Electrospinning organic solvent resistant preoxidized poly(acrylonitrile) nanofiber membrane and its properties

doi:10.1016/j.cjche.2022.01.030

中国化学工程学报 ›› 2023, Vol. 53 ›› Issue (1): 289-299.DOI: 10.1016/j.cjche.2022.01.030

• Full Length Article • 上一篇下一篇

Electrospinning organic solvent resistant preoxidized poly(acrylonitrile) nanofiber membrane and its properties

Zhiwei Du^1,2, Jinxue Cheng^1,2, Qinglin Huang^1,2, Mingxing Chen³, Changfa Xiao⁴

1. State Key Laboratory of Separation Membranes and Membrane Processes/National Center for International Joint Research on Separation Membranes, Tianjin 300387, China;
2. Department of Material Science and Engineering, Tiangong University, Tianjin 300387, China;
3. College of Textile and Garments, Hebei University of Science and Technology, Shijiazhuang 050018, China;
4. Fiber Materials Research Center, Shanghai University of Engineering Science, Shanghai 201620, China

收稿日期:2021-09-17 修回日期:2022-01-23 出版日期:2023-01-28 发布日期:2023-04-08
通讯作者: Qinglin Huang,E-mail:huangqinglin@tiangong.edu.cn;Mingxing Chen,E-mail:mxchen1990@163.com
基金资助:
This work was supported by the Science and Technology Plans of Tianjin (18PTSYJC00170), the Young Elite Scientists Sponsorship Program by China Association for Science and Technology ( YESS20160168). The Analytical & Testing Center of Tiangong University was appreciated.

Electrospinning organic solvent resistant preoxidized poly(acrylonitrile) nanofiber membrane and its properties

Zhiwei Du^1,2, Jinxue Cheng^1,2, Qinglin Huang^1,2, Mingxing Chen³, Changfa Xiao⁴

1. State Key Laboratory of Separation Membranes and Membrane Processes/National Center for International Joint Research on Separation Membranes, Tianjin 300387, China;
2. Department of Material Science and Engineering, Tiangong University, Tianjin 300387, China;
3. College of Textile and Garments, Hebei University of Science and Technology, Shijiazhuang 050018, China;
4. Fiber Materials Research Center, Shanghai University of Engineering Science, Shanghai 201620, China

Received:2021-09-17 Revised:2022-01-23 Online:2023-01-28 Published:2023-04-08
Contact: Qinglin Huang,E-mail:huangqinglin@tiangong.edu.cn;Mingxing Chen,E-mail:mxchen1990@163.com
Supported by:
This work was supported by the Science and Technology Plans of Tianjin (18PTSYJC00170), the Young Elite Scientists Sponsorship Program by China Association for Science and Technology ( YESS20160168). The Analytical & Testing Center of Tiangong University was appreciated.

摘要/Abstract

摘要： A high performance preoxidized poly(acrylonitrile) (O-PAN) nanofiber membrane with excellent solvent resistance, thermal stability and flexibility was fabricated by the preoxidation of electrospun PAN nanofiber membrane. The performance of resultant O-PAN nanofiber membrane was optimized by altering the PAN concentration and preoxidation temperature. The results showed that the O-PAN nanofiber membrane which made from PAN concentration of 14% (mass) and preoxidation temperature of 250.0 ℃ have a more optimal comprehensive performance. In the long-term separation test of SiO₂ particle (1 μm) in DMAc suspension, the permeate flux of O-PAN nanofiber membrane stabilized at 227.91 L·m^-2·h^-1 (25 ℃, 0.05 MPa) while the SiO₂ rejection above 99.6%, which showed excellent solvent resistance and separation performance. In order to further explore the application of the O-PAN nanofiber membrane, the O-PAN nanofiber membrane was treated with fluoride and used in oil/water separation process. The O-PAN nanofiber membrane after hydrophobic treatment showed excellent hydrophobicity and good oil/water separation performance with the permeate flux about 969.59 L·m^-2·h^-1 while the separation efficiency above 96.1%. The O-PAN nanofiber membrane exhibited a potential application prospect in harsh environment separation.

关键词: Poly(acrylonitrile) (PAN), Preoxidation, Nanofiber membrane, Solvent resistance, Oil/water separation

Abstract: A high performance preoxidized poly(acrylonitrile) (O-PAN) nanofiber membrane with excellent solvent resistance, thermal stability and flexibility was fabricated by the preoxidation of electrospun PAN nanofiber membrane. The performance of resultant O-PAN nanofiber membrane was optimized by altering the PAN concentration and preoxidation temperature. The results showed that the O-PAN nanofiber membrane which made from PAN concentration of 14% (mass) and preoxidation temperature of 250.0 ℃ have a more optimal comprehensive performance. In the long-term separation test of SiO₂ particle (1 μm) in DMAc suspension, the permeate flux of O-PAN nanofiber membrane stabilized at 227.91 L·m^-2·h^-1 (25 ℃, 0.05 MPa) while the SiO₂ rejection above 99.6%, which showed excellent solvent resistance and separation performance. In order to further explore the application of the O-PAN nanofiber membrane, the O-PAN nanofiber membrane was treated with fluoride and used in oil/water separation process. The O-PAN nanofiber membrane after hydrophobic treatment showed excellent hydrophobicity and good oil/water separation performance with the permeate flux about 969.59 L·m^-2·h^-1 while the separation efficiency above 96.1%. The O-PAN nanofiber membrane exhibited a potential application prospect in harsh environment separation.

Key words: Poly(acrylonitrile) (PAN), Preoxidation, Nanofiber membrane, Solvent resistance, Oil/water separation

Zhiwei Du, Jinxue Cheng, Qinglin Huang, Mingxing Chen, Changfa Xiao. Electrospinning organic solvent resistant preoxidized poly(acrylonitrile) nanofiber membrane and its properties[J]. 中国化学工程学报, 2023, 53(1): 289-299.

参考文献

[1] L. Song, Q.L. Huang, Y. Huang, R.F. Bi, C.F. Xiao, An electro-thermal braid-reinforced PVDF hollow fiber membrane for vacuum membrane distillation, J. Membr. Sci. 591 (2019) 117359.
[2] J. Gao, T.S. Chung, Influence of contaminants in glycerol/water mixtures during post-treatment on physicochemical properties and separation performance of air-dried membranes, J. Membr. Sci. 572 (2019) 223–229.
[3] Z.H. Yang, G.L. Zhang, F.N. Liu, Q. Meng, Physicochemical characteristics of hollow fiber structured packings in isopropanol/water distillation, Ind. Eng. Chem. Res. 49 (22) (2010) 11594–11601.
[4] C. Shi, J.H. Dai, X. Shen, L.Q. Peng, C. Li, X. Wang, P. Zhang, J.B. Zhao, A high-temperature stable ceramic-coated separator prepared with polyimide binder/Al₂O₃ particles for lithium-ion batteries, J. Membr. Sci. 517 (2016) 91–99.
[5] S.R. Park, Y.C. Jung, W.K. Shin, K.H. Ahn, C.H. Lee, D.W. Kim, Cross-linked fibrous composite separator for high performance lithium-ion batteries with enhanced safety, J. Membr. Sci. 527 (2017) 129–136.
[6] X.F. Hu, W.H. Lee, J.Y. Bae, J.Y. Zhao, J.S. Kim, Z. Wang, J.L. Yan, Y.M. Lee, Highly permeable polyimides incorporating Tröger's base (TB) units for gas separation membranes, J. Membr. Sci. 615 (2020) 118533.
[7] M. Minelli, M. Giacinti Baschetti, D.T. Hallinan Jr, N.P. Balsara, Study of gas permeabilities through polystyrene-block-poly(ethylene oxide) copolymers, J. Membr. Sci. 432 (2013) 83–89.
[8] H.Z. Zeng, S.J. Liu, J. Wang, Y.B. Li, L. Zhu, M. Xu, C.W. Wang, Hydrophilic SPEEK/PES composite membrane for pervaporation desalination, Sep. Purif. Technol. 250 (2020) 117265.
[9] W.Z. Ma, T.Y. Li, C. Jiang, P. Zhang, L. Deng, R. Xu, Q. Zhang, J. Zhong, H. Matsuyama, Effect of chain structure on the solvent resistance in aprotic solvents and pervaporation performance of PMDA and BTDA based polyimide membranes, J. Membr. Sci. 584 (2019) 216–226.
[10] H.A. Tsai, Y.S. Ciou, C.C. Hu, K.R. Lee, D.G. Yu, J.Y. Lai, Heat-treatment effect on the morphology and pervaporation performances of asymmetric PAN hollow fiber membranes, J. Membr. Sci. 255 (1–2) (2005) 33–47.
[11] Z.Y. Zhou, Y.X. Hu, Q. Wang, B.X. Mi, Carbon nanotube-supported polyamide membrane with minimized internal concentration polarization for both aqueous and organic solvent forward osmosis process, J. Membr. Sci. 611 (2020) 118273.
[12] Y. Zhao, Y.B. Qiu, Z.H. Mai, E. Ortega, J.N. Shen, C.J. Gao, B. van der Bruggen, Symmetrically recombined nanofibers in a high-selectivity membrane for cation separation in high temperature and organic solvent, J. Mater. Chem. A 7 (34) (2019) 20006–20012.
[13] C. Li, W.J. Sun, Z.D. Lu, X.W. Ao, S.M. Li, Ceramic nanocomposite membranes and membrane fouling: A review, Water Res. 175 (2020) 115674.
[14] B. Pulido, S. Chisca, S.P. Nunes, Solvent and thermal resistant ultrafiltration membranes from alkyne-functionalized high-performance polymers, J. Membr. Sci. 564 (2018) 361–371.
[15] Z. Yang, Y. Zhou, Z.Y. Feng, X.B. Rui, T. Zhang, Z.E. Zhang, A review on reverse osmosis and nanofiltration membranes for water purification, Polymers 11 (8) (2019) 1252.
[16] V. Lachat, V. Varshney, A. Dhinojwala, M.S. Yeganeh, Molecular origin of solvent resistance of polyacrylonitrile, Macromolecules 42 (18) (2009) 7103–7107.
[17] S.K. Nataraj, K.S. Yang, T.M. Aminabhavi, Polyacrylonitrile-based nanofibers—A state-of-the-art review, Prog. Polym. Sci. 37 (3) (2012) 487–513.
[18] J. Gao, X.X. Wang, J.S. Zhang, R.L. Guo, Preparation of heat-treated PAN/SiO₂ hybrid hollow fiber membrane contactor for acetylene absorption, Sep. Purif. Technol. 159 (2016) 116–123.
[19] Z. Wang, R. Sahadevan, C. Crandall, T.J. Menkhaus, H. Fong, Hot-pressed PAN/PVDF hybrid electrospun nanofiber membranes for ultrafiltration, J. Membr. Sci. 611 (2020) 118327.
[20] H.A. Tsai, Y.L. Chen, K.R. Lee, J.Y. Lai, Preparation of heat-treated PAN hollow fiber membranes for pervaporation of NMP/H₂O mixtures, Sep. Purif. Technol. 100 (2012) 97–105.
[21] W.B. Li, Z.H. Yang, Q. Meng, C. Shen, G.L. Zhang, Thermally stable and solvent resistant self-crosslinked TiO₂/PAN hybrid hollow fiber membrane fabricated by mutual supporting method, J. Membr. Sci. 467 (2014) 253–261.
[22] B. Zhang, D. Wang, Y.H. Wu, Z. Wang, T.H. Wang, J.S. Qiu, Modification of the desalination property of PAN-based nanofiltration membranes by a preoxidation method, Desalination 357 (2015) 208–214.
[23] W.B. Li, Z.H. Yang, G.L. Zhang, Q. Meng, Heat-treated polyacrylonitrile (PAN) hollow fiber structured packings in isopropanol (IPA)/water distillation with improved thermal and chemical stability, Ind. Eng. Chem. Res. 52 (19) (2013) 6492–6501.
[24] Z.Y. Fu, B.J. Liu, L.H. Sun, H.X. Zhang, Study on the thermal oxidative stabilization reactions and the formed structures in polyacrylonitrile during thermal treatment, Polym. Degrad. Stab. 140 (2017) 104–113.
[25] X.H. Qin, Structure and property of electrospinning PAN nanofibers by different preoxidation temperature, J. Therm. Anal. Calorim. 99 (2) (2010) 571–575.
[26] S.H. Yen, F.C. Chang, Effects of fiber processing conditions on the yield, carbon content, and diameter of lignosulfonate-based carbon fibers, BioResources 11 (4) (2016) 10158–10172.
[27] Gergin, E. Ismar, A.S. Sarac, Oxidative stabilization of polyacrylonitrile nanofibers and carbon nanofibers containing graphene oxide (GO): A spectroscopic and electrochemical study, Beilstein J. Nanotechnol. 8 (2017) 1616–1628.
[28] M. Wortmann, N. Frese, A. Mamun, M. Trabelsi, W. Keil, B. Büker, A. Javed, M. Tiemann, E. Moritzer, A. Ehrmann, A. Hütten, C. Schmidt, A. Gölzhäuser, B. Hüsgen, L. Sabantina, Chemical and morphological transition of poly(acrylonitrile)/poly(vinylidene fluoride) blend nanofibers during oxidative stabilization and incipient carbonization, Nanomaterials 10 (6) (2020) 1210.
[29] S.S. Homaeigohar, K. Buhr, K. Ebert, Polyethersulfone electrospun nanofibrous composite membrane for liquid filtration, J. Membr. Sci. 365 (1–2) (2010) 68–77.
[30] W. Jang, J. Yun, K. Jeon, H. Byun, PVdF/graphene oxide hybrid membranes via electrospinning for water treatment applications, RSC Adv. 5 (58) (2015) 46711–46717.
[31] R. Wang, Y. Liu, B. Li, B.S. Hsiao, B. Chu, Electrospun nanofibrous membranes for high flux microfiltration, J. Membr. Sci. 392-393 (2012) 167–174.
[32] M. Faccini, G. Borja, M. Boerrigter, D. Morillo Martín, S. Martìnez Crespiera, S. Vázquez-Campos, L. Aubouy, D. Amantia, Electrospun carbon nanofiber membranes for filtration of nanoparticles from water, J. Nanomater. 2015 (2015) 247471.
[33] X.W. Cao, M.L. Huang, B. Ding, J.Y. Yu, G. Sun, Robust polyacrylonitrile nanofibrous membrane reinforced with jute cellulose nanowhiskers for water purification, Desalination 316 (2013) 120–126.

Electrospinning organic solvent resistant preoxidized poly(acrylonitrile) nanofiber membrane and its properties

Electrospinning organic solvent resistant preoxidized poly(acrylonitrile) nanofiber membrane and its properties

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