In situ growth of cobalt on ultrathin Ti3C2Tx as an efficient cocatalyst of g-C3N4 for enhanced photocatalytic CO2 reduction

doi:10.1016/j.cjche.2023.06.018

中国化学工程学报 ›› 2023, Vol. 64 ›› Issue (12): 76-86.DOI: 10.1016/j.cjche.2023.06.018

• Full Length Article • 上一篇下一篇

In situ growth of cobalt on ultrathin Ti₃C₂T_x as an efficient cocatalyst of g-C₃N₄ for enhanced photocatalytic CO₂ reduction

Tongming Su¹, Jundong Meng¹, Ya Xiao¹, Liuyun Chen¹, Hongbing Ji^1,2, Zuzeng Qin¹

1. School of Chemistry and Chemical Engineering, Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University, Nanning 530004, China;
2. Fine Chemical Industry Research Institute, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China

收稿日期:2023-02-28 修回日期:2023-05-15 出版日期:2023-12-28 发布日期:2024-02-05
通讯作者: Tongming Su,E-mail:sutm@gxu.edu.cn;Zuzeng Qin,E-mail:qinzuzeng@gxu.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (22208065), Guangxi Natural Science Foundation (2022GXNSFBA035483, 2020GXNSFDA297007), Opening Project of Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology (2021K009, 2020K002), and Special funding for ‘Guangxi Bagui Scholars’.

In situ growth of cobalt on ultrathin Ti₃C₂T_x as an efficient cocatalyst of g-C₃N₄ for enhanced photocatalytic CO₂ reduction

Tongming Su¹, Jundong Meng¹, Ya Xiao¹, Liuyun Chen¹, Hongbing Ji^1,2, Zuzeng Qin¹

1. School of Chemistry and Chemical Engineering, Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University, Nanning 530004, China;
2. Fine Chemical Industry Research Institute, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China

Received:2023-02-28 Revised:2023-05-15 Online:2023-12-28 Published:2024-02-05
Contact: Tongming Su,E-mail:sutm@gxu.edu.cn;Zuzeng Qin,E-mail:qinzuzeng@gxu.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (22208065), Guangxi Natural Science Foundation (2022GXNSFBA035483, 2020GXNSFDA297007), Opening Project of Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology (2021K009, 2020K002), and Special funding for ‘Guangxi Bagui Scholars’.

摘要/Abstract

摘要： Photocatalytic CO₂ reduction to valuable product exhibit promising prospect for solving the energy crisis and the greenhouse effect. Herein, Co-Ti₃C₂T_x/g-C₃N₄ (Co-TC/CN) composite with enhanced photocatalytic performance for converting CO₂ to CO and CH₄ was constructed by electrostatic self-assembly method. The close contact interface between Co-Ti₃C₂T_x and g-C₃N₄ nanosheets can be used as fast transport channels of photogenerated electrons and effectively promote the separation of photogenerated electrons and holes, and the interface between the Co and Ti₃C₂T_x might be the active sites for CO₂ adsorption and activation. The optimized Co-Ti₃C₂T_x/g-C₃N₄ composite exhibited the highest photocatalytic performance with the CO and CH₄ production of 55.04 μmol·g^-1 and 2.29 μmol·g^-1, respectively, which were 7.5 times and 5.8 times than those of g-C₃N₄. Furthermore, the stability of g-C₃N₄ was improved after coupling with Co-Ti₃C₂T_x.

关键词: g-C₃N₄, MXene, Cobalt, Photocatalytic, CO₂ reduction

Abstract: Photocatalytic CO₂ reduction to valuable product exhibit promising prospect for solving the energy crisis and the greenhouse effect. Herein, Co-Ti₃C₂T_x/g-C₃N₄ (Co-TC/CN) composite with enhanced photocatalytic performance for converting CO₂ to CO and CH₄ was constructed by electrostatic self-assembly method. The close contact interface between Co-Ti₃C₂T_x and g-C₃N₄ nanosheets can be used as fast transport channels of photogenerated electrons and effectively promote the separation of photogenerated electrons and holes, and the interface between the Co and Ti₃C₂T_x might be the active sites for CO₂ adsorption and activation. The optimized Co-Ti₃C₂T_x/g-C₃N₄ composite exhibited the highest photocatalytic performance with the CO and CH₄ production of 55.04 μmol·g^-1 and 2.29 μmol·g^-1, respectively, which were 7.5 times and 5.8 times than those of g-C₃N₄. Furthermore, the stability of g-C₃N₄ was improved after coupling with Co-Ti₃C₂T_x.

Key words: g-C₃N₄, MXene, Cobalt, Photocatalytic, CO₂ reduction

Tongming Su, Jundong Meng, Ya Xiao, Liuyun Chen, Hongbing Ji, Zuzeng Qin. In situ growth of cobalt on ultrathin Ti₃C₂T_x as an efficient cocatalyst of g-C₃N₄ for enhanced photocatalytic CO₂ reduction[J]. 中国化学工程学报, 2023, 64(12): 76-86.

参考文献

[1] I. Shown, S. Samireddi, Y.C. Chang, R. Putikam, P.H. Chang, A. Sabbah, F.Y. Fu, W.F. Chen, C.I. Wu, T.Y. Yu, P.W. Chung, M.C. Lin, L.C. Chen, K.H. Chen, Carbon-doped SnS₂ nanostructure as a high-efficiency solar fuel catalyst under visible light, Nat. Commun. 9 (2018) 169.
[2] A. Kumar, P. Raizada, V. Kumar Thakur, V. Saini, A. Aslam Parwaz Khan, N. Singh, P. Singh, An overview on polymeric carbon nitride assisted photocatalytic CO₂ reduction: Strategically manoeuvring solar to fuel conversion efficiency, Chem. Eng. Sci. 230 (2021) 116219.
[3] M. Zhang, M. Lu, Z.L. Lang, J.A. Liu, M. Liu, J.N. Chang, L.Y. Li, L.J. Shang, M. Wang, S.L. Li, Y.Q. Lan, Semiconductor/covalent-organic-framework Z-scheme heterojunctions for artificial photosynthesis, Angew. Chem. Int. Ed. 59 (16) (2020) 6500–6506.
[4] L.Y. Chen, K.L. Huang, Q.R. Xie, S.M. Lam, J.C. Sin, T.M. Su, H.B. Ji, Z.Z. Qin, The enhancement of photocatalytic CO₂ reduction by the in situ growth of TiO₂ on Ti₃C₂ MXene, Catal. Sci. Technol. 11 (4) (2021) 1602–1614.
[5] J.M. Yang, X.W. Zhu, Q. Yu, M.Q. He, W. Zhang, Z. Mo, J.J. Yuan, Y.B. She, H. Xu, H.M. Li, Multidimensional In₂O₃/In₂S₃ heterojunction with lattice distortion for CO₂ photoconversion, Chin. J. Catal. 43 (5) (2022) 1286–1294.
[6] G.M. Huang, S.Z. Li, L.J. Liu, L.F. Zhu, Q. Wang, Ti₃C₂ MXene-modified Bi₂WO₆ nanoplates for efficient photodegradation of volatile organic compounds, Appl. Surf. Sci. 503 (2020) 144183.
[7] A. Fujishima, K. Honda, Electrochemical photolysis of water at a semiconductor electrode, Nature 238 (5358) (1972) 37–38.
[8] M. Halmann, Photoelectrochemical reduction of aqueous carbon dioxide on p-type gallium phosphide in liquid junction solar cells, Nature 275 (5676) (1978) 115–116.
[9] H.P. Li, J.Y. Liu, W.G. Hou, N. Du, R.J. Zhang, X.T. Tao, Synthesis and characterization of g-C₃N₄/Bi₂MoO₆ heterojunctions with enhanced visible light photocatalytic activity, Appl. Catal. B: Environ. 160–161 (2014) 89–97.
[10] Q.L. Zhang, P.F. Chen, L. Chen, M.F. Wu, X.Q. Dai, P.X. Xing, H.J. Lin, L.H. Zhao, Y.M. He, Facile fabrication of novel Ag₂S/K-g-C₃N₄ composite and its enhanced performance in photocatalytic H₂ evolution, J. Colloid Interface Sci. 568 (2020) 117–129.
[11] H. Zhao, Z.F. Jiang, K.M. Xiao, H.L. Sun, H.S. Chan, T.H. Tsang, S.J. Yang, P.K. Wong, Photo-assisted separation of noble-metal-free oxidation and reduction cocatalysts for graphitic carbon nitride nanosheets with efficient photocatalytic hydrogen evolution, Appl. Catal. B 280 (2021) 119456.
[12] C.C. Han, P.F. Su, B.H. Tan, X.G. Ma, H. Lv, C.Y. Huang, P. Wang, Z.F. Tong, G. Li, Y.Z. Huang, Z.F. Liu, Defective ultra-thin two-dimensional g-C₃N₄ photocatalyst for enhanced photocatalytic H₂ evolution activity, J. Colloid Interface Sci. 581 (2021) 159–166.
[13] J.Z. Liao, W. Cui, J.Y. Li, J.P. Sheng, H. Wang, X.A. Dong, P. Chen, G.M. Jiang, Z.M. Wang, F. Dong, Nitrogen defect structure and NO+ intermediate promoted photocatalytic NO removal on H₂ treated g-C₃N₄, Chem. Eng. J. 379 (2020) 122282.
[14] J.M. Yang, L.Q. Jing, X.W. Zhu, W. Zhang, J.J. Deng, Y.B. She, K.Q. Nie, Y.C. Wei, H.M. Li, H. Xu, Modulating electronic structure of lattice O-modified orange polymeric carbon nitrogen to promote photocatalytic CO₂ conversion, Appl. Catal. B 320 (2023) 122005.
[15] H.J. Dong, Y. Zuo, N. Song, S.H. Hong, M.Y. Xiao, D.Q. Zhu, J.X. Sun, G. Chen, C.M. Li, Bimetallic synergetic regulating effect on electronic structure in cobalt/vanadium co-doped carbon nitride for boosting photocatalytic performance, Appl. Catal. B 287 (2021) 119954.
[16] N. Tian, H.W. Huang, S.B. Wang, T.R. Zhang, X. Du, Y.H. Zhang, Facet-charge-induced coupling dependent interfacial photocharge separation: A case of BiOI/g-C₃N₄ p-n junction, Appl. Catal. B 267 (2020) 118697.
[17] X.Q. Yan, H. An, Z.H. Chen, G.D. Yang, Significantly enhanced charge transfer efficiency and surface reaction on NiP₂/g-C₃N₄ heterojunction for photocatalytic hydrogen evolution, Chin. J. Chem. Eng. 43 (2022) 31–39.
[18] P.F. Chen, L. Chen, S.F. Ge, W.Q. Zhang, M.F. Wu, P.X. Xing, T.B. Rotamond, H.J. Lin, Y. Wu, Y.M. He, Microwave heating preparation of phosphorus doped g-C₃N₄ and its enhanced performance for photocatalytic H₂ evolution in the help of Ag₃PO₄ nanoparticles, Int. J. Hydrog. Energy 45 (28) (2020) 14354–14367.
[19] Q.C. Lin, Z.S. Li, T.J. Lin, B.L. Li, X.C. Liao, H.Q. Yu, C.L. Yu, Controlled preparation of P-doped g-C₃N₄ nanosheets for efficient photocatalytic hydrogen production, Chin. J. Chem. Eng. 28 (10) (2020) 2677–2688.
[20] Z.H. Chen, F. Guo, H.R. Sun, Y.X. Shi, W.L. Shi, Well-designed three-dimensional hierarchical hollow tubular g-C₃N₄/ZnIn₂S₄ nanosheets heterostructure for achieving efficient visible-light photocatalytic hydrogen evolution, J. Colloid Interface Sci. 607 (2022) 1391–1401.
[21] Q. Xie, W.M. He, S.W. Liu, C.H. Li, J.F. Zhang, P.K. Wong, Bifunctional S-scheme g-C₃N₄/Bi/BiVO₄ hybrid photocatalysts toward artificial carbon cycling, Chin. J. Catal. 41 (1) (2020) 140–153.
[22] Z.Q. Liang, X.F. Meng, Y.J. Xue, X.Y. Chen, Y.L. Zhou, X.L. Zhang, H.Z. Cui, J. Tian, Facile preparation of metallic 1T phase molybdenum selenide as cocatalyst coupled with graphitic carbon nitride for enhanced photocatalytic H₂ production, J. Colloid Interface Sci. 598 (2021) 172–180.
[23] C. Cheng, L.H. Mao, J.W. Shi, F. Xue, S.C. Zong, B.T. Zheng, L.J. Guo, NiCo₂O₄ nanosheets as a novel oxygen-evolution-reaction cocatalyst in situ bonded on the g-C₃N₄ photocatalyst for excellent overall water splitting, J. Mater. Chem. A 9 (20) (2021) 12299–12306.
[24] K. Li, Y.Z. Lin, K. Wang, Y.J. Wang, Y. Zhang, Y.Z. Zhang, F.T. Liu, Rational design of cocatalyst system for improving the photocatalytic hydrogen evolution activity of graphite carbon nitride, Appl. Catal. B 268 (2020) 118402.
[25] J.Z. Jiang, Z.G. Xiong, H.T. Wang, K. Xiang, P.X. Wu, J. Zou, Anchoring Pt nanoparticles and Ti₃C₂T_x MXene nanosheets on CdS nanospheres as efficient synergistic photocatalysts for hydrogen evolution, Sci. China Technol. Sci. 65 (12) (2022) 3020–3028.
[26] C. Jin, S.S. Rao, J. Xie, Z.T. Sun, J.S. Gao, Y. Li, B. Li, S.W. Liu, L. Liu, Q.Q. Liu, J. Yang, Enhanced photocatalytic antibacterial performance by hierarchical TiO₂/W₁₈O₄₉ Z-scheme heterojunction with Ti₃C₂T_x-MXene cocatalyst, Chem. Eng. J. 447 (2022) 137369.
[27] Y.X. Liu, Y.L. Li, A.J. Li, Y. Gao, X.F. Wang, R. Fujii, S.I. Sasaki, Squaraine dye/Ti₃C₂T_x MXene organic-inorganic hybrids for photocatalytic hydrogen evolution, J. Colloid Interface Sci. 633 (2023) 218–225.
[28] T.M. Su, X.H. Ma, J.H. Tong, H.B. Ji, Z.Z. Qin, Z.L. Wu, Surface engineering of MXenes for energy and environmental applications, J. Mater. Chem. A 10 (19) (2022) 10265–10296.
[29] A. Rafieerad, W.A. Yan, K.N. Alagarsamy, A. Srivastava, N. Sareen, R.C. Arora, S. Dhingra, Fabrication of smart tantalum carbide MXene quantum dots with intrinsic immunomodulatory properties for treatment of allograft vasculopathy (adv. funct. mater. 46/2021), Adv. Funct. Mater. 31 (46) (2021) 2106786.
[30] T.M. Su, C.Z. Men, L.Y. Chen, B.X. Chu, X.A. Luo, H.B. Ji, J.H. Chen, Z.Z. Qin, Sulfur vacancy and Ti₃C₂T_x cocatalyst synergistically boosting interfacial charge transfer in 2D/2D Ti₃C₂T_x /ZnIn₂S₄ heterostructure for enhanced photocatalytic hydrogen evolution, Adv. Sci. 9 (4) (2022) 2103715.
[31] S.J. Wu, J.G. Sun, Q. Li, Z.D. Hood, S.Z. Yang, T.M. Su, R. Peng, Z.L. Wu, W.W. Sun, P.R.C. Kent, B. Jiang, M.F. Chisholm, Effects of surface terminations of 2D Bi₂WO₆ on photocatalytic hydrogen evolution from water splitting, ACS Appl. Mater. Interfaces 12 (17) (2020) 20067–20074.
[32] Y. Xiao, C.Z. Men, B.X. Chu, Z.Z. Qin, H.B. Ji, J.H. Chen, T.M. Su, Spontaneous reduction of copper on Ti₃C₂T_x as fast electron transport channels and active sites for enhanced photocatalytic CO₂ reduction, Chem. Eng. J. 446 (2022) 137028.
[33] Y.L. Yang, D.N. Zhang, J.J. Fan, Y.L. Liao, Q.J. Xiang, Construction of an ultrathin S-scheme heterojunction based on few-layer g-C₃N₄ and monolayer Ti₃C₂ t x MXene for photocatalytic CO₂ reduction, Sol. RRL 5 (2) (2021) 2000351.
[34] X. Li, Y. Bai, X. Shi, J.D. Huang, K. Zhang, R. Wang, L.Q. Ye, Mesoporous g-C₃N₄/MXene (Ti₃C₂T_x) heterojunction as a 2D electronic charge transfer for efficient photocatalytic CO₂ reduction, Appl. Surf. Sci. 546 (2021) 149111.
[35] Q. Song, J.H. Hu, Y.M. Zhou, Q.J. Ye, X.L. Shi, D. Li, D.L. Jiang, Carbon vacancy-mediated exciton dissociation in Ti₃C₂T_x/g-C₃N₄ Schottky junctions for efficient photoreduction of CO₂, J. Colloid Interface Sci. 623 (2022) 487–499.
[36] S.Y. Zheng, S.N. Peng, Z.M. Wang, J.T. Huang, X.D. Luo, L. Han, X.B. Li, Schottky-structured 0D/2D composites via electrostatic self-assembly for efficient photocatalytic hydrogen evolution, Ceram. Int. 47 (20) (2021) 28304–28311.
[37] K.F. Yu, S.M. Wang, Q. Li, T.T. Hou, Y. Xin, R. He, W.H. Zhang, S.Q. Liang, L.B. Wang, W.K. Zhu, Au atoms doped in Ti₃C₂T_x MXene: Benefiting recovery of oxygen vacancies towards photocatalytic aerobic oxidation, Nano Res. 15 (4) (2022) 2862–2869.
[38] S.W. Cao, J. Jiang, B.C. Zhu, J.G. Yu, Shape-dependent photocatalytic hydrogen evolution activity over a Pt nanoparticle coupled g-C₃N₄ photocatalyst, Phys. Chem. Chem. Phys. 18 (28) (2016) 19457–19463.
[39] W.J. Ong, L.L. Tan, S.P. Chai, S.T. Yong, Heterojunction engineering of graphitic carbon nitride (g-C₃N₄) via Pt loading with improved daylight-induced photocatalytic reduction of carbon dioxide to methane, Dalton Trans. 44 (3) (2015) 1249–1257.
[40] Y. Bai, T. Chen, P.Q. Wang, L. Wang, L.Q. Ye, X. Shi, W. Bai, Size-dependent role of gold in g-C₃N₄/BiOBr/Au system for photocatalytic CO₂ reduction and dye degradation, Sol. Energy Mater. Sol. Cells 157 (2016) 406–414.
[41] Z. Li, Y.R. Cui, Z.W. Wu, C. Milligan, L. Zhou, G. Mitchell, B.A. Xu, E.Z. Shi, J.T. Miller, F.H. Ribeiro, Y.E. Wu, Reactive metal–support interactions at moderate temperature in two-dimensional niobium-carbide-supported platinum catalysts, Nat. Catal. 1 (5) (2018) 349–355.
[42] J.Q. Zhang, Y.F. Zhao, X. Guo, C. Chen, C.L. Dong, R.S. Liu, C.P. Han, Y.D. Li, Y. Gogotsi, G.X. Wang, Single platinum atoms immobilized on an MXene as an efficient catalyst for the hydrogen evolution reaction, Nat. Catal. 1 (12) (2018) 985–992.
[43] S.X. Min, Y. Xue, F. Wang, Z.G. Zhang, H.T. Zhu, Ti₃C₂T_x MXene nanosheet-confined Pt nanoparticles efficiently catalyze dye-sensitized photocatalytic hydrogen evolution reaction, Chem. Commun. 55 (71) (2019) 10631–10634.
[44] J. Low, L.Y. Zhang, T. Tong, B.J. Shen, J.G. Yu, TiO₂/MXene Ti₃C₂ composite with excellent photocatalytic CO₂ reduction activity, J. Catal. 361 (2018) 255–266.
[45] A. Shahzad, K. Rasool, M. Nawaz, W. Miran, J. Jang, M. Moztahida, K.A. Mahmoud, D.S. Lee, Heterostructural TiO₂/Ti₃C₂T_x (MXene) for photocatalytic degradation of antiepileptic drug carbamazepine, Chem. Eng. J. 349 (2018) 748–755.
[46] G.J. Lan, H.Y. Li, J.Q. Shen, Bimetallic zeolitic imidazole framework derived[email protected]materials as oxygen reduction reaction catalysts application for microbial fuel cells, Int. J. Hydrog. Energy 47 (19) (2022) 10701–10714.
[47] F. He, B.C. Zhu, B. Cheng, J.G. Yu, W. Ho, W. Macyk, 2D/2D/0D TiO₂/C₃N₄/Ti₃C₂ MXene composite S-scheme photocatalyst with enhanced CO₂ reduction activity, Appl. Catal. B 272 (2020) 119006.
[48] M. Ghidiu, M. Naguib, C. Shi, O. Mashtalir, L.M. Pan, B. Zhang, J. Yang, Y. Gogotsi, S.J.L. Billinge, M.W. Barsoum, Synthesis and characterization of two-dimensional Nb₄C₃ (MXene), Chem. Commun. 50 (67) (2014) 9517–9520.
[49] B. Li, W. Peng, J. Zhang, J.C. Lian, T. Huang, N. Cheng, Z.Y. Luo, W.Q. Huang, W.Y. Hu, A.L. Pan, L. Jiang, G.F. Huang, One-photon excitation pathway: High-throughput one-photon excitation pathway in 0D/3D heterojunctions for visible-light driven hydrogen evolution (adv. funct. mater. 18/2021), Adv. Funct. Mater. 31 (18) (2021)2100816.
[50] J.M. Hu, J. Ding, Q. Zhong, Ultrathin 2D Ti₃C₂ MXene Co-catalyst anchored on porous g-C₃N₄ for enhanced photocatalytic CO₂ reduction under visible-light irradiation, J. Colloid Interface Sci. 582 (2021) 647–657.
[51] Q. Xue, H.J. Zhang, M.S. Zhu, Z.X. Pei, H.F. Li, Z.F. Wang, Y. Huang, Y. Huang, Q.H. Deng, J.E. Zhou, S.Y. Du, Q. Huang, C.Y. Zhi, Photoluminescent Ti₃C₂MXene quantum dots for multicolor cellular imaging, Adv. Mater. 29 (15) (2017) 1604847.
[52] W.Y. Chen, B. Han, Y.L. Xie, S.J. Liang, H. Deng, Z. Lin, Ultrathin Co-Co LDHs nanosheets assembled vertically on MXene: 3D nanoarrays for boosted visible-light-driven CO₂ reduction, Chem. Eng. J. 391 (2020) 123519.
[53] S.C. Meng, P.F. An, L.J. Chen, S.C. Sun, Z.K. Xie, M. Chen, D.L. Jiang, Integrating Ru-modulated CoP nanosheets binary co-catalyst with 2D g-C₃N₄ nanosheets for enhanced photocatalytic hydrogen evolution activity, J. Colloid Interface Sci. 585 (2021) 108–117.
[54] Y.L. Sun, D. Jin, Y. Sun, X. Meng, Y. Gao, Y. Dall’Agnese, G. Chen, X.F. Wang, G-C₃N₄/Ti₃C₂T_x (MXenes) composite with oxidized surface groups for efficient photocatalytic hydrogen evolution, J. Mater. Chem. A 6 (19) (2018) 9124–9131.

In situ growth of cobalt on ultrathin Ti₃C₂T_x as an efficient cocatalyst of g-C₃N₄ for enhanced photocatalytic CO₂ reduction

In situ growth of cobalt on ultrathin Ti₃C₂T_x as an efficient cocatalyst of g-C₃N₄ for enhanced photocatalytic CO₂ reduction

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Ting Li, Hongxia Guo, Xiao Wang, Huan Wang, Li Liu, Wenquan Cui, Xiaoran Sun, Yinghua Liang. Loading CuO on the surface of MgO with low-coordination basic O^2- sites for effective enhanced CO₂ capture and photothermal synergistic catalytic reduction of CO₂ to ethanol[J]. 中国化学工程学报, 2023, 61(9): 58-67.
[2]	Pengcheng Hu, Ruimin Chai, Ping Wang, Jinke Yang, Shufeng Zhou. Supercapacitive properties of MnNiS_x@Ti₃C₂T_x MXene positive electrode assisted by functionalized ionic liquid[J]. 中国化学工程学报, 2023, 61(9): 102-109.
[3]	Ali Nikkhah, Hasan Nikkhah, Hadis langari, Alireza Nouri, Abdul Wahab Mohammad, Ang Wei Lun, Ng law Yong, Rosiah Rohani, Ebrahim Mahmoudi. MXene: From synthesis to environment remediation[J]. 中国化学工程学报, 2023, 61(9): 260-280.
[4]	Yi Wu, Pengfei Song, Ningyan Li, Yanan Jiang, Yuan Liu. Molybdenum tailored Co⁰/Co²⁺ active pairs on a perovskite-type oxide for direct ethanol synthesis from syngas[J]. 中国化学工程学报, 2023, 59(7): 279-289.
[5]	Iltaf Khan, Chunjuan Wang, Shoaib Khan, Jinyin Chen, Aftab Khan, Sayyar Ali Shah, Aihua Yuan, Sohail Khan, Mehwish K. Butt, Humaira Asghar. Bio-capped and green synthesis of ZnO/g-C₃N₄ nanocomposites and its improved antibiotic and photocatalytic activities: An exceptional approach towards environmental remediation[J]. 中国化学工程学报, 2023, 56(4): 215-224.
[6]	Jingjing Pan, Haoran Sun, Keyi Chen, Yuhao Zhang, Pengnian Shan, Weilong Shi, Feng Guo. Nanodiamonds decorated yolk-shell ZnFe₂O₄ sphere as magnetically separable and recyclable composite for boosting antibiotic degradation performance[J]. 中国化学工程学报, 2023, 54(2): 162-172.
[7]	Umsalama Abuelgasim Abubakr Yasin, Zhixin Jia, Ziwen Qin, Tianyu Guo, Ruihua Zhao, Jianping Du. Synergistic effect of CuO coupled with MoS₂ for enhanced photodegradation of organic dyes under visible light[J]. 中国化学工程学报, 2023, 64(12): 96-105.
[8]	Gaiqin Miao, Lifei Liu, Xia An, Xu Wu. Construction of CuNiAl-LDHs electrocatalyst with rich-Cu⁺ and —OH for highly selective reduction of CO₂ to methanol[J]. 中国化学工程学报, 2023, 64(12): 156-167.
[9]	Supeng Yu, Ting Xiang, Njud S. Alharbi, Bothaina A. Al-aidaroos, Changlun Chen. Recent development of catalytic strategies for sustainable ammonia production[J]. 中国化学工程学报, 2023, 62(10): 65-113.
[10]	Duanlian Tang, Xiaoyan Chen, Jiayan Yan, Zhuo Xiong, Xiaoyu Lou, Changshen Ye, Jie Chen, Ting Qiu. Facile one-pot synthesis of a BiOBr/Bi₂WO₆ heterojunction with enhanced visible-light photocatalytic activity for tetracycline degradation[J]. 中国化学工程学报, 2023, 53(1): 222-231.
[11]	Weilong Shi, Jie Gao, Haoran Sun, Zhongyi Liu, Feng Guo, Lijing Wang. Highly efficient visible/near-infrared light photocatalytic degradation of antibiotic wastewater over 3D yolk-shell ZnFe₂O₄ supported 0D carbon dots with up-conversion property[J]. 中国化学工程学报, 2022, 49(9): 213-223.
[12]	Feng Guo, Chunli Shi, Wei Sun, Yanan Liu, Xue Lin, Weilong Shi. Pomelo biochar as an electron acceptor to modify graphitic carbon nitride for boosting visible-light-driven photocatalytic degradation of tetracycline[J]. 中国化学工程学报, 2022, 48(8): 1-11.
[13]	Jing Gao, Zhijun Ma, Fuli Liu, Cunxin Chen. Synthesis of carbon-coated cobalt ferrite core–shell structure composite: A method for enhancing electromagnetic wave absorption properties by adjusting impedance matching[J]. 中国化学工程学报, 2022, 47(7): 206-217.
[14]	Hao Zhou, Qi Yin. Hydrothermal preparation of Nb-doped NaTaO₃ with enhanced photocatalytic activity for removal of organic dye[J]. 中国化学工程学报, 2022, 46(6): 142-149.
[15]	Xinyu Chen, Shuo Shi, Ximei Han, Min Li, Ying Nian, Jing Sun, Wentao Zhang, Tianli Yue, Jianlong Wang. Insights into high-efficient removal of tetracycline by a codoped mesoporous carbon adsorbent[J]. 中国化学工程学报, 2022, 44(4): 148-156.