Ternary Ni2P/Bi2MoO6/g-C3N4 composite with Z-scheme electron transfer path for enhanced removal broad-spectrum antibiotics by the synergistic effect of adsorption and photocatalysis

doi:10.1016/j.cjche.2021.08.024

中国化学工程学报 ›› 2022, Vol. 44 ›› Issue (4): 157-168.DOI: 10.1016/j.cjche.2021.08.024

Ternary Ni₂P/Bi₂MoO₆/g-C₃N₄ composite with Z-scheme electron transfer path for enhanced removal broad-spectrum antibiotics by the synergistic effect of adsorption and photocatalysis

Feng Guo¹, Zhihao Chen², Xiliu Huang², Longwen Cao², Xiaofang Cheng², Weilong Shi^3,4, Lizhuang Chen²

1 School of Energy and Power, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2 School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
3 School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
4 College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

收稿日期:2021-02-17 修回日期:2021-08-05 出版日期:2022-04-28 发布日期:2022-06-18
通讯作者: Weilong Shi,E-mail:shiwl@just.edu.cn;Lizhuang Chen,E-mail:clz1977@sina.com
基金资助:
This work was financially supported by the National Natural Science Foundation of China (No. 21906072, 22006057, 21671084 and 51902140), the Natural Science Foundation of Jiangsu Province (BK20190982), Henan Postdoctoral Foundation (202003013), "Doctor of Mass entrepreneurship and innovation" Project in Jiangsu Province, Jiangsu 333 talents project funding (BRA2018342), Jiangsu provincial government scholarship for overseas studies, the Doctoral Scientific Research Foundation of Jiangsu University of Science and Technology (China) (1062931806 and 1142931803).

Ternary Ni₂P/Bi₂MoO₆/g-C₃N₄ composite with Z-scheme electron transfer path for enhanced removal broad-spectrum antibiotics by the synergistic effect of adsorption and photocatalysis

Feng Guo¹, Zhihao Chen², Xiliu Huang², Longwen Cao², Xiaofang Cheng², Weilong Shi^3,4, Lizhuang Chen²

1 School of Energy and Power, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2 School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
3 School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
4 College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

Received:2021-02-17 Revised:2021-08-05 Online:2022-04-28 Published:2022-06-18
Contact: Weilong Shi,E-mail:shiwl@just.edu.cn;Lizhuang Chen,E-mail:clz1977@sina.com
Supported by:
This work was financially supported by the National Natural Science Foundation of China (No. 21906072, 22006057, 21671084 and 51902140), the Natural Science Foundation of Jiangsu Province (BK20190982), Henan Postdoctoral Foundation (202003013), "Doctor of Mass entrepreneurship and innovation" Project in Jiangsu Province, Jiangsu 333 talents project funding (BRA2018342), Jiangsu provincial government scholarship for overseas studies, the Doctoral Scientific Research Foundation of Jiangsu University of Science and Technology (China) (1062931806 and 1142931803).

摘要/Abstract

摘要： Constructing the stable, low-cost, efficient, and highly adaptable visible light-driven photocatalyst to implement the synergistic effect of photocatalysis and adsorption has been excavated a promising strategy to deal with antibiotic pollution in water bodies. Herein, a novel 3D ternary Z-scheme heterojunction photocatalyst Ni₂P/Bi₂MoO₆/g-C₃N₄ (Ni₂P/BMO/CN) was fabricated by a simple solvothermal method in which the broad spectrum antibiotics (mainly tetracyclines and supplemented by quinolones) were used as target pollution sources to evaluate its adsorption and photocatalytic performance. Notably, the Z-scheme composite significantly exhibit the enhancement for degradation efficiency of tetracycline and other antibiotic by using Ni₂P nanoparticles as electron conductor. Active species capture experiment and electron spin resonance (ESR) technology reveal the mechanism of Z-scheme Ni₂P/BMO/CN photocatalytic reaction in detail. In addition, based on the identification of intermediates by liquid chromatography–mass spectroscopy (LC–MS), the possible photocatalytic degradation pathways of TC were proposed.

关键词: Ni₂P, Bi₂MoO₆/g-C₃N₄, Z-scheme, Photocatalysis, Adsorption

Abstract: Constructing the stable, low-cost, efficient, and highly adaptable visible light-driven photocatalyst to implement the synergistic effect of photocatalysis and adsorption has been excavated a promising strategy to deal with antibiotic pollution in water bodies. Herein, a novel 3D ternary Z-scheme heterojunction photocatalyst Ni₂P/Bi₂MoO₆/g-C₃N₄ (Ni₂P/BMO/CN) was fabricated by a simple solvothermal method in which the broad spectrum antibiotics (mainly tetracyclines and supplemented by quinolones) were used as target pollution sources to evaluate its adsorption and photocatalytic performance. Notably, the Z-scheme composite significantly exhibit the enhancement for degradation efficiency of tetracycline and other antibiotic by using Ni₂P nanoparticles as electron conductor. Active species capture experiment and electron spin resonance (ESR) technology reveal the mechanism of Z-scheme Ni₂P/BMO/CN photocatalytic reaction in detail. In addition, based on the identification of intermediates by liquid chromatography–mass spectroscopy (LC–MS), the possible photocatalytic degradation pathways of TC were proposed.

Key words: Ni₂P, Bi₂MoO₆/g-C₃N₄, Z-scheme, Photocatalysis, Adsorption

Feng Guo, Zhihao Chen, Xiliu Huang, Longwen Cao, Xiaofang Cheng, Weilong Shi, Lizhuang Chen. Ternary Ni₂P/Bi₂MoO₆/g-C₃N₄ composite with Z-scheme electron transfer path for enhanced removal broad-spectrum antibiotics by the synergistic effect of adsorption and photocatalysis[J]. 中国化学工程学报, 2022, 44(4): 157-168.

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Ternary Ni₂P/Bi₂MoO₆/g-C₃N₄ composite with Z-scheme electron transfer path for enhanced removal broad-spectrum antibiotics by the synergistic effect of adsorption and photocatalysis

Ternary Ni₂P/Bi₂MoO₆/g-C₃N₄ composite with Z-scheme electron transfer path for enhanced removal broad-spectrum antibiotics by the synergistic effect of adsorption and photocatalysis

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