Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T

doi:10.1016/S1004-9541(14)60016-1

Chin.J.Chem.Eng. ›› 2014, Vol. 22 ›› Issue (1): 89-97.DOI: 10.1016/S1004-9541(14)60016-1

• CHEMICAL ENGINEERING THERMODYNAMICS • Previous Articles Next Articles

Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T

LI Jie^1,2,3, LIN Xiao^1,2, NING Pengge^1,2, CAO Hongbin^1,2, ZHANG Yi^1,2, John C. Crittenden⁴

1 Research Center for Process Pollution Control, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2 Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
3 Graduate University of Chinese Academy of Sciences, Beijing 100049, China;
4 Brook Byers Institute for Sustainable Systems, Georgia Institute of Technology, Atlanta, GA 30332, USA

Received:2012-10-26 Revised:2013-01-15 Online:2014-01-04 Published:2014-01-05
Contact: NING Pengge
Supported by:
Supported by the National Natural Science Foundation of China (51178446, 21206168).

Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T

李杰^1,2,3, 林晓^1,2, 宁朋歌^1,2, 曹宏斌^1,2, 张懿^1,2, John C. Crittenden⁴

1 Research Center for Process Pollution Control, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2 Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
3 Graduate University of Chinese Academy of Sciences, Beijing 100049, China;
4 Brook Byers Institute for Sustainable Systems, Georgia Institute of Technology, Atlanta, GA 30332, USA

通讯作者: NING Pengge
基金资助:
Supported by the National Natural Science Foundation of China (51178446, 21206168).

Abstract

Abstract: The primary aliphatic amine Primene JM-T was investigated as a potential absorbent for H₂S removal. The solubility of H₂S in JM-T was measured at 298, 313, 333, 353, and 368 K with H₂S partial pressures from 20 to 760 kPa and H₂S loading from 0.02 to 0.8 mol H₂S per mol JM-T. Relevant physical properties, such as density, viscosity and dielectric constant, of the material were measured. The thermodynamic model with two-suffix Margules equation was used to correlate the experimental vapor-liquid equilibrium data. Furthermore, the absorption mechanism in non-aqueous system is suggested and the difference between non-aqueous and aqueous absorption system is pointed out.

Key words: Primene JM-T, H₂S removal, absorption, thermodynamic model

摘要： The primary aliphatic amine Primene JM-T was investigated as a potential absorbent for H₂S removal. The solubility of H₂S in JM-T was measured at 298, 313, 333, 353, and 368 K with H₂S partial pressures from 20 to 760 kPa and H₂S loading from 0.02 to 0.8 mol H₂S per mol JM-T. Relevant physical properties, such as density, viscosity and dielectric constant, of the material were measured. The thermodynamic model with two-suffix Margules equation was used to correlate the experimental vapor-liquid equilibrium data. Furthermore, the absorption mechanism in non-aqueous system is suggested and the difference between non-aqueous and aqueous absorption system is pointed out.

关键词: Primene JM-T, H₂S removal, absorption, thermodynamic model

LI Jie, LIN Xiao, NING Pengge, CAO Hongbin, ZHANG Yi, John C. Crittenden. Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T[J]. Chin.J.Chem.Eng., 2014, 22(1): 89-97.

李杰, 林晓, 宁朋歌, 曹宏斌, 张懿, John C. Crittenden. Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T[J]. Chinese Journal of Chemical Engineering, 2014, 22(1): 89-97.

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Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T

Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T

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