Abstract: NiMo bimetallic catalysts were prepared by a solid reaction method. On the NiMo catalyst, the selective liquid phase hydrogenation of nitrobenzene to aniline was achieved in slurry bubble mode. And the high yields (98.9%) were obtained under the conditions of 80 ℃, solvent-free and atmospheric pressure. The effect of Mo on the catalytic behavior of Ni based catalyst was investigated. The characterization displayed that the inclusion of Mo could improve the specific surface area and pore volume, and the solid reaction method made metal Mo enrichment on the surface of catalyst. These two aspects should be responsible for excellent catalytic performance of NiMo catalyst. In sum, we described a simple and efficient NiMo catalyst and provided a facile and green procedure for liquid phase hydrogenation of nitrobenzene to aniline.

Key words: Catalysis, Nitroarenes, Hydrogenation, NiMo catalyst, Solid reaction, Bubble column reactor

摘要： NiMo bimetallic catalysts were prepared by a solid reaction method. On the NiMo catalyst, the selective liquid phase hydrogenation of nitrobenzene to aniline was achieved in slurry bubble mode. And the high yields (98.9%) were obtained under the conditions of 80 ℃, solvent-free and atmospheric pressure. The effect of Mo on the catalytic behavior of Ni based catalyst was investigated. The characterization displayed that the inclusion of Mo could improve the specific surface area and pore volume, and the solid reaction method made metal Mo enrichment on the surface of catalyst. These two aspects should be responsible for excellent catalytic performance of NiMo catalyst. In sum, we described a simple and efficient NiMo catalyst and provided a facile and green procedure for liquid phase hydrogenation of nitrobenzene to aniline.

关键词: Catalysis, Nitroarenes, Hydrogenation, NiMo catalyst, Solid reaction, Bubble column reactor