou, H.Z. Liu, B.X. Han, Cooperative catalysis of Pt/C and acid resin for the production of 2, 5-dimethyltetrahydrofuran from biomass derived 2, 5-hexanedione under mild conditions, Green Chem. 18 (1) (2016) 220–225. https://doi.org/10.1039/c5gc01741f
[7] X.Y. Wan, C.M. Zhou, J.S. Chen, W.P. Deng, Q.H. Zhang, Y.H. Yang, Y. Wang, Base-free aerobic oxidation of 5-hydroxymethyl-furfural to 2, 5-furandicarboxylic acid in water catalyzed by functionalized carbon nanotube-supported Au-Pd alloy nanoparticles, ACS Catal. 4 (7) (2014) 2175–2185. http://dx.doi.org/10.1021/cs5003096
[8] D. Bonincontro, A. Lolli, A. Villa, L. Prati, N. Dimitratos, G.M. Veith, L.E. Chinchilla, G.A. Botton, F. Cavani, S. Albonetti, AuPd-nNiO as an effective catalyst for the base-free oxidation of HMF under mild reaction conditions, Green Chem. 21 (15) (2019) 4090–4099. https://doi.org/10.1039/c9gc01283d
[9] M.P.J. van Deurzen, F. van Rantwijk, R.A. Sheldon, Chloroperoxidase-catalyzed oxidation of 5-hydroxymethylfurfural, J. Carbohydr. Chem. 16 (3) (1997) 299–309. http://dx.doi.org/10.1080/07328309708006531
[10] A.S. Amarasekara, D. Green, E. McMillan, Efficient oxidation of 5-hydroxymethylfurfural to 2, 5-diformylfuran using Mn(III)-salen catalysts, Catal. Commun. 9 (2) (2008) 286–288. http://dx.doi.org/10.1016/j.catcom.2007.06.021
[11] M. Zhang, Z.H. Yu, J. Xiong, R. Zhang, X.Z. Liu, X.B. Lu, One-step hydrothermal synthesis of CdxInyS(x+1.5y) for photocatalytic oxidation of biomass-derived 5-hydroxymethylfurfural to 2, 5-diformylfuran under ambient conditions, Appl. Catal. B Environ. 300 (2022) 120738. http://dx.doi.org/10.1016/j.apcatb.2021.120738
[12] L. Hu, A.Y. He, X.Y. Liu, J. Xia, J.X. Xu, S.Y. Zhou, J.M. Xu, Biocatalytic transformation of 5-hydroxymethylfurfural into high-value derivatives: Recent advances and future aspects, ACS Sustain. Chem. Eng. 6 (12) (2018) 15915–15935. http://dx.doi.org/10.1021/acssuschemeng.8b04356
[13] L. Hu, J.X. Xu, S.Y. Zhou, A.Y. He, X. Tang, L. Lin, J.M. Xu, Y.J. Zhao, Catalytic advances in the production and application of biomass-derived 2, 5-dihydroxymethylfuran, ACS Catal. 8 (4) (2018) 2959–2980. https://doi.org/10.1021/acscatal.7b03530
[14] D.Y. Zhao, T. Su, Y.T. Wang, R.S. Varma, C. Len, Recent advances in catalytic oxidation of 5-hydroxymethylfurfural, Mol. Catal. 495 (2020) 111133. http://dx.doi.org/10.1016/j.mcat.2020.111133
[15] S. Yurdakal, B.S. Tek, O. Alagöz, V. Augugliaro, V. Loddo, G. Palmisano, L. Palmisano, Photocatalytic selective oxidation of 5-(hydroxymethyl)-2-furaldehyde to 2, 5-furandicarbaldehyde in water by using anatase, rutile, and brookite TiO₂ nanoparticles, ACS Sustainable Chem. Eng. 1 (5) (2013) 456–461. https://doi.org/10.1021/sc300142a
[16] C.C. Li, Y. Na, Recent advances in photocatalytic oxidation of 5-hydroxymethylfurfural, ChemPhotoChem 5 (6) (2021) 502–511. http://dx.doi.org/10.1002/cptc.202000261
[17] X. Wu, N. Luo, S. Xie, H. Zhang, Q. Zhang, F. Wang, Y. Wang, Photocatalytic transformations of lignocellulosic biomass into chemicals, Chem. Soc. Rev. 49 (2020) 6198-6223.
[18] I. Krivtsov, E.I. García-López, G. Marcì, L. Palmisano, Z. Amghouz, J.R. García, S. Ordóñez, E. Díaz, Selective photocatalytic oxidation of 5-hydroxymethyl-2-furfural to 2, 5-furandicarboxyaldehyde in aqueous suspension of g-C₃N₄, Appl. Catal. B Environ. 204 (2017) 430–439. http://dx.doi.org/10.1016/j.apcatb.2016.11.049
[19] A. Kumar, R. Srivastava, Rose-like Bi₂WO₆ nanostructure for visible-light-assisted oxidation of lignocellulose-derived 5-hydroxymethylfurfural and vanillyl alcohol, ACS Appl. Nano Mater. 4 (9) (2021) 9080–9093. https://doi.org/10.1021/acsanm.1c01679
[20] H.L. Zhang, Z.Y. Feng, Y.K. Zhu, Y. Wu, T.H. Wu, Photocatalytic selective oxidation of biomass-derived 5-hydroxymethylfurfural to 2, 5-diformylfuran on WO₃/g-C₃N₄ composite under irradiation of visible light, J. Photochem. Photobiol. A Chem. 371 (2019) 1–9. http://dx.doi.org/10.1016/j.jphotochem.2018.10.044
[21] I. Krivtsov, M. Ilkaeva, E. Salas-Colera, Z. Amghouz, J.R. García, E. Díaz, S. Ordóñez, S. Villar-Rodil, Consequences of nitrogen doping and oxygen enrichment on titanium local order and photocatalytic performance of TiO₂ anatase, J. Phys. Chem. C 121 (2017) 6770–6780.
[22] S.X. Yu, Y.H. Zhang, F. Dong, M. Li, T.R. Zhang, H.W. Huang, Readily achieving concentration-tunable oxygen vacancies in Bi₂O₂CO₃: Triple-functional role for efficient visible-light photocatalytic redox performance, Appl. Catal. B Environ. 226 (2018) 441–450. http://dx.doi.org/10.1016/j.apcatb.2017.12.074
[23] M. Ilkaeva, I. Krivtsov, E.I. García-López, G. Marcì, O. Khainakova, J.R. García, L. Palmisano, E. Díaz, S. Ordóñez, Selective photocatalytic oxidation of 5-hydroxymethylfurfural to 2, 5-furandicarboxaldehyde by polymeric carbon nitride-hydrogen peroxide adduct, J. Catal. 359 (2018) 212–222. http://dx.doi.org/10.1016/j.jcat.2018.01.012
[24] D. Li, F.F. Shi, D.L. Jiang, M. Chen, W.D. Shi, CdIn₂S₄/g-C₃N₄ heterojunction photocatalysts: Enhanced photocatalytic performance and charge transfer mechanism, RSC Adv. 7 (1) (2017) 231–237. https://doi.org/10.1039/c6ra24809h
[25] B.W. Zhou, J.L. Song, Z.R. Zhang, Z.W. Jiang, P. Zhang, B.X. Han, Highly selective photocatalytic oxidation of biomass-derived chemicals to carboxyl compounds over Au/TiO₂, Green Chem. 19 (4) (2017) 1075–1081. https://doi.org/10.1039/c6gc03022j
[26] B. Ma, Y.Y. Wang, X.N. Guo, X.L. Tong, C. Liu, Y.W. Wang, X.Y. Guo, Photocatalytic synthesis of 2, 5-diformylfuran from 5-hydroxymethyfurfural or fructose over bimetallic Au-Ru nanoparticles supported on reduced graphene oxides, Appl. Catal. A Gen. 552 (2018) 70–76. http://dx.doi.org/10.1016/j.apcata.2018.01.002
[27] Y.K. Zhu, Y. Zhang, L.L. Cheng, M. Ismael, Z.Y. Feng, Y. Wu, Novel application of g-C₃N₄/NaNbO₃ composite for photocatalytic selective oxidation of biomass-derived HMF to FFCA under visible light irradiation, Adv. Powder Technol. 31 (3) (2020) 1148–1159. http://dx.doi.org/10.1016/j.apt.2019.12.040
[28] C.Y. Pei, Y.G. Chen, L. Wang, W. Chen, G.B. Huang, Step-scheme WO₃/CdIn₂S₄ hybrid system with high visible light activity for tetracycline hydrochloride photodegradation, Appl. Surf. Sci. 535 (2021) 147682. http://dx.doi.org/10.1016/j.apsusc.2020.147682
[29] B. Zhang, H.X. Shi, X.Y. Hu, Y.S. Wang, E.Z. Liu, J. Fan, A novel S-scheme MoS₂/CdIn₂S₄ flower-like heterojunctions with enhanced photocatalytic degradation and H₂ evolution activity, J. Phys. D: Appl. Phys. 53 (20) (2020) 205101. https://doi.org/10.1088/1361-6463/ab7563
[30] H. Liu, Z. Zhang, J.C. Meng, J. Zhang, Novel visible-light-driven CdIn₂S₄/mesoporous g-C₃N₄ hybrids for efficient photocatalytic reduction of CO₂ to methanol, Mol. Catal. 430 (2017) 9–19. http://dx.doi.org/10.1016/j.molcata.2016.12.006
[31] C. Xue, H. An, X.Q. Yan, J.L. Li, B.L. Yang, J.J. Wei, G.D. Yang, Spatial charge separation and transfer in ultrathin CdIn₂S₄/rGO nanosheet arrays decorated by ZnS quantum dots for efficient visible-light-driven hydrogen evolution, Nano Energy 39 (2017) 513–523. http://dx.doi.org/10.1016/j.nanoen.2017.07.030
[32] P. Xiao, D.L. Jiang, L.X. Ju, J.J. Jing, M. Chen, Construction of RGO/CdIn₂S₄/g-C₃N₄ ternary hybrid with enhanced photocatalytic activity for the degradation of tetracycline hydrochloride, Appl. Surf. Sci. 433 (2018) 388–397. http://dx.doi.org/10.1016/j.apsusc.2017.10.028
[33] W. Chen, T. Huang, Y.X. Hua, T.Y. Liu, X.H. Liu, S.M. Chen, Hierarchical CdIn ₂ S₄ microspheres wrapped by mesoporous g-C ₃ N₄ ultrathin nanosheets with enhanced visible light driven photocatalytic reduction activity, J. Hazard. Mater. 320 (2016) 529–538. https://pubmed.ncbi.nlm.nih.gov/27597153/
[34] Y.Z. Li, X.J. Wang, H.H. Huo, Z. Li, J.H. Shi, A novel binary visible-light-driven photocatalyst type-I CdIn₂S₄/g-C₃N₄ heterojunctions coupling with H₂O₂: Synthesis, characterization, photocatalytic activity for Reactive Blue 19 degradation and mechanism analysis, Colloids Surf. A Physicochem. Eng. Aspects 587 (2020) 124322. http://dx.doi.org/10.1016/j.colsurfa.2019.124322
[35] M.A. Mahadadalkar, S.W. Gosavi, B.B. Kale, Interstitial charge transfer pathways in a TiO₂/CdIn₂S₄ heterojunction photocatalyst for direct conversion of sunlight into fuel, J. Mater. Chem. A 6 (33) (2018) 16064–16073. https://doi.org/10.1039/c8ta03398f
[36] M. Sun, X. Zhao, Q. Zeng, T. Yan, P.G. Ji, T.T. Wu, D. Wei, B. Du, Facile synthesis of hierarchical ZnIn₂S₄/CdIn₂S₄ microspheres with enhanced visible light driven photocatalytic activity, Appl. Surf. Sci. 407 (2017) 328–336. http://dx.doi.org/10.1016/j.apsusc.2017.02.181
[37] Y.G. Yu, G. Chen, G. Wang, Z.S. Lv, Visible-light-driven ZnIn₂S₄/CdIn₂S₄ composite photocatalyst with enhanced performance for photocatalytic H₂ evolution, Int. J. Hydrog. Energy 38 (3) (2013) 1278–1285. http://dx.doi.org/10.1016/j.ijhydene.2012.11.020
[38] M.H. Yu, Q. Hu, X.Y. Gong, H. Yu, S. Wang, Z.Q. Li, Y.Y. Chen, S.J. Li, The construction of three-dimensional CdIn₂S₄/MoS₂ composite materials for efficient hydrogen production, J. Alloys Compd. 892 (2022) 162168. http://dx.doi.org/10.1016/j.jallcom.2021.162168
[39] J. Wang, D.L. Chao, J.L. Liu, L.L. Li, L.F. Lai, J.Y. Lin, Z.X. Shen, Ni₃S₂@MoS₂ core/shell nanorod arrays on Ni foam for high-performance electrochemical energy storage, Nano Energy 7 (2014) 151–160. http://dx.doi.org/10.1016/j.nanoen.2014.04.019
[40] T. Stephenson, Z. Li, B. Olsen, D. Mitlin, Lithium ion battery applications of molybdenum disulfide (MoS₂) nanocomposites, Energy Environ. Sci. 7 (1) (2014) 209–231. https://doi.org/10.1039/c3ee42591f
[41] J.L. Huang, D.M. Hou, Y.C. Zhou, W.J. Zhou, G.Q. Li, Z.H. Tang, L.G. Li, S.W. Chen, MoS₂ nanosheet-coated CoS₂ nanowire arrays on carbon cloth as three-dimensional electrodes for efficient electrocatalytic hydrogen evolution, J. Mater. Chem. A 3 (45) (2015) 22886–22891. https://doi.org/10.1039/c5ta07234d
[42] Y.T. Prabhu, R. Kumari, A. Gautam, B. Sreedhar, U. Pal, Highly oriented MoS₂@CdIn₂S₄ nanostructures for efficient solar fuel generation, Nano Struct. Nano Objects 26 (2021) 100682. http://dx.doi.org/10.1016/j.nanoso.2021.100682
[43] G. Eda, H. Yamaguchi, D. Voiry, T. Fujita, M.W. Chen, M. Chhowalla, Photoluminescence from chemically exfoliated MoS₂, Nano Lett. 11 (12) (2011) 5111–5116. https://pubmed.ncbi.nlm.nih.gov/22035145/
[44] C.L. Tan, M.Y. Qi, Z.R. Tang, Y.J. Xu, Cocatalyst decorated ZnIn₂S₄ composites for cooperative alcohol conversion and H₂ evolution, Appl. Catal. B Environ. 298 (2021) 120541. http://dx.doi.org/10.1016/j.apcatb.2021.120541
[45] H.C. Shan, S.F. Li, Z. Yang, X.X. Zhang, Y. Zhuang, Q. Zhu, D. Cai, P.Y. Qin, J. Baeyens, Triazine-based N-rich porous covalent organic polymer for the effective detection and removal of Hg (II) from an aqueous solution, Chem. Eng. J. 426 (2021) 130757. http://dx.doi.org/10.1016/j.cej.2021.130757
[46] Y. Zhuang, H.C. Shan, Z.P. Zhang, S.F. Li, Q. Zhu, Z.H. Si, S. Yang, Z. Yang, D. Cai, P.Y. Qin, Triazine-based covalent organic polymer as stable luminescent probe for highly selective detection of 2, 4, 6-trinitrophenol, Dyes Pigments 192 (2021) 109421. http://dx.doi.org/10.1016/j.dyepig.2021.109421
[47] X.X. Wang, S.G. Meng, S.J. Zhang, X.Z. Zheng, S.F. Chen, 2D/2D MXene/g-C₃N₄ for photocatalytic selective oxidation of 5-hydroxymethylfurfural into 2, 5-formylfuran, Catal. Commun. 147 (2020) 106152. http://dx.doi.org/10.1016/j.catcom.2020.106152
[48] D.A. Giannakoudakis, V. Nair, A. Khan, E.A. Deliyanni, J.C. Colmenares, K.S. Triantafyllidis, Additive-free photo-assisted selective partial oxidation at ambient conditions of 5-hydroxymethylfurfural by manganese (IV) oxide nanorods, Appl. Catal. B Environ. 256 (2019) 117803. http://dx.doi.org/10.1016/j.apcatb.2019.117803
[49] S.H. Dong, M.Z. Chen, J.R. Zhang, J.Z. Chen, Y.S. Xu, Visible-light-induced hydrogenation of biomass-based aldehydes by graphitic carbon nitride supported metal catalysts, Green Energy Environ. 6 (5) (2021) 715–724. http://dx.doi.org/10.1016/j.gee.2020.07.004
[50] Y. Wang, X. Kong, M. Jiang, F. Zhang, X. Lei, A Z-scheme ZnIn₂S₄/Nb₂O₅ nanocomposite: Constructed and used as an efficient bifunctional photocatalyst for H₂ evolution and oxidation of 5-hydroxymethylfurfural, Inorg. Chem. Front. 7 (2020) 437–446.
[51] Y.Y. Zhao, X.H. Liang, H.X. Shi, Y.B. Wang, Y.K. Ren, E.Z. Liu, X. Zhang, J. Fan, X.Y. Hu, Photocatalytic activity enhanced by synergistic effects of nano-silver and ZnSe quantum dots co-loaded with bulk g-C₃N₄ for Ceftriaxone sodium degradation in aquatic environment, Chem. Eng. J. 353 (2018) 56–68. http://dx.doi.org/10.1016/j.cej.2018.07.109
[52] J.G. Yu, W.G. Wang, B. Cheng, B.L. Su, Enhancement of photocatalytic activity of mesporous TiO₂ powders by hydrothermal surface fluorination treatment, J. Phys. Chem. C 113 (16) (2009) 6743–6750. https://doi.org/10.1021/jp900136q
[53] S.F. Chen, Y.F. Hu, S.G. Meng, X.L. Fu, Study on the separation mechanisms of photogenerated electrons and holes for composite photocatalysts g-C₃N₄-WO₃, Appl. Catal. B Environ. 150-151 (2014) 564–573. https://doi.org/10.1016/j.apcatb.2013.12.053
[54] J. Cao, B.D. Luo, H.L. Lin, B.Y. Xu, S.F. Chen, Thermodecomposition synthesis of WO₃/H₂WO₄ heterostructures with enhanced visible light photocatalytic properties, Appl. Catal. B Environ. 111-112 (2012) 288–296. http://dx.doi.org/10.1016/j.apcatb.2011.10.010
[55] C. Ayed, W. Huang, G. Kizilsavas, K. Landfester, K.A.I. Zhang, Photocatalytic partial oxidation of 5-hydroxymethylfurfural (HMF) to 2, 5-diformylfuran (DFF) over a covalent triazine framework in water, ChemPhotoChem 4 (8) (2020) 571–576. https://doi.org/10.1002/cptc.202000070
[56] S.S. Yu, S.D. Zhang, K.N. Li, Q. Yang, M. Wang, D. Cai, T.W. Tan, B.Q. Chen, Furfuryl alcohol production with high selectivity by a novel visible-light driven biocatalysis process, ACS Sustainable Chem. Eng. 8 (42) (2020) 15980–15988. https://doi.org/10.1021/acssuschemeng.0c05978
[57] H.Q. Zhao, Q. Zhu, Y. Zhuang, P. Zhan, Y.O. Qi, W.Q. Ren, Z.H. Si, D. Cai, S.S. Yu, P.Y. Qin, Hierarchical ZnIn₂S₄ microspheres as photocatalyst for boosting the selective biohydrogenation of furfural into furfuryl alcohol under visible light irradiation, Green Chem. Eng. (2022)http://dx.doi.org/10.1016/j.gce.2022.01.004
[58] J.J. Xue, C.J. Huang, Y.Q. Zong, J.D. Gu, M.X. Wang, S.S. Ma, Fe (III)-grafted Bi 2 MoO 6 nanoplates for enhanced photocatalytic activities on tetracycline degradation and HMF oxidation, Appl. Organomet. Chem. 33 (11) (2019): https://doi.org/10.1002/aoc.5187. https://doi.org/10.1002/aoc.5187
[59] Y. Zhuang, Q. Zhu, G.Z. Li, Z.L. Wang, P. Zhan, C. Ren, Z.H. Si, S.F. Li, D. Cai, P.Y. Qin, Photocatalytic degradation of organic dyes using covalent triazine-based framework, Mater. Res. Bull. 146 (2022) 111619. http://dx.doi.org/10.1016/j.materresbull.2021.111619
[60] J.F. Zhang, Y.F. Hu, X.L. Jiang, S.F. Chen, S.G. Meng, X.L. Fu, Design of a direct Z-scheme photocatalyst: Preparation and characterization of Bi₂O₃/g-C₃N₄ with high visible light activity, J. Hazard. Mater. 280 (2014) 713–722. https://pubmed.ncbi.nlm.nih.gov/25232654/
[61] W.J. Li, D.Z. Li, Y.M. Lin, P.X. Wang, W. Chen, X.Z. Fu, Y. Shao, Evidence for the active species involved in the photodegradation process of methyl orange on TiO₂, J. Phys. Chem. C 116 (5) (2012) 3552–3560. https://doi.org/10.1021/jp209661d
[62] Y.M. Lin, D.Z. Li, J.H. Hu, G.C. Xiao, J.X. Wang, W.J. Li, X.Z. Fu, Highly efficient photocatalytic degradation of organic pollutants by PANI-modified TiO₂ composite, J. Phys. Chem. C 116 (9) (2012) 5764–5772. http://dx.doi.org/10.1021/jp211222w

2,5-Diformylfuran production by photocatalytic selective oxidation of 5-hydroxymethylfurfural in water using MoS₂/CdIn₂S₄ flower-like heterojunctions

2,5-Diformylfuran production by photocatalytic selective oxidation of 5-hydroxymethylfurfural in water using MoS₂/CdIn₂S₄ flower-like heterojunctions

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Feng Guo, Zhihao Chen, Xiliu Huang, Longwen Cao, Xiaofang Cheng, Weilong Shi, Lizhuang Chen. Ternary Ni₂P/Bi₂MoO₆/g-C₃N₄ composite with Z-scheme electron transfer path for enhanced removal broad-spectrum antibiotics by the synergistic effect of adsorption and photocatalysis[J]. 中国化学工程学报, 2022, 44(4): 157-168.
[2]	Muhammad Faizan, Yingwei Li, Ruirui Zhang, Xingsheng Wang, Piao Song, Ruixia Liu. Progress of vanadium phosphorous oxide catalyst for n-butane selective oxidation[J]. 中国化学工程学报, 2022, 43(3): 297-315.
[3]	Feng Guo, Haoran Sun, Yuxing Shi, Fengyu Zhou, Weilong Shi. CdS nanoparticles decorated hexagonal Fe₂O₃ nanosheets with a Z-scheme photogenerated electron transfer path for improved visible-light photocatalytic hydrogen production[J]. 中国化学工程学报, 2022, 43(3): 266-274.
[4]	Zeng Wei Heng, Woon Chan Chong, Yean Ling Pang, Lan Ching Sim, Chai Hoon Koo. Photocatalytic degradation of organic pollutants using green oil palm frond-derived carbon quantum dots/titanium dioxide as multifunctional photocatalysts under visible light radiation[J]. 中国化学工程学报, 2022, 51(11): 21-34.
[5]	Rui Zheng, Chunhu Li, Chengzhen Zhang, Wentai Wang, Liang Wang, Lijuan Feng, Junjie Bian. Photo-reduction of NO by g-C₃N₄@foamed ceramic[J]. 中国化学工程学报, 2020, 28(7): 1840-1846.
[6]	Jing Zhao, Yifu Zhang, Lei Xu, Fuping Tian, Tao Hu, Changgong Meng. Weak base favoring the synthesis of highly ordered V-MCM-41 with well-dispersed vanadium and the catalytic performances on selective oxidation of benzyl alcohol[J]. 中国化学工程学报, 2020, 28(5): 1424-1435.
[7]	Jinghang Li, Huimin Zang, Shun Yao, Zicheng Li, Hang Song. Photodegradation of benzothiazole ionic liquids catalyzed by titanium dioxide and silver-loaded titanium dioxide[J]. 中国化学工程学报, 2020, 28(5): 1397-1404.
[8]	Xianfeng Liu, Fu Yang, Shuying Gao, Bo Shao, Shijian Zhou, Yan Kong. Preparation of ZSM-5 containing vanadium and Brønsted acid sites with high promoting of styrene oxidation using 30% H₂O₂[J]. 中国化学工程学报, 2020, 28(5): 1302-1310.
[9]	Jue Li, Li Wang, Chunqiu Han, Fengyun Su, Yumin Leng, Liqun Ye. Industrial TiO₂ based nacreous pigments as functional building materials: Photocatalytic removal of NO[J]. 中国化学工程学报, 2020, 28(10): 2587-2591.
[10]	K. V. Divya Lakshmi, T. Siva Rao, J. Swathi Padmaja, I. Manga Raju, M. Ravi Kumar. Structure, photocatalytic and antibacterial activity study of Meso porous Ni and S co-doped TiO₂ nano material under visible light irradiation[J]. 中国化学工程学报, 2019, 27(7): 1630-1641.
[11]	Jianling Meng, Yongdan Li. A high H₂ evolution rate under visible light of a CdS/TiO₂@NiS catalyst due to a directional electron transfer between the phases[J]. 中国化学工程学报, 2019, 27(3): 544-548.
[12]	Qin Zhou, Hengbo Yin, Aili Wang, Yang Si. Preparation of hollow B-SiO₂@TiO₂ composites and their photocatalytic performances for degradation of ammonia-nitrogen and green algae in aqueous solution[J]. 中国化学工程学报, 2019, 27(10): 2535-2543.
[13]	Radha Devi Chekuri, Siva Rao Tirukkovalluri. One step synthesis and characterization of copper doped sulfated titania and its enhanced photocatalytic activity in visible light by degradation of methyl orange[J]. Chinese Journal of Chemical Engineering, 2016, 24(4): 475-483.
[14]	储金宇, 仲蕾. Photocatalytic Degradation of Methylene Blue with Side-glowing Optical Fiber Deliverying Visible Light[J]. Chinese Journal of Chemical Engineering, 2012, 20(5): 895-899.
[15]	於煌, 郑旭煦, 殷钟意, 陶丰, 房蓓蓓, 侯苛山. 纳米N掺杂TiO₂的制备及可见光催化活性研究[J]. , 2007, 15(6): 802-807.