Efficient hydrolysis of cellulose to glucose catalyzed by lignin-derived mesoporous carbon solid acid in water

doi:10.1016/j.cjche.2020.03.012

Chinese Journal of Chemical Engineering ›› 2020, Vol. 28 ›› Issue (7): 1866-1874.DOI: 10.1016/j.cjche.2020.03.012

• Catalysis, Kinetics and Reaction Engineering • Previous Articles Next Articles

Efficient hydrolysis of cellulose to glucose catalyzed by lignin-derived mesoporous carbon solid acid in water

Shuai Wang^1,2, Guobao Sima^1,2, Ying Cui^1,2, Longjun Chang¹, Linhuo Gan^1,2

1 College of Chemical Engineering, Huaqiao University, Xiamen 361021, China;
2 Key Laboratory of Pulp and Paper Science&Technology of Ministry of Education/Shandong Province, Qilu University of Technology(Shandong Academy of Science), Jinan 250353, China

Received:2019-12-21 Revised:2020-02-08 Online:2020-08-31 Published:2020-07-28
Contact: Linhuo Gan
Supported by:
The authors are grateful for the financial support from the National Natural Science Foundation of China (grant No. 21706085), Subsidized Project for Postgraduates' Innovative Fund in Scientific Research of Huaqiao University and the Foundation of Key Laboratory of Pulp and Paper Science and Technology of Ministry of Education/Shandong Province of China (grant No. KF201804).

Efficient hydrolysis of cellulose to glucose catalyzed by lignin-derived mesoporous carbon solid acid in water

Shuai Wang^1,2, Guobao Sima^1,2, Ying Cui^1,2, Longjun Chang¹, Linhuo Gan^1,2

1 College of Chemical Engineering, Huaqiao University, Xiamen 361021, China;
2 Key Laboratory of Pulp and Paper Science&Technology of Ministry of Education/Shandong Province, Qilu University of Technology(Shandong Academy of Science), Jinan 250353, China

通讯作者: Linhuo Gan
基金资助:
The authors are grateful for the financial support from the National Natural Science Foundation of China (grant No. 21706085), Subsidized Project for Postgraduates' Innovative Fund in Scientific Research of Huaqiao University and the Foundation of Key Laboratory of Pulp and Paper Science and Technology of Ministry of Education/Shandong Province of China (grant No. KF201804).

Abstract

Abstract: Two kinds of mesoporous carbon solid acids (LDMC_E-SO₃H and LDMC_S-SO₃H) were successfully prepared using masson pine alkali lignin as carbon source by evaporation-induced self-assembly (EISA) and salt-induced selfassembly (SISA) followed by sulfonation, respectively. In terms of preparation process, SISA (self-assembly in water and preparation time of 2 days) is greener and simpler than EISA (self-assembly in ethanol and preparation time of 7 days). The prepared LDMC_E-SO₃H and LDMC_S-SO₃H exhibit obvious differences in structural characteristics such as pore channel structure, specific surface area, mesopore volume and the density of -SO₃H groups. Furthermore, the catalytic performances of LDMC_E-SO₃H and LDMC_S-SO₃H were investigated in the hydrolysis of microcrystalline cellulose in water, and the glucose yields of 48.99% and 54.42% were obtained under the corresponding optimal reaction conditions. More importantly, the glucose yields still reached 28.85% and 30.35% after five runs, and restored to 39.02% and 45.98% through catalysts regeneration, respectively, demonstrating that LDMC_E-SO₃H and LDMC_S-SO₃H have excellent recyclability and regenerability.

Key words: Biomass, Evaporation-induced self-assembly, Salt-induced self-assembly, Mesoporous carbon solid acid, Catalysis, Hydrolysis

摘要： Two kinds of mesoporous carbon solid acids (LDMC_E-SO₃H and LDMC_S-SO₃H) were successfully prepared using masson pine alkali lignin as carbon source by evaporation-induced self-assembly (EISA) and salt-induced selfassembly (SISA) followed by sulfonation, respectively. In terms of preparation process, SISA (self-assembly in water and preparation time of 2 days) is greener and simpler than EISA (self-assembly in ethanol and preparation time of 7 days). The prepared LDMC_E-SO₃H and LDMC_S-SO₃H exhibit obvious differences in structural characteristics such as pore channel structure, specific surface area, mesopore volume and the density of -SO₃H groups. Furthermore, the catalytic performances of LDMC_E-SO₃H and LDMC_S-SO₃H were investigated in the hydrolysis of microcrystalline cellulose in water, and the glucose yields of 48.99% and 54.42% were obtained under the corresponding optimal reaction conditions. More importantly, the glucose yields still reached 28.85% and 30.35% after five runs, and restored to 39.02% and 45.98% through catalysts regeneration, respectively, demonstrating that LDMC_E-SO₃H and LDMC_S-SO₃H have excellent recyclability and regenerability.

关键词: Biomass, Evaporation-induced self-assembly, Salt-induced self-assembly, Mesoporous carbon solid acid, Catalysis, Hydrolysis

Shuai Wang, Guobao Sima, Ying Cui, Longjun Chang, Linhuo Gan. Efficient hydrolysis of cellulose to glucose catalyzed by lignin-derived mesoporous carbon solid acid in water[J]. Chinese Journal of Chemical Engineering, 2020, 28(7): 1866-1874.

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Efficient hydrolysis of cellulose to glucose catalyzed by lignin-derived mesoporous carbon solid acid in water

Efficient hydrolysis of cellulose to glucose catalyzed by lignin-derived mesoporous carbon solid acid in water

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