Recent advances on mixed matrix membranes for CO2 separation

doi:10.1016/j.cjche.2017.07.006

Chin.J.Chem.Eng. ›› 2017, Vol. 25 ›› Issue (11): 1581-1597.DOI: 10.1016/j.cjche.2017.07.006

• Special Issue of Membranes and Membrane Processes based on Confined Mass Transfer • Previous Articles Next Articles

Recent advances on mixed matrix membranes for CO₂ separation

Ming Wang^1,2,3,4, Zhi Wang^1,2,3,4, Song Zhao^1,2,3,4, Jixiao Wang^1,2,3,4, Shichang Wang^1,2,3,4

1 Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China;
2 Tianjin Key Laboratory of Membrane Science and Desalination Technology, Tianjin 300350, China;
3 State Key Laboratory of Chemical Engineering, Tianjin 300350, China;
4 Collaborative Innovation Center of Chemical Science and Engineering, Tianjin University, Tianjin 300350, China

Received:2017-02-28 Revised:2017-07-02 Online:2018-01-18 Published:2017-11-28
Contact: Zhi Wang,E-mail address:wangzhi@tju.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China (21436009) and the Program of Introducing Talents of Discipline to Universities (B06006).

Recent advances on mixed matrix membranes for CO₂ separation

Ming Wang^1,2,3,4, Zhi Wang^1,2,3,4, Song Zhao^1,2,3,4, Jixiao Wang^1,2,3,4, Shichang Wang^1,2,3,4

1 Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China;
2 Tianjin Key Laboratory of Membrane Science and Desalination Technology, Tianjin 300350, China;
3 State Key Laboratory of Chemical Engineering, Tianjin 300350, China;
4 Collaborative Innovation Center of Chemical Science and Engineering, Tianjin University, Tianjin 300350, China

通讯作者: Zhi Wang,E-mail address:wangzhi@tju.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China (21436009) and the Program of Introducing Talents of Discipline to Universities (B06006).

Abstract

Abstract: Recent advances on mixed matrix membrane for CO₂ separation are reviewed in this paper. To improve CO₂ separation performance of polymer membranes, mixed matrix membranes (MMMs) are developed. The concept of MMM is illustrated distinctly. Suitable polymer and inorganic or organic fillers for MMMs are summarized. Possible interface morphologies between polymer and filler, and the effect of interface morphologies on gas transport properties of MMMs are summarized. The methods to improve compatibility between polymer and filler are introduced. There are eight methods including silane coupling, Grignard treatment, incorporation of additive, grafting, in situ polymerization, polydopamine coating, particle fusion approach and polymer functionalization. To achieve higher productivity for industrial application, mixed matrix composite membranes are developed. The recent development on hollow fiber and flat mixed matrix composite membrane is reviewed in detail. Last, the future trend of MMM is forecasted.

Key words: CO₂ separation, Mixed matrix membrane, Material selection, Compatibility, Composite membrane, Future direction

摘要： Recent advances on mixed matrix membrane for CO₂ separation are reviewed in this paper. To improve CO₂ separation performance of polymer membranes, mixed matrix membranes (MMMs) are developed. The concept of MMM is illustrated distinctly. Suitable polymer and inorganic or organic fillers for MMMs are summarized. Possible interface morphologies between polymer and filler, and the effect of interface morphologies on gas transport properties of MMMs are summarized. The methods to improve compatibility between polymer and filler are introduced. There are eight methods including silane coupling, Grignard treatment, incorporation of additive, grafting, in situ polymerization, polydopamine coating, particle fusion approach and polymer functionalization. To achieve higher productivity for industrial application, mixed matrix composite membranes are developed. The recent development on hollow fiber and flat mixed matrix composite membrane is reviewed in detail. Last, the future trend of MMM is forecasted.

关键词: CO₂ separation, Mixed matrix membrane, Material selection, Compatibility, Composite membrane, Future direction

Ming Wang, Zhi Wang, Song Zhao, Jixiao Wang, Shichang Wang. Recent advances on mixed matrix membranes for CO₂ separation[J]. Chin.J.Chem.Eng., 2017, 25(11): 1581-1597.

Ming Wang, Zhi Wang, Song Zhao, Jixiao Wang, Shichang Wang. Recent advances on mixed matrix membranes for CO₂ separation[J]. Chinese Journal of Chemical Engineering, 2017, 25(11): 1581-1597.

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Recent advances on mixed matrix membranes for CO₂ separation

Recent advances on mixed matrix membranes for CO₂ separation

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