Volumetric and Viscometric Studies of 4-Aminobutyric Acid in Aqueous Solutions of Salbutamol Sulphate at 308.15,313.15 and 318.15K

摘要/Abstract

摘要： Density (ρ) and viscosity (η) measurements were carried out for 4-aminobutyric acid in 0.0041,0.0125 and 0.0207 mol·L^-1 aqueous salbutamol sulphate at T=308.15,313.15 and 318.15K.The measured values of density and viscosity were used to estimate some important parameters such as apparent molar volume V_φ,limiting apparent molar volume V_φ⁰ transfer volume △V_φ⁰,hydration number n_H,second derivative of infinite dilution of partial molar volume with temperature ∂²V_φ⁰/∂T²,viscosity B-coefficients,variation of B with temperature dB/dT,free energy of activation per mole of solvent △μ₁^0* and solute △μ₂^0*,activation entropy △S₂^0* and activation enthalpy △H₂^0* of the amino acids.These parameters have been interpreted in terms of solute-solute and solute-solvent interactions and structure making/breaking ability of solutes in the given solution.

关键词: density, standard partial molar volume, hydration number, relative viscosity, B-coefficient, activation parameters

Abstract: Density (ρ) and viscosity (η) measurements were carried out for 4-aminobutyric acid in 0.0041,0.0125 and 0.0207 mol·L^-1 aqueous salbutamol sulphate at T=308.15,313.15 and 318.15K.The measured values of density and viscosity were used to estimate some important parameters such as apparent molar volume V_φ,limiting apparent molar volume V_φ⁰ transfer volume △V_φ⁰,hydration number n_H,second derivative of infinite dilution of partial molar volume with temperature ?²V_φ⁰/?T2,viscosity B-coefficients,variation of B with temperature dB/dT,free energy of activation per mole of solvent △μ₁^0* and solute △μ₂^0*,activation entropy △S₂^0* and activation enthalpy △H₂^0* of the amino acids.These parameters have been interpreted in terms of solute-solute and solute-solvent interactions and structure making/breaking ability of solutes in the given solution.

Key words: density, standard partial molar volume, hydration number, relative viscosity, B-coefficient, activation parameters

K. Rajagopal, S. S. Jayabalakrishnan. Volumetric and Viscometric Studies of 4-Aminobutyric Acid in Aqueous Solutions of Salbutamol Sulphate at 308.15,313.15 and 318.15K[J]. , 2009, 17(5): 796-804.

参考文献

1 Ali, A., Hyder, S., Sabir, S., Chand, D., Nain, A.K., “Volumetric, viscometric and refractive index behavior of α-amino acids and their groups contribution in aqueous D-glucose solutions at different temperatures”, J. Chem. Thermodynamics, 38, 136-143 (2006).
2 Wadi, R.K., Ramasami, P., “Partial molar volumes and adiabatic compressibilities of transfer of glycine and DL-alanine from water to aqueous sodium sulphate at 288.15, 298.15 and 308.15 K”, J. Chem. Soc. Faraday. Trans., 93, 243-247 (1997).
3 Yan, Z., Wang, J., Kong, W., Lu, J., “Effects of temperature on volumetric and viscosity properties of some α-amino acids in aqueous calcium chloride solutions”, Fluid Phase Equilib., 215, 143-150 (2004).
4 Banipal, T.S., Sehgal, G., “Partial molar adiabatic compressibility of transfer of some amino acids from water to aqueous sodium chloride and aqueous glucose solutions”, Thermochem. Acta, 265, 175-183 (1995).
5 Yan, Z., Wang, J., Kong, W., Lu, J., “Effect of temperature on volumetric and viscosity properties of some α-amino acids in aqueous calcium chloride solutions”, Fluid Phase Equilibria., 215, 130-143 (2004).
6 Soto, A., Arce, A., Kheshkbarchi, M.K., “Experimental data and modeling of apparent molar volumes, isentropic compressibilities and refractive indices in aqueous solutions of glycine+NaCl”, Biophys. Chem., 74, 165-173 (1998).
7 Wadi, R.K., Goyal, R.K., “Densities, viscosity and applications of transition-state theory for water and potassium thiocyanate+amino acid solutions at 288.15-308.15 K”, J. Chem. Eng. Data., 37, 377-386 (1992).
8 Kharakoz, D.P., “Volumetric properties of proteins and their analogues in diluted water solutions partial molar volumes of amino acids at 15-55℃”, Biophys. Chem., 34, 115-125 (1989).
9 Kharakoz, D.P., “Partial volumes and compressibilities of extended polypeptide chains in aqueous solutions additivity scheme and implications of protein unfolding at normal and high pressure”, Bio-Chem., 36, 10276-10285 (1997).
10 Sakurai, M., Nakumaura, T., Takenaka, N., “Apparent molar volumes and apparent molar adiabatic compressions of water in some alcohols”, Bull. Chem. Soc. Jpn., 67, 352 (1994).
11 Kikuchi, M., Sakurai, M., Nitta, N., “Partial molar volumes and isentropic compressibilities of N-acetyl amino acid amides in dilute aqueous solutions at (5,15,25,35 and 45)℃”, J. Chem. Eng. Data, 41, 1439-1445 (1996).
12 Pal, A., Kumar, S., “Volumetric and viscometric studies of glycine in binary aqueous solutions of sucrose at different temperatures”, Ind. J. Chem., 44A, 469-475 (2005).
13 Ren, X., Hu, X., Lin, R., Zong, H., “Apparent molar volumes of L-glycine, L-alanine and L-serine in water + dimethyl formamide mixtures at 298.15 K”, J. Chem. Eng. Data, 43, 700-702 (1998).
14 Islam, M.N., Wadi, R.K., “Temperature dependence of apparent molar volumes and viscosity coefficients of amino acids in aqueous sodium sulphate solutions from 15 to 35℃”, Phys. Chem. Liq., 41, 533-544 (2003).
15 Wadi, R.K., Goyal, R.K., “Temperature dependence of apparent molar volume and viscosity coefficients of amino acids in aqueous potassium thiocyanate solutions from 15 to 35℃”, J. Solution Chem., 21, 163-170 (1992).
16 Bhattaacharyya, M.M., Sengupta, M., “Ion-solvent interaction of amino acids:IV. Apparent molar volumes of amino acids in natural acidic and alkaline media at different temperatures”, J. Indian Chem. Soc., 62, 959-964 (1985).
17 Chalikian, T.V., Sarvazyan, A.V., Breslauer, K.J., “Partial molar volumes expansibilities and compressibilities of α,ω-amino carboxycylic acids in aqueous solutions between 18 and 55℃”, J. Phys. Chem., 97, 13017-13026 (1993).
18 Beli bagli, K., Ayranci, E., “Viscosities and apparent molar volumes of some amino acids in water and in 6M guanidine hydrochloride at 25℃”, J. Solutions Chem., 19, 867-882 (1990).
19 Friedman, H., Krishnan, C.V., Thermodynamics of Ion Hydration, in:Water-A comprehensive treatise, Plenum press, New York, Vol. 3 (Chapter 1), 1-118 (1973).
20 Bhat, R., Kishore, N., Ahluwalia, J.C., “Thermodynamic studies of transfer of some amino acids and peptides from water to aqueous glucose and sucrose solutions at 298.15 K”, J. Chem. Faraday Trans. I, 84 (8), 2651-2665 (1988).
21 Li, S., Sang, W., Lin, R., “Partial molar volumes of glycine, L-alanine and L-serine in aqueous glucose solutions at T=298.15K”, J. Chem. Thermodynamics, 34, 1761-1768 (2002).
22 Liu, Q., Hu, X., Lin, R., Sang, W., Li, S., “Limiting partial molar volumes of glycine L-alanine and L-serine in ethylene glycol + water mixtures at 298.15 K”, J. Chem. Eng. Data, 46, 522-525 (2001).
23 Zhao, C., Ma, P., Li, J., “Partial molar volumes and viscosity B-coefficients of arginine in aqueous glucose, sucrose and L-ascorbic acid solutions at T = 298.15 K”, J. Chem. Thermodynamics, 37, 37-42 (2005).
24 Natarajan, M., Wadi, R.K., Gaur, H.C., “Apparent molar volumes and viscosities of some α, ωamino acids in aqueous ammonium chloride solutions at T = 298.15 K”, J. Chem. Eng. Data, 35, 87-93 (1990).
25 Franks, F., Quickenden, M.A., Reig, D.S., Watson, B., “Calorimetric and volumetric studies of dilute aqueous of cycle ether derivatives”, Trans. Faraday. Soc. Trans. I, 66, 582-589 (1970).
26 Millero, F.J., Surdo, A.L., Shin, C., “The apparent molar volumes and adiabatic compressibilities of aqueous amino acids at 25℃”, J. Phys. Chem., 82, 784-792 (1978).
27 Pal, A., Kumar, K., “Volumetric and ultrasonic studies of some amino acids in binary aqueous solutions of MgCl 2 ·6H 2 O at 298.15 K”, J. Mol. Liq., 121, 148-155 (2005).
28 Millero, F.J, Leppa, G.K., Lepple, F.K., Hoff, E.V., “Isothermal compressibility of aqueous sodium chloride, magnesium chloride, sodium sulphate and magnesium sulphate solutions from 0 to 45℃ at 1 atm”, J. Phys. Chem., 78, 1636-1643 (1974).
29 Romero, C.M., Negrete, F., “Effect of temperature on partial molar volumes and viscosities of aqueous solutions of α-DL-aminobutyric and DL-norvaline and DL-norLeucine”, Phys. Chem. Liq., 42, 261-267 (2004).
30 McMillan, W.G., Mayer, J.E., “The statistical thermodynamics of multi component system”, J. Chem. Phys., 13, 276-305 (1945)
31 Banipal, T.S., Kaur, D., Banipal, P.K., “Effect of magnesium acetate on the volumetric and transport behaviour of some amino acids in aqueous solutions at 298.15 K”, J. Chem. Thermodynamics, 38, 1214-1226 (2006).
32 Hepler, L., “Thermal expansion and structure in water and aqueous solutions”, Can. J. Chem., 47, 4613-4617 (1969).
33 Pal, A., Kumar, S., “Viscometric and volumetric studies of some amino acids in binary aqueous solutions of urea at various temperatures”, J. Mol. Liq., 109, 23-31 (2004).
34 Lark, B.S., Patyar, P., Banipal, T.S., Kishore, N., “Densities, parial molar volumes and heat capacities of glycine, L-alanine and L-leucine in aqueous magnesium chloride solutions at different temperatures”, J. Chem. Eng. data., 49, 553-565 (2004).
35 Jones, G., Dole, M., “The viscosity of aqueous solutions of strong electrolytes with special reference to barium chloride”, J. Am. Chem. Soc., 51, 2950-2964 (1929).
36 Bhattacharyya, M.M., Sengupta, M., “Ion solvent interaction of amino acids;part II. Amino acids in aqueous solutions in the cationic, anionic and zwitterionic forms”, Z. Phys. Chem. (N.F.), 133, 79-91 (1982).
37 Jenkins, H.D.B., Marcus, Y., “Viscosity B-coefficients of ions in solutions”, Chem. Rev. ,95, 2695-2724 (1995).
38 Bai, T.C., Yan, G.B., “Viscosity B-coefficients and activation parameters for viscous flow of a solution of heptanedioic acid in aqueous sucrose solutions”, Carbohydrate Research, 338, 2921-2927 (2003).
39 Tsangins, J.M., Martin, R.B., “Viscosities of aqueous solutions of dipolar ions”, Arch. Biochem. Biophys., 112, 267-272 (1965).
40 Kaminsky, M., “Densities and apparent molal volumes of some aqueous rare earth solutions at 25℃”, Discuss Faraday. Soc., 24, 171 (1957).
41 Sharma, T.S., Ahluwalia, J.C., “Experimental studies on the structure of aqueous solutions of hydrophobic solutes”, Chem. Soc. Rev., 2, 203-232 (1973).
42 Feakins, D., Bates, F.M., Waghorne, W.E., Lawrence, K.G., “Relative viscosities and quasi thermodynamics of solutions of tert-butyl alcohol in the methanol water system;a different view of the alkyl-water interaction”, J. Chem. Soc. Faraday Trans., 89, 3381-3388 (1993).
43 Glasstone, S., Laidler, K., Eyring, H., The Theory of Rate Processes, McGraw-hill, New York, 477 (1941).
44 Mishra, A.P., Gautam, S.K., “Viscometric and volumetric studies of some transition metal chlorides in glycine water solutions”, Indian J. Chem. Part A, 40, 100-104 (2001).
45 Yan, Z., Wang, J., Lu, J., “Viscosity behaviour of some α-amino acids and their groups in water-sodium acetate mixtures”, Biophys. Chem., 99, 199-207 (2002).

[1]	Hae-Kyun Park, Dong-Hyuk Park, Bum-Jin Chung. Influence of the electrolyte conductivity on the critical current density and the breakdown voltage[J]. 中国化学工程学报, 2023, 59(7): 169-175.
[2]	Tinghao Jia, Yunbo Yu, Qing Liu, Yao Yang, Ji-Jun Zou, Xiangwen Zhang, Lun Pan. Theoretical and experimental study on the inhibition of jet fuel oxidation by diarylamine[J]. 中国化学工程学报, 2023, 56(4): 225-232.
[3]	Xianglin Liu, Minjie Xu, Chenxi Cao, Zixu Yang, Jing Xu. Effects of zinc on χ-Fe₅C₂ for carbon dioxide hydrogenation to olefins: Insights from experimental and density function theory calculations[J]. 中国化学工程学报, 2023, 54(2): 206-214.
[4]	Yang Liu, Qiu Han, Guiliang Li, Haibo Lin, Fu Liu, Gang Deng, Dingfeng Lv, Weijie Sun. Purifying chylous plasma by precluding triglyceride via carboxylated polyethersulfone microfiltration membrane[J]. 中国化学工程学报, 2022, 49(9): 130-139.
[5]	Fenfen You, Qing-Hong Shi. In situ investigation of lysozyme adsorption into polyelectrolyte brushes by quartz crystal microbalance with dissipation[J]. 中国化学工程学报, 2022, 48(8): 106-115.
[6]	Liuting Zhang, Haijie Yu, Zhiyu Lu, Changhao Zhao, Jiaguang Zheng, Tao Wei, Fuying Wu, Beibei Xiao. The effect of different Co phase structure (FCC/HCP) on the catalytic action towards the hydrogen storage performance of MgH₂[J]. 中国化学工程学报, 2022, 43(3): 343-352.
[7]	Qingjun Zhang, Pengyuan Shi, Xigang Yuan, Youguang Ma, Aiwu Zeng. Direct carboxylation of thiophene with CO₂ in the solvent-free carboxylate-carbonate molten medium: Experimental and mechanistic insights[J]. 中国化学工程学报, 2022, 50(10): 264-282.
[8]	Wei-Qi Yan, Yi-An Zhu, Xing-Gui Zhou, Wei-Kang Yuan. Rational design of heterogeneous catalysts by breaking and rebuilding scaling relations[J]. 中国化学工程学报, 2022, 41(1): 22-28.
[9]	Jipeng Li, Huan Xu, Jingqi Wang, Yujun Wang, Diannan Lu, Jichang Liu, Jianzhong Wu. Theoretical insights on the hydration of quinones as catholytes in aqueous redox flow batteries[J]. 中国化学工程学报, 2021, 37(9): 72-78.
[10]	Feng Liu, Jing Liu, Yu Li, Ruixue Fang. Theoretical study of reduction mechanism of Fe₂O₃ by H₂ during chemical looping combustion[J]. 中国化学工程学报, 2021, 37(9): 175-183.
[11]	Chengxiang Shi, Jisheng Xu, Lun Pan, Xiangwen Zhang, Ji-Jun Zou. Perspective on synthesis of high-energy-density fuels: From petroleum to coal-based pathway[J]. 中国化学工程学报, 2021, 35(7): 83-91.
[12]	Sunita Malik, Poonam Jangra Darolia, S. K. Garg, V. K. Sharma. Densities and excess molar volumes of mixtures containing diesel, biodiesel and alkanols at temperatures from 288.15 to 313.15 K[J]. 中国化学工程学报, 2021, 34(6): 198-207.
[13]	Luchao Jin, Yongming He, Guobing Zhou, Qiuhao Chang, Liangliang Huang, Xingru Wu. Natural gas density under extremely high pressure and high temperature: Comparison of molecular dynamics simulation with corresponding state model[J]. 中国化学工程学报, 2021, 29(3): 2-9.
[14]	Changjie Lu, Weiqiang Tang, Zijiang Dou, Peng Xie, Xiaofei Xu, Shuangliang Zhao. A reaction density functional theory study of solvent effects on keto-enol tautomerism and isomerization in pyruvic acid[J]. 中国化学工程学报, 2021, 29(3): 10-16.
[15]	Jie Yang, Alejandro Gallegos, Cheng Lian, Shengwei Deng, Honglai Liu, Jianzhong Wu. Curvature effects on electric-double-layer capacitance[J]. 中国化学工程学报, 2021, 29(3): 145-152.