Structure, photocatalytic and antibacterial activity study of Meso porous Ni and S co-doped TiO2 nano material under visible light irradiation

doi:10.1016/j.cjche.2018.11.001

Abstract

Abstract: Undoped and Ni-S co-doped mesoporous TiO₂ nano materials were synthesized by using sol-gel method. The characteristic features of as prepared catalyst samples were investigated using various advanced spectroscopic and analytical techniques. The characterization results of the samples revealed that all the samples exhibited anatase phase (XRD), decreasing band gap (2.68 eV) (UV-Vis-DRS), small particle size (9.2 nm) (TEM), high surface area (142.156 m²·g^-1) (BET), particles with spherical shape and smooth morphology (SEM); there is a frequency shift observed for co-doped sample (FT-IR) and the elemental composition electronic states and position of the doped elements (Ni and S) in the TiO₂ lattice analyzed by XPS and EDX. These results supported the photocatalytic degradation of Bismarck Brown Red (BBR) achieved with in 110 min and also exhibited the antibacterial activity on Staphylococcus aureus (MTCC-3160), Pseudomonas fluorescence (MTCC-1688) under visible light irradiation.

Key words: Sol-gel, Ni-S co-doped TiO₂, Photocatalysis under visible light, Degradation of Bismarck Brown Red, Antibacterial activity

摘要： Undoped and Ni-S co-doped mesoporous TiO₂ nano materials were synthesized by using sol-gel method. The characteristic features of as prepared catalyst samples were investigated using various advanced spectroscopic and analytical techniques. The characterization results of the samples revealed that all the samples exhibited anatase phase (XRD), decreasing band gap (2.68 eV) (UV-Vis-DRS), small particle size (9.2 nm) (TEM), high surface area (142.156 m²·g^-1) (BET), particles with spherical shape and smooth morphology (SEM); there is a frequency shift observed for co-doped sample (FT-IR) and the elemental composition electronic states and position of the doped elements (Ni and S) in the TiO₂ lattice analyzed by XPS and EDX. These results supported the photocatalytic degradation of Bismarck Brown Red (BBR) achieved with in 110 min and also exhibited the antibacterial activity on Staphylococcus aureus (MTCC-3160), Pseudomonas fluorescence (MTCC-1688) under visible light irradiation.

关键词: Sol-gel, Ni-S co-doped TiO₂, Photocatalysis under visible light, Degradation of Bismarck Brown Red, Antibacterial activity

K. V. Divya Lakshmi, T. Siva Rao, J. Swathi Padmaja, I. Manga Raju, M. Ravi Kumar. Structure, photocatalytic and antibacterial activity study of Meso porous Ni and S co-doped TiO₂ nano material under visible light irradiation[J]. Chinese Journal of Chemical Engineering, 2019, 27(7): 1630-1641.

References

[1] M.T. Craig, P. Jaramillo, H. Zhai, et al., The economic merits of flexible carbon capture and sequestration as a compliance strategy with the clean power plan, Environ. Sci. Technol. 51(3) (2017) 1102-1109.
[2] D. Leeson, N. Mac Dowell, N. Shah, et al., A techno-economic analysis and systematic review of carbon capture and storage (CCS) applied to the iron and steel, cement, oil refining and pulp and paper industries, as well as other high purity sources, Int. J. Greenhouse Gas Control 61(2017) 71-84.
[3] IPCC, IPCC report, Geneva https://www.ipcc.ch/report/ar5/syr/, 2014.
[4] G.N. Nikolaidis, E.S. Kikkinides, M.C. Georgiadis, Model-based approach for the evaluation of materials and processes for post-combustion carbon dioxide capture from flue gas by PSA/VSA processes, Ind. Eng. Chem. Res. 55(3) (2016) 635-646.
[5] M.S. Walters, Y.J. Lin, D.J. Sachde, et al., Control relevant model of amine scrubbing for CO₂ capture from power plants, Ind. Eng. Chem. Res. 55(6) (2016) 1690-1700.
[6] F.A. Chowdhury, H. Yamada, T. Higashii, et al., CO₂ capture by tertiary amine absorbents:A performance comparison study, Ind. Eng. Chem. Res. 52(24) (2013) 8323-8331.
[7] P.C. Chen, M.W. Yang, C.H. Wei, et al., Selection of blended amine for CO₂ capture in a packed bed scrubber using the Taguchi method, Int. J. Greenhouse Gas Control 45(2016) 245-252.
[8] Y. Yu, T. Zhang, X. Wu, et al., Mass and heat transfer characteristic in MEA absorption of CO₂ improved by meso-scale method, Int. J. Greenhouse Gas Control 47(2016) 310-321.
[9] S. Ma'mun, H.F. Svendsen, K.A. Hoff, et al., Selection of new absorbents for carbon dioxide capture, Energy Convers. Manag. 48(1) (2007) 251-258.
[10] A. Sanna, M.M. Maroto-Valer, Potassium-based sorbents from fly ash for hightemperature CO₂ capture, Environ. Sci. Pollut. Res. 23(22) (2016) 22242-22252.
[11] M. Ghadiri, A. Marjani, S. Shirazian, Development of a mechanistic model for prediction of CO₂ capture from gas mixtures by amine solutions in porous membranes, Environ. Sci. Pollut. Res. 24(16) (2017) 14508-14515.
[12] E. Catalanotti, K.J. Hughes, R.T. Porter, et al., Evaluation of performance and cost of combustion-based power plants with CO₂ capture in the United Kingdom, Environ. Prog. Sustain. Energy 33(4) (2014) 1425-1431.
[13] B. Dutcher, M. Fan, A.G. Russell, Amine-based CO₂ capture technology development from the beginning of 2013. A Review, ACS Appl. Mater. Interfaces 7(4) (2015) 2137-2148.
[14] M. Fan, A. Tuwati, M. Assiri, Catalytic CO₂ desorption for ethanolamine based CO₂ capture technologies, United States Pat., 20160250591(2017).
[15] P.A. Osei, Mass Transfer Studies on Catalyst-Aided CO₂ Desorption in a Post Combustion CO₂ Capture Plant, 2016, Master Thesis, University of Regina, Canada.
[16] H. Shi, A. Naami, R. Idem, et al., Catalytic and non catalytic solvent regeneration during absorption-based CO₂ capture with single and blended reactive amine solvents, Int. J. Greenhouse Gas Control 26(2014) 39-50.
[17] M.E. Diego, B. Arias, G. Grasa, et al., Design of a novel fluidized bed reactor to enhance sorbent performance in CO₂ capture systems using CaO, Ind. Eng. Chem. Res. 53(24) (2014) 10059-10071.
[18] Y.A. Criado, A. Huille, S. Rougé, et al., Experimental investigation and model validation of a CaO/Ca(OH)2 fluidized bed reactor for thermochemical energy storage applications, Chem. Eng. J. 313(2017) 1194-1205.
[19] S. Kallio, J. Peltola, T. Niemi, Modeling of the time-averaged gas-solid drag force in a fluidized bed based on results from transient 2D Eulerian-Eulerian simulations, Powder Technol. 261(2014) 257-271.
[20] A. Bakshi, C. Altantzis, R.B. Bates, et al., Eulerian-Eulerian simulation of dense solid-gas cylindrical fluidized beds:Impact of wall boundary condition and drag model on fluidization, Powder Technol. 277(2015) 47-62.
[21] E. Ghadirian, H. Arastoopour, CFD simulation of a fluidized bed using the EMMS approach for the gas-solid drag force, Powder Technol. 288(2016) 35-44.
[22] M. Ayobi, S. Shahhosseini, Y. Behjat, Computational and experimental investigation of CO₂ capture in gas-solid bubbling fluidized bed, J. Taiwan Inst. Chem. Eng. 45(2) (2014) 421-430.
[23] Y.L. He, W. Tao, F. Song, et al., Three-dimensional numerical study of heat transfer characteristics of plain plate fin-and-tube heat exchangers from view point of field synergy principle, Int. J. Heat Fluid Flow 26(3) (2005) 459-473.
[24] A.A. Minea, O. Manca, Field-synergy and figure-of-merit analysis of two oxide-water-based Nanofluids' flow in heated tubes, heat transfer, Engineering 38(10) (2017) 909-918.
[25] Y. Yu, Y. Li, H. Lu, et al., Performance improvement for chemical absorption of CO₂ by global field synergy optimization, Int. J. Greenhouse Gas Control 5(4) (2011) 649-658.
[26] H. Yamada, Y. Matsuzaki, T. Higashii, et al., Density functional theory study on carbon dioxide absorption into aqueous solutions of 2-amino-2-methyl-1-propanol using a continuum solvation model, J. Phys. Chem. A 115(14) (2011) 3079-3086.
[27] J.M. Plaza, D. Van Wagener, G.T. Rochelle, Modeling CO₂ capture with aqueous monoethanolamine, Int. J. Greenhouse Gas Control 4(2) (2010) 161-166.
[28] A. Di Renzo, N. Grassano, F.P. Di Maio, Force on a large sphere immersed in an expanded water-fluidized bed over a wide range of voidage values, Powder Technol. 316(1) (2017) 296-302.
[29] A.S. Joel, M. Wang, C. Ramshaw, et al., Process analysis of intensified absorber for post-combustion CO₂ capture through modelling and simulation, Int. J. Greenhouse Gas Control 21(2014) 91-100.
[30] W. Li, K. Yu, X. Yuan, et al., A Reynolds mass flux model for gas separation process simulation:Ⅱ. Application to adsorption on activated carbon in a packed column, Chin. J. Chem. Eng. 23(8) (2015) 1245-1255.
[31] M.G. Schroeder, E. Brehob, M. Benedict, Experimentally Validated Model of Transient Heat Transfer between a Magnetocaloric Packed Particle Bed and Stagnant Interstitial Fluid Ph.D. Thesis, University of Louisville, 2016.
[32] G. Liu, K. Yu, X. Yuan, et al., Simulations of chemical absorption in pilot-scale and industrial-scale packed columns by computational mass transfer, Chem. Eng. Sci. 61(19) (2006) 6511-6529.
[33] S. Ogawa, A. Umemura, N. Oshima, On the equations of fully fluidized granular materials, Z. Angew. Math. Phys. 31(4) (1980) 483-493.
[34] C.K.K. Lun, S.B. Savage, D.J. Jeffrey, et al., Kinetic theories for granular flow:Inelastic particles in Couette flow and slightly inelastic particles in a general flowfield, J. Fluid Mech. 140(1984) 223-256.
[35] D.G. Schaeffer, Instability in the evolution equations describing incompressible granular flow, J. Differ. Equ. 66(1) (1987) 19-50.
[36] A.W. Date, Introduction to Computational Fluid Dynamics, Cambridge University Press, New York, 2005.
[37] G. Martinopoulos, D. Missirlis, G. Tsilingiridis, et al., CFD modeling of a polymer solar collector, Renew. Energy 35(7) (2010) 1499-1508.
[38] Y.S. Yu, Y. Li, H.F. Lu, et al., Performance improvement for chemical absorption of CO₂ by global field synergy optimization, Int. J. Greenhouse Gas Control 5(4) (2011) 649-658.
[39] A. Aroonwilas, A. Veawab, Characterization and comparison of the CO₂ absorption performance into single and blended Alkanolamines in a packed column, Ind. Eng. Chem. Res. 43(9) (2004) 2228-2237.
[40] A. Krzemień, A. Więckol-Ryk, A. Smoliń ski, et al., Assessing the risk of corrosion in amine-based CO₂ capture process, J. Loss Prev. Process Ind. 43(2016) 189-197.

Structure, photocatalytic and antibacterial activity study of Meso porous Ni and S co-doped TiO₂ nano material under visible light irradiation

Structure, photocatalytic and antibacterial activity study of Meso porous Ni and S co-doped TiO₂ nano material under visible light irradiation

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Ruilong Zhang, Zhiping Zhou, Wenna Ge, Yi Lu, Tianshu Liu, Wenming Yang, Jiangdong Dai. Robust, fluorine-free and superhydrophobic composite melamine sponge modified with dual silanized SiO₂ microspheres for oil-water separation [J]. Chinese Journal of Chemical Engineering, 2021, 33(5): 50-60.
[2]	Dai Shi, He Yang, Xiangxin Xue. Preparation, characterization and antibacterial properties of cobalt doped titania nanomaterials [J]. Chinese Journal of Chemical Engineering, 2020, 28(5): 1474-1482.
[3]	Xinxin Li, Hebang Shi, Liqiang Zhang, Jingbo Chen, Pengpeng Lü. Novel synthesis of SiO_x/C composite as high-capacity lithium-ion battery anode from silica-carbon binary xerogel [J]. Chinese Journal of Chemical Engineering, 2020, 28(2): 579-583.
[4]	V. Elakkiya, R. Abhishekram, S. Sumathi. Copper doped nickel aluminate: Synthesis, characterisation, optical and colour properties [J]. Chinese Journal of Chemical Engineering, 2019, 27(10): 2596-2605.
[5]	Nurul Azrin Zubbri, Abdul Rahman Mohamed, Maedeh Mohammadi. Parametric study and effect of calcination and carbonation conditions on the CO₂ capture performance of lithium orthosilicate sorbent [J]. Chin.J.Chem.Eng., 2018, 26(3): 631-641.
[6]	Huating Song, Yibin Wei, Chenying Wang, Shuaifei Zhao, Hong Qi. Tuning sol size to optimize organosilica membranes for gas separation [J]. Chin.J.Chem.Eng., 2018, 26(1): 53-59.
[7]	Radha Devi Chekuri, Siva Rao Tirukkovalluri. One step synthesis and characterization of copper doped sulfated titania and its enhanced photocatalytic activity in visible light by degradation of methyl orange [J]. Chin.J.Chem.Eng., 2016, 24(4): 475-483.
[8]	Zujin Yang, Yanxiong Fang, Hongbing Ji. Controlled release and enhanced antibacterial activity of salicylic acid by hydrogen bonding with chitosan [J]. Chin.J.Chem.Eng., 2016, 24(3): 421-426.
[9]	Li Li, Hong Qi. Gas separation using sol-gel derived microporous zirconia membranes with high hydrothermal stability [J]. Chin.J.Chem.Eng., 2015, 23(8): 1300-1306.
[10]	Magdalena Streckova, Radovan Bures, Maria Faberova, Lubomir Medvecky, Jan Fuzer, Peter Kollar. A comparison of soft magnetic composites designed from different ferromagnetic powders and phenolic resins [J]. Chin.J.Chem.Eng., 2015, 23(4): 736-743.
[11]	Guizhi Zhu, Qian Jiang, Hong Qi, Nanping Xu. Effect of sol size on nanofiltration performance of a sol-gel derived microporous zirconia membrane [J]. Chin.J.Chem.Eng., 2015, 23(1): 31-41.
[12]	Baowen Wang, Xiaoyong Song, ZonghuaWang, Chuguang Zheng. Preparation and Application of the Sol-Gel Combustion Synthesis-Made CaO/CaZrO₃ Sorbent for Cyclic CO₂ Capture Through the Severe Calcination Condition [J]. , 2014, 22(9): 991-999.
[13]	GUO Qiang, WANG Tao. Preparation and Characterization of Sodium Sulfate/Silica Composite as a Shape-stabilized Phase Change Material by Sol-gel Method [J]. Chin.J.Chem.Eng., 2014, 22(3): 360-364.
[14]	ZHENG Guangjian, CUI Xuemin, ZHANG Weipeng, TONG Zhangfa, LI Feng. Al₂O₃-2SiO₂ Nanoparticles with Defined Al-Si Ratio:Processing Optimization and Conversion [J]. , 2012, 20(2): 312-318.
[15]	YUAN Wenhui, SHEN Rongping, LI Li. Synthesis and Conductivity of Oxyapatite Ionic Conductor La_10-xV_x（SiO₄）₆O_3+x [J]. , 2010, 18(2): 328-332.