Salt effect on the liquid-liquid equilibrium of the ternary (water + phenol + methyl isobutyl ketone) system: Experimental data and correlation

doi:10.1016/j.cjche.2018.02.013

Chin.J.Chem.Eng. ›› 2019, Vol. 27 ›› Issue (1): 168-173.DOI: 10.1016/j.cjche.2018.02.013

• Chemical Engineering Thermodynamics • Previous Articles Next Articles

Salt effect on the liquid-liquid equilibrium of the ternary (water + phenol + methyl isobutyl ketone) system: Experimental data and correlation

Yun Chen, Kangning Xiong, Shuai Shen, Huimin Wang, Shaoming Zhou, Libo Li

Department of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China;State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China

Received:2017-11-11 Revised:2018-01-26 Online:2019-01-31 Published:2019-01-28
Contact: Yun Chen, Libo Li
Supported by:
Supported by the National Natural Science Foundation of China (21506066), State Key Laboratory of Pulp and Paper Engineering (201708), the Guangdong Natural Science Foundation (2014A030310260), and the Fundamental Research Funds for the Central Universities SCUT (2017ZD069), and the Guangzhou Technology Project (201804010219).

Salt effect on the liquid-liquid equilibrium of the ternary (water + phenol + methyl isobutyl ketone) system: Experimental data and correlation

Yun Chen, Kangning Xiong, Shuai Shen, Huimin Wang, Shaoming Zhou, Libo Li

Department of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China;State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China

通讯作者: Yun Chen, Libo Li
基金资助:
Supported by the National Natural Science Foundation of China (21506066), State Key Laboratory of Pulp and Paper Engineering (201708), the Guangdong Natural Science Foundation (2014A030310260), and the Fundamental Research Funds for the Central Universities SCUT (2017ZD069), and the Guangzhou Technology Project (201804010219).

Abstract

Abstract: The effects of NaCl, KCl and Na₂SO₄ on the liquid-liquid equilibrium (LLE) data for the ternary system, water + phenol + methyl isobutyl ketone, were determined at 0.101 MPa and 333.15 K and 343.15 K. The nonrandom two-liquid (NRTL) model was used to correlate the experimental data and to yield corresponding binary interaction parameters for these salt containing systems. The Hand and Othmer-Tobias equations were used to confirm the dependability of the determined LLE data in this work. Distribution coefficient and selectivity were used to evaluate the extraction performance of methyl isobutyl ketone with the existence of salt. The magnitude of salt effect on the water + phenol + methyl isobutyl ketone (MIBK) system is in the following order:Na₂SO₄ > NaCl > KCl.

Key words: Liquid-liquid equilibrium, Methyl isobutyl ketone, Salt effect, Phenol

摘要： The effects of NaCl, KCl and Na₂SO₄ on the liquid-liquid equilibrium (LLE) data for the ternary system, water + phenol + methyl isobutyl ketone, were determined at 0.101 MPa and 333.15 K and 343.15 K. The nonrandom two-liquid (NRTL) model was used to correlate the experimental data and to yield corresponding binary interaction parameters for these salt containing systems. The Hand and Othmer-Tobias equations were used to confirm the dependability of the determined LLE data in this work. Distribution coefficient and selectivity were used to evaluate the extraction performance of methyl isobutyl ketone with the existence of salt. The magnitude of salt effect on the water + phenol + methyl isobutyl ketone (MIBK) system is in the following order:Na₂SO₄ > NaCl > KCl.

关键词: Liquid-liquid equilibrium, Methyl isobutyl ketone, Salt effect, Phenol

Yun Chen, Kangning Xiong, Shuai Shen, Huimin Wang, Shaoming Zhou, Libo Li. Salt effect on the liquid-liquid equilibrium of the ternary (water + phenol + methyl isobutyl ketone) system: Experimental data and correlation[J]. Chin.J.Chem.Eng., 2019, 27(1): 168-173.

References

[1] L. Yong, C. Yun, X. Li, Liquid-liquid equilibria for the ternary system 2-methoxy-2-methylpropane + phenol + water, J. Chem. Eng. Data 58(6) (2013) 1874-1878.

[2] M.J. Gonzalez-Munoz, S. Luque, J. RAlvarez, Recovery of phenol from aqueous solutions using hollow fibre contactors, J. Membr. Sci. 213(1-2) (2003) 181-193.

[3] R. Lv, Z. Wang, L. Li, Liquid-liquid equilibria in the ternary systems water + cresols + methyl butyl ketone at 298.2 and 313.2 K:Experimental data and correlation, Fluid Phase Equilib. 404(2015) 89-95.

[4] L. Luo, D. Liu, L. Li, Phase equilibria of (water + propionic acid or butyric acid +2-methoxy-2-methylpropane) ternary systems at 298.2 K and 323.2 K, Fluid Phase Equilib. 403(2015) 30-35.

[5] T.J. Afolabi, A.I. Alao, Liquid-liquid equilibria of water + lactic acid + methyl isobutyl ketone, Fluid Phase Equilib. 379(2014) 19-25.

[6] L. Yong, C. Yun, X. Li, Measurements of Liquid-Liquid Equilibria for the Quaternary System 2-Methoxy-2-methylpropane + Phenol + Hydroquinone + Water at 313.15 K, J. Chem. Eng. Data 58(10) (2013) 2793-2798.

[7] D. Liu, L. Luo, L. Li, Liquid-liquid equilibria for the methyl tert-butyl ketone + phenol + water ternary system at 298.15, 313.15 and 323.15 K, J. Solut. Chem. 44(9) (2015) 1891-1899.

[8] M.R. Mafra, M.A. Krahenbuhl, Liquid-liquid equilibrium of (water + acetone) with cumene or α-methylstyrene or phenol at temperatures of (323.15 and 333.15) K, J. Chem. Eng. Data 51(2) (2006) 753-756.

[9] Y. Chen, Z. Wang, L. Li, Liquid-liquid equilibria for ternary systems:methyl butyl ketone + phenol + water and methyl butyl ketone + hydroquinone + water at 298.15 K and 323.15 K, J. Chem. Eng. Data 59(9) (2014) 2750-2755.

[10] C. Yang, Y. Qian, L. Zhang, Measurement and correlation of liquid-liquid equilibrium data for methyl isobutyl ketone-water-phenol ternary system, Huagong Xuebao/J. Chem. Ind. Eng. 58(4) (2007) 805-809.

[11] C. Yang, Y. Qian, Y. Jiang, Liquid-liquid equilibria for the quaternary system methyl isobutyl ketone-water-phenol-hydroquinone, Fluid Phase Equilib. 258(1) (2007) 73-77.

[12] Y. Chen, P.Y. Zhang, Extraction of highly concentrated phenols from wastewater in coal chemical industry with methyl isobutyl ketone at high temperatures, 2013(CN Pat., 103420442A).

[13] E. Nemati-Kande, H. Shekaari, Salting-out effect of sodium, potassium, carbonate, sulfite, tartrate and thiosulfate ions on aqueous mixtures of acetonitrile or 1-methyl-2-pyrrolidone:A liquid-liquid equilibrium study, Fluid Phase Equilib. 360(9) (2013) 357-366.

[14] X. Chen, X. Gao, H. Zheng, Salting effect on the liquid-liquid equilibrium for the ternary system water + methanol + methyl acetate at 283.15 K, Fluid Phase Equilib. 313(2012) 102-106.

[15] R. Sadeghi, B. Jamehbozorg, The salting-out effect and phase separation in aqueous solutions of sodium phosphate salts and poly(propylene glycol), Fluid Phase Equilib. 280(1) (2009) 68-75.

[16] G.R. Vakili-Nezhaad, M. Mohsen-Nia, V. Taghikhani, Salting-out effect of NaCl and KCl on the ternary LLE data for the systems of (water + propionic acid + isopropyl methyl ketone) and of (water + propionic acid + isobutyl methyl ketone), J. Chem. Thermodyn. 36(4) (2004) 341-348.

[17] M. Gorgenyi, J. Dewulf, L.H. Van, Aqueous salting-out effect of inorganic cations and anions on non-electrolytes, Chemosphere 65(5) (2006) 802-810.

[18] S.P. Pinho, E.A. Macedo, Experimental measurement and modelling of KBr solubility in water, methanol, ethanol, and its binary mixed solvents at different temperatures, J. Chem. Thermodyn. 34(3) (2002) 337-360.

[19] Y. Ji, X. Ji, X. Feng, Progress in the study on the phase equilibria of the CO₂-H₂O and CO₂-H₂O-NaCl systems, Chin. J. Chem. Eng. 15(3) (2007) 439-448.

[20] L. Li, C.J. Fennell, K.A. Dil, Field-SEA:a model for computing the solvation free energies of nonpolar, polar, and charged solutes in water, J. Phys. Chem. B 118(24) (2014) 6431-6437.

[21] H. Wang, L. Li, R. Lv, Measurement and correlation of liquid-liquid equilibria for the ternary methyl isobutyl ketone + phenol + water system at (333.15, 343.15 and 353.15) K under atmospheric pressure, J. Solut. Chem. 45(6) (2016) 875-884.

[22] D.B. Hand, Dineric distribution, J. Phys. Chem. 34(9) (1930) 1961-2000.

[23] D. Othmer, P. Tobias, Liquid-liquid extraction data-The line correlation, Ind. Eng. Chem. 34(6) (1942) 693-696.

[24] J. Saien, F. Ashrafi, Mass transfer enhancement in liquid-liquid extraction with very dilute aqueous salt solutions, Ind. Eng. Chem. Res. 48(22) (2009) 10008-10014.

[25] M. Cox, J.D. Thornton, Science and Practice of Liquid-Liquid Extraction, vol. 2, Oxford Science Pub., New York, 1992.

[26] L. Li, C.J. Fennell, K.A. Dill, Field-SEA:a model for computing the solvation free energies of nonpolar, polar, and charged solutes in water, J. Phys. Chem. 118(24) (2014) 6431-6437.

Salt effect on the liquid-liquid equilibrium of the ternary (water + phenol + methyl isobutyl ketone) system: Experimental data and correlation

Salt effect on the liquid-liquid equilibrium of the ternary (water + phenol + methyl isobutyl ketone) system: Experimental data and correlation

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