Boosting the hydrogen storage performance of magnesium hydride with metal organic framework-derived Cobalt@Nickel oxide bimetallic catalyst

doi:10.1016/j.cjche.2022.06.026

Chinese Journal of Chemical Engineering ›› 2022, Vol. 52 ›› Issue (12): 161-171.DOI: 10.1016/j.cjche.2022.06.026

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Boosting the hydrogen storage performance of magnesium hydride with metal organic framework-derived Cobalt@Nickel oxide bimetallic catalyst

Yan Zhang¹, Jiaguang Zheng¹, Zhiyu Lu¹, Mengchen Song¹, Jiahuan He³, Fuying Wu², Liuting Zhang¹

1. School of Energy and Power, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2. Analysis and Testing Center, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
3. State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China

Received:2022-03-29 Revised:2022-05-16 Online:2023-01-31 Published:2022-12-28
Contact: Jiaguang Zheng,E-mail:jgzheng@just.edu.cn;Fuying Wu,E-mail:wufuying@just.edu.cn;Liuting Zhang,E-mail:zhanglt89@just.edu.cn
Supported by:
The authors appreciatively acknowledge the financial supports from the National Natural Science Foundation of China (51801078), the Natural Science Foundation of Jiangsu Province (BK20210884).

Boosting the hydrogen storage performance of magnesium hydride with metal organic framework-derived Cobalt@Nickel oxide bimetallic catalyst

Yan Zhang¹, Jiaguang Zheng¹, Zhiyu Lu¹, Mengchen Song¹, Jiahuan He³, Fuying Wu², Liuting Zhang¹

1. School of Energy and Power, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2. Analysis and Testing Center, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
3. State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China

通讯作者: Jiaguang Zheng,E-mail:jgzheng@just.edu.cn;Fuying Wu,E-mail:wufuying@just.edu.cn;Liuting Zhang,E-mail:zhanglt89@just.edu.cn
基金资助:
The authors appreciatively acknowledge the financial supports from the National Natural Science Foundation of China (51801078), the Natural Science Foundation of Jiangsu Province (BK20210884).

Abstract

Abstract: In this study, a MOF-derived bimetallic Co@NiO catalyst was synthesized and doped into MgH₂ to improve the hydrogen desorption and resorption kinetics. The Co@NiO catalyst decreased the onset dehydrogenation temperature of MgH₂ by 160 ℃, compared with un-doped MgH₂. The MgH₂ + 9% (mass) Co@NiO composite released 6.6% (mass) hydrogen in 350 s at 315 ℃ and uptook 5.4% (mass) hydrogen in 500 s at 165 ℃, showing greatly accelerated de/rehydrogenation rates. Besides, the desorption activation energy of MgH₂ + 9% (mass) Co@NiO was decreased to (93.8 ±8.4) kJ·mol^-1. Noteworthy, symbiotic Mg₂NiH₄/Mg₂CoH₅ clusters were in-situ formed from bimetallic precursors and inlaid on MgH₂ surface, which are considered as “multi-step hydrogen pumps”, and provides surface pathways for hydrogen absorption. Meanwhile, the introduced Mg₂NiH₄/Mg₂CoH₅ interfaces could provide numerous low energy barrier H diffusion channels, therefore accelerating the hydrogen release and uptake. This research proposes new insights to design high-efficiency bimetallic catalyst for MgH₂ hydrogen storage.

Key words: Hydrogen, Absorption, Catalyst, MgH₂, Bimetallic materials, Synergistic effect

摘要： In this study, a MOF-derived bimetallic Co@NiO catalyst was synthesized and doped into MgH₂ to improve the hydrogen desorption and resorption kinetics. The Co@NiO catalyst decreased the onset dehydrogenation temperature of MgH₂ by 160 ℃, compared with un-doped MgH₂. The MgH₂ + 9% (mass) Co@NiO composite released 6.6% (mass) hydrogen in 350 s at 315 ℃ and uptook 5.4% (mass) hydrogen in 500 s at 165 ℃, showing greatly accelerated de/rehydrogenation rates. Besides, the desorption activation energy of MgH₂ + 9% (mass) Co@NiO was decreased to (93.8 ±8.4) kJ·mol^-1. Noteworthy, symbiotic Mg₂NiH₄/Mg₂CoH₅ clusters were in-situ formed from bimetallic precursors and inlaid on MgH₂ surface, which are considered as “multi-step hydrogen pumps”, and provides surface pathways for hydrogen absorption. Meanwhile, the introduced Mg₂NiH₄/Mg₂CoH₅ interfaces could provide numerous low energy barrier H diffusion channels, therefore accelerating the hydrogen release and uptake. This research proposes new insights to design high-efficiency bimetallic catalyst for MgH₂ hydrogen storage.

关键词: Hydrogen, Absorption, Catalyst, MgH₂, Bimetallic materials, Synergistic effect

Yan Zhang, Jiaguang Zheng, Zhiyu Lu, Mengchen Song, Jiahuan He, Fuying Wu, Liuting Zhang. Boosting the hydrogen storage performance of magnesium hydride with metal organic framework-derived Cobalt@Nickel oxide bimetallic catalyst[J]. Chinese Journal of Chemical Engineering, 2022, 52(12): 161-171.

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Boosting the hydrogen storage performance of magnesium hydride with metal organic framework-derived Cobalt@Nickel oxide bimetallic catalyst

Boosting the hydrogen storage performance of magnesium hydride with metal organic framework-derived Cobalt@Nickel oxide bimetallic catalyst

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