Achieving high-efficient photocatalytic persulfate-activated degradation of tetracycline via carbon dots modified MIL-101(Fe) octahedrons

doi:10.1016/j.cjche.2023.10.006

中国化学工程学报 ›› 2024, Vol. 66 ›› Issue (2): 298-309.DOI: 10.1016/j.cjche.2023.10.006

• Full Length Article • 上一篇下一篇

Achieving high-efficient photocatalytic persulfate-activated degradation of tetracycline via carbon dots modified MIL-101(Fe) octahedrons

Hao Yuan¹, Xinhai Sun², Shuai Zhang¹, Weilong Shi¹, Feng Guo²

1. School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2. School of Energy and Power, Jiangsu University of Science and Technology, Zhenjiang 212003, China

收稿日期:2023-06-14 修回日期:2023-10-04 出版日期:2024-02-28 发布日期:2024-04-20
通讯作者: Weilong Shi,E-mail:shiwl@just.edu.cn;Feng Guo,E-mail:gfeng0105@126.com
基金资助:
The authors would like to acknowledge the funding support from the National Natural Science Foundation of China (21906072 and 22006057), the Natural Science Foundation of Jiangsu Province (BK20190982), “Doctor of Mass entrepreneurship and innovation” Project in Jiangsu Province.

Achieving high-efficient photocatalytic persulfate-activated degradation of tetracycline via carbon dots modified MIL-101(Fe) octahedrons

Hao Yuan¹, Xinhai Sun², Shuai Zhang¹, Weilong Shi¹, Feng Guo²

1. School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2. School of Energy and Power, Jiangsu University of Science and Technology, Zhenjiang 212003, China

Received:2023-06-14 Revised:2023-10-04 Online:2024-02-28 Published:2024-04-20
Contact: Weilong Shi,E-mail:shiwl@just.edu.cn;Feng Guo,E-mail:gfeng0105@126.com
Supported by:
The authors would like to acknowledge the funding support from the National Natural Science Foundation of China (21906072 and 22006057), the Natural Science Foundation of Jiangsu Province (BK20190982), “Doctor of Mass entrepreneurship and innovation” Project in Jiangsu Province.

摘要/Abstract

摘要： The synergistic reaction of photocatalysis and advanced oxidation is a valid strategy for the degradation of harmful antibiotic wastewater. Herein, carbon dots (CDs) modified MIL-101(Fe) octahedrons to form CDs/MIL-101(Fe) composite photocatalyst was synthesized for visible light–driven photocatalytic/persulfate(PS)-activated tetracycline(TC) degradation. The electron spin resonance (ESR) spectra, scavenging experiment and electrochemical analysis were carried out to reveal that the high visible light–driven photocatalytic degradation activity of TC over CDs/MIL-101(Fe) photocatalysts is not only ascribed to the production of free active radicals in the CDs/MIL-101(Fe)/PS system (·OH, ·SO, ¹O₂, h and ·O₂^-)but also attributed to the consumption of electrons caused by the PS, which can suppress the recombination of photo-generated carriers as well as strong light scattering and electron trapping effects of CDs. Finally, the possible degradation pathways were proposed by analyzing intermediates via liquid chromatography–mass spectrometrytechnique. This research presents a rational design conception to construct a CDs/PS-based photocatalysis/advanced oxidation technology with high-efficient degradation activity for the remediation of organic antibiotic pollutant wastewater and for the improvement of carrier transport kinetics of photocatalysts.

关键词: Carbon dots, MIL-101(Fe), Photocatalytic, Persulfate activation, Tetracycline degradation

Abstract: The synergistic reaction of photocatalysis and advanced oxidation is a valid strategy for the degradation of harmful antibiotic wastewater. Herein, carbon dots (CDs) modified MIL-101(Fe) octahedrons to form CDs/MIL-101(Fe) composite photocatalyst was synthesized for visible light–driven photocatalytic/persulfate(PS)-activated tetracycline(TC) degradation. The electron spin resonance (ESR) spectra, scavenging experiment and electrochemical analysis were carried out to reveal that the high visible light–driven photocatalytic degradation activity of TC over CDs/MIL-101(Fe) photocatalysts is not only ascribed to the production of free active radicals in the CDs/MIL-101(Fe)/PS system (·OH, ·SO, ¹O₂, h and ·O₂^-)but also attributed to the consumption of electrons caused by the PS, which can suppress the recombination of photo-generated carriers as well as strong light scattering and electron trapping effects of CDs. Finally, the possible degradation pathways were proposed by analyzing intermediates via liquid chromatography–mass spectrometrytechnique. This research presents a rational design conception to construct a CDs/PS-based photocatalysis/advanced oxidation technology with high-efficient degradation activity for the remediation of organic antibiotic pollutant wastewater and for the improvement of carrier transport kinetics of photocatalysts.

Key words: Carbon dots, MIL-101(Fe), Photocatalytic, Persulfate activation, Tetracycline degradation

Hao Yuan, Xinhai Sun, Shuai Zhang, Weilong Shi, Feng Guo. Achieving high-efficient photocatalytic persulfate-activated degradation of tetracycline via carbon dots modified MIL-101(Fe) octahedrons[J]. 中国化学工程学报, 2024, 66(2): 298-309.

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Achieving high-efficient photocatalytic persulfate-activated degradation of tetracycline via carbon dots modified MIL-101(Fe) octahedrons

Achieving high-efficient photocatalytic persulfate-activated degradation of tetracycline via carbon dots modified MIL-101(Fe) octahedrons

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