Catalytic depolymerization of calcium lignosulfonate by NiMgFeOx derived from sub-micron sized NiMgFe hydrotalcite prepared by introducing hydroxyl compounds

doi:10.1016/j.cjche.2019.01.024

Chinese Journal of Chemical Engineering ›› 2019, Vol. 27 ›› Issue (8): 1933-1938.DOI: 10.1016/j.cjche.2019.01.024

• Biotechnology and Bioengineering • Previous Articles Next Articles

Catalytic depolymerization of calcium lignosulfonate by NiMgFeO_x derived from sub-micron sized NiMgFe hydrotalcite prepared by introducing hydroxyl compounds

Hongjing Han^1,2, Jinxin Li^1,2, Haiying Wang^1,2, Feng Xue³, Yanguang Chen^1,2, Yanan Zhang^1,2, Yizhen Wang^1,2, Mei Zhang^1,2

1 School of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing 163318, China;
2 Heilongjiang Provincial Key Laboratory of Oil & Gas Chemical Technology, Daqing 163318, China;
3 Shandong Sinocera Functional Material Co., Ltd, Dongying 257000, China

Received:2018-10-28 Revised:2019-01-14 Online:2019-11-16 Published:2019-08-28
Contact: Hongjing Han
Supported by:
Supported by the Program for National Natural Science Foundation of China (No. 51674089), Excellent Youth Foundation of Heilongjiang Province of China (No. JC2018002), Postdoctoral Scientific Research Development Fund of Heilongjiang Province of China (No. LBH-Q16037), the Youth Fund of Northeast Petroleum University (No. 2018QNL-17) and the Postgraduate Innovative Research Projects of Northeast Petroleum University (No. YJSCX2017-014NEPU).

Catalytic depolymerization of calcium lignosulfonate by NiMgFeO_x derived from sub-micron sized NiMgFe hydrotalcite prepared by introducing hydroxyl compounds

Hongjing Han^1,2, Jinxin Li^1,2, Haiying Wang^1,2, Feng Xue³, Yanguang Chen^1,2, Yanan Zhang^1,2, Yizhen Wang^1,2, Mei Zhang^1,2

1 School of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing 163318, China;
2 Heilongjiang Provincial Key Laboratory of Oil & Gas Chemical Technology, Daqing 163318, China;
3 Shandong Sinocera Functional Material Co., Ltd, Dongying 257000, China

通讯作者: Hongjing Han
基金资助:
Supported by the Program for National Natural Science Foundation of China (No. 51674089), Excellent Youth Foundation of Heilongjiang Province of China (No. JC2018002), Postdoctoral Scientific Research Development Fund of Heilongjiang Province of China (No. LBH-Q16037), the Youth Fund of Northeast Petroleum University (No. 2018QNL-17) and the Postgraduate Innovative Research Projects of Northeast Petroleum University (No. YJSCX2017-014NEPU).

Abstract

Abstract: A new method for regulating the synthesis of NiMgFe hydrotalcites (NMF LDHs) with the addition of hydroxyl compounds was proposed. A series of NMF LDHs were prepared by the above method, and then were calcined to obtain the NiMgFeO_x (NMFO_x) samples. The NMFO_x samples were characterized by XRD, SEM, TG-DTG, XPS and CO₂-TPD, respectively. The catalytic performance of NMFO_x for depolymerizing calcium lignosulfonate (CLS) was evaluated by hydrothermal reaction. The results showed that the addition of hydroxyl compounds favored reducing the particle sizes of NMF LDHs. For the depolymerization of CSL, the yield of liquid product increased from 45% to 75.8% with the addition of NMFO_x-ethanol (NMFO_xET). The liquid products were mainly phenolics, aromatics, ketones and esters. The total selectivity of oxy-containing compounds was over 90.6%, among them, the phenolics were approximately 35.2%. The valence of Ni and Fe, crystalline phase and basicity almost remained unchanged. The NMFO_x-ET samples were recycled for the depolymerization of CLS, moreover, the NMFO_x-ET samples had high activity and stability after 4 cycles.

Key words: Hydrotalcite, Calcium lignosulfonate, Depolymerization, Oxy-containing compounds

摘要： A new method for regulating the synthesis of NiMgFe hydrotalcites (NMF LDHs) with the addition of hydroxyl compounds was proposed. A series of NMF LDHs were prepared by the above method, and then were calcined to obtain the NiMgFeO_x (NMFO_x) samples. The NMFO_x samples were characterized by XRD, SEM, TG-DTG, XPS and CO₂-TPD, respectively. The catalytic performance of NMFO_x for depolymerizing calcium lignosulfonate (CLS) was evaluated by hydrothermal reaction. The results showed that the addition of hydroxyl compounds favored reducing the particle sizes of NMF LDHs. For the depolymerization of CSL, the yield of liquid product increased from 45% to 75.8% with the addition of NMFO_x-ethanol (NMFO_xET). The liquid products were mainly phenolics, aromatics, ketones and esters. The total selectivity of oxy-containing compounds was over 90.6%, among them, the phenolics were approximately 35.2%. The valence of Ni and Fe, crystalline phase and basicity almost remained unchanged. The NMFO_x-ET samples were recycled for the depolymerization of CLS, moreover, the NMFO_x-ET samples had high activity and stability after 4 cycles.

关键词: Hydrotalcite, Calcium lignosulfonate, Depolymerization, Oxy-containing compounds

Hongjing Han, Jinxin Li, Haiying Wang, Feng Xue, Yanguang Chen, Yanan Zhang, Yizhen Wang, Mei Zhang. Catalytic depolymerization of calcium lignosulfonate by NiMgFeO_x derived from sub-micron sized NiMgFe hydrotalcite prepared by introducing hydroxyl compounds[J]. Chinese Journal of Chemical Engineering, 2019, 27(8): 1933-1938.

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Catalytic depolymerization of calcium lignosulfonate by NiMgFeO_x derived from sub-micron sized NiMgFe hydrotalcite prepared by introducing hydroxyl compounds

Catalytic depolymerization of calcium lignosulfonate by NiMgFeO_x derived from sub-micron sized NiMgFe hydrotalcite prepared by introducing hydroxyl compounds

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