Production of aryl oxygen-containing compounds from catalytic pyrolysis of bagasse lignin over LaTixFe1-xO3

doi:10.1016/j.cjche.2019.01.023

Chinese Journal of Chemical Engineering ›› 2019, Vol. 27 ›› Issue (8): 1939-1944.DOI: 10.1016/j.cjche.2019.01.023

• Energy, Resources and Environmental Technology • Previous Articles Next Articles

Production of aryl oxygen-containing compounds from catalytic pyrolysis of bagasse lignin over LaTi_xFe_1-xO₃

Haiying Wang^1,2, Hongjing Han^1,2, Enhao Sun³, Yanan Zhang^1,2, Jinxin Li^1,2, Yanguang Chen^1,2, Hua Song^1,2, Hongzhi Zhao^1,2

1 College of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing 163318, China;
2 Provincial Key Laboratory of Oil & Gas Chemical Technology, Daqing 163318, China;
3 Daqing Petrochemical Research Center, PetroChina, Daqing 163000, China

Received:2018-11-02 Revised:2019-01-08 Online:2019-11-16 Published:2019-08-28
Contact: Yanguang Chen
Supported by:
Supported by the National Natural Science Foundation of China, China (51674089), Heilongjiang Provincial Science Fund for Distinguished Youth Scholar (JC2018002), Heilongjiang Postdoctoral Scientific Research Development Fund of China (LBH-Q16037), the Youth Fund of Northeast Petroleum University (2018QNL-17) and Postgraduate Innovative Research Projects of Northeast Petroleum University (YJSCX2017-014NEPU).

Production of aryl oxygen-containing compounds from catalytic pyrolysis of bagasse lignin over LaTi_xFe_1-xO₃

Haiying Wang^1,2, Hongjing Han^1,2, Enhao Sun³, Yanan Zhang^1,2, Jinxin Li^1,2, Yanguang Chen^1,2, Hua Song^1,2, Hongzhi Zhao^1,2

1 College of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing 163318, China;
2 Provincial Key Laboratory of Oil & Gas Chemical Technology, Daqing 163318, China;
3 Daqing Petrochemical Research Center, PetroChina, Daqing 163000, China

通讯作者: Yanguang Chen
基金资助:
Supported by the National Natural Science Foundation of China, China (51674089), Heilongjiang Provincial Science Fund for Distinguished Youth Scholar (JC2018002), Heilongjiang Postdoctoral Scientific Research Development Fund of China (LBH-Q16037), the Youth Fund of Northeast Petroleum University (2018QNL-17) and Postgraduate Innovative Research Projects of Northeast Petroleum University (YJSCX2017-014NEPU).

Abstract

Abstract: A new approach, named production of aryl oxygen-containing compounds from the catalytic pyrolysis of bagasse lignin (BL) over perovskite oxide, was proposed. A series of LaTi_xFe_1-xO₃ (LTF-x) samples were prepared by the solid state reaction method. The crystal phase and morphology of LTF-x were characterized by XRD and SEM respectively. Catalytic pyrolysis performance of LTF-x was performed by TG-DTG and the distribution patterns of gaseous, liquid and solid products from BL was investigated using a fixed-bed micro-reactor. The optimal reaction conditions were determined:the pyrolysis temperature was 600℃, the mass ratio of m_BL:m_LTF-0.2 was 3:1, the velocity of carrier gas was 100 ml·min^-1. The gaseous products were mainly composed of CO₂, CO, CH₄ and C_nH_m (n=2-4, m=2n + 2 or m=2n). The main aryl oxygen-containing compounds in liquid products were phenolics, guaiacols, syringols and phenylates, the rest were benzenes, furans, esters and carboxylic acid. The total contents of aryl oxygencontaining compounds were from 62% up to more than 72% under the action of the perovskite. Moreover, the LTF-0.2 sample had nice regenerability.

Key words: Bagasse lignin, Perovskite, Catalytic pyrolysis, Aryl oxygen-containing compounds

摘要： A new approach, named production of aryl oxygen-containing compounds from the catalytic pyrolysis of bagasse lignin (BL) over perovskite oxide, was proposed. A series of LaTi_xFe_1-xO₃ (LTF-x) samples were prepared by the solid state reaction method. The crystal phase and morphology of LTF-x were characterized by XRD and SEM respectively. Catalytic pyrolysis performance of LTF-x was performed by TG-DTG and the distribution patterns of gaseous, liquid and solid products from BL was investigated using a fixed-bed micro-reactor. The optimal reaction conditions were determined:the pyrolysis temperature was 600℃, the mass ratio of m_BL:m_LTF-0.2 was 3:1, the velocity of carrier gas was 100 ml·min^-1. The gaseous products were mainly composed of CO₂, CO, CH₄ and C_nH_m (n=2-4, m=2n + 2 or m=2n). The main aryl oxygen-containing compounds in liquid products were phenolics, guaiacols, syringols and phenylates, the rest were benzenes, furans, esters and carboxylic acid. The total contents of aryl oxygencontaining compounds were from 62% up to more than 72% under the action of the perovskite. Moreover, the LTF-0.2 sample had nice regenerability.

关键词: Bagasse lignin, Perovskite, Catalytic pyrolysis, Aryl oxygen-containing compounds

Haiying Wang, Hongjing Han, Enhao Sun, Yanan Zhang, Jinxin Li, Yanguang Chen, Hua Song, Hongzhi Zhao. Production of aryl oxygen-containing compounds from catalytic pyrolysis of bagasse lignin over LaTi_xFe_1-xO₃[J]. Chinese Journal of Chemical Engineering, 2019, 27(8): 1939-1944.

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Production of aryl oxygen-containing compounds from catalytic pyrolysis of bagasse lignin over LaTi_xFe_1-xO₃

Production of aryl oxygen-containing compounds from catalytic pyrolysis of bagasse lignin over LaTi_xFe_1-xO₃

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