Nitrogen-doped composite aerogels from ZIF-8 derived porous carbon and chitosan for CO2 adsorption

doi:10.1016/j.cjche.2025.01.009

Chinese Journal of Chemical Engineering ›› 2025, Vol. 82 ›› Issue (6): 95-104.DOI: 10.1016/j.cjche.2025.01.009

Nitrogen-doped composite aerogels from ZIF-8 derived porous carbon and chitosan for CO₂ adsorption

Xiaoqian Peng¹, Shaojun Liu¹, Jing Zhang¹, Xu Zhang¹, Xiaochan Liu¹, Zhipeng Yuan¹, Guoran Liu¹, Xibin Yi¹, Serguei Filatov²

1. Shandong Key Laboratory for Special Silicon-containing Material, Advanced Materials Institute, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250014, China;
2. Laboratory of Hydrogen Energy, Institute of Hent and Mass Transfer of the National Academy of Science of Belarus, Minsk 220072, Belarus

Received:2024-09-19 Revised:2024-12-26 Accepted:2025-01-08 Online:2025-03-14 Published:2025-08-19
Contact: Jing Zhang,E-mail:zhangjing@sdas.org;Xibin Yi,E-mail:yixb@sdas.org
Supported by:
This work is supported by the Natural Science Foundation of Shandong Province (ZR2021ME124, ZR2023ME033), Science-Education-Industry Integration Innovation Pilot Project of Qilu University of Technology (2024GH09), Innovation Capacity Improvement Project of Small and Medium-Sized Technology-Based Enterprise of Shandong Province (2023TSGC0706, 2022TSGC1022), Technological Innovation Projects of Shandong Province (202350700179; 202351600213), Science and technology plan project of Shandong Railway Investment Holding Group (TTKJ2023-01).

Nitrogen-doped composite aerogels from ZIF-8 derived porous carbon and chitosan for CO₂ adsorption

Xiaoqian Peng¹, Shaojun Liu¹, Jing Zhang¹, Xu Zhang¹, Xiaochan Liu¹, Zhipeng Yuan¹, Guoran Liu¹, Xibin Yi¹, Serguei Filatov²

1. Shandong Key Laboratory for Special Silicon-containing Material, Advanced Materials Institute, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250014, China;
2. Laboratory of Hydrogen Energy, Institute of Hent and Mass Transfer of the National Academy of Science of Belarus, Minsk 220072, Belarus

通讯作者: Jing Zhang,E-mail:zhangjing@sdas.org;Xibin Yi,E-mail:yixb@sdas.org
基金资助:
This work is supported by the Natural Science Foundation of Shandong Province (ZR2021ME124, ZR2023ME033), Science-Education-Industry Integration Innovation Pilot Project of Qilu University of Technology (2024GH09), Innovation Capacity Improvement Project of Small and Medium-Sized Technology-Based Enterprise of Shandong Province (2023TSGC0706, 2022TSGC1022), Technological Innovation Projects of Shandong Province (202350700179; 202351600213), Science and technology plan project of Shandong Railway Investment Holding Group (TTKJ2023-01).

Abstract

Abstract: It is well known that adsorbent material is the key to determine the CO₂ adsorption performance. Herein, ZIF-8 derived porous carbon (ZIF-8-C) is anchored into the framework of a novel composite aerogel (ZCPx), which utilizes chitosan (CS) and polyvinyl alcohol (PVA) as raw materials. By controlling the ratio of ZIF-8-C, the developed hierarchical porous structures combine the advantages of micropores, mesopores, and macropores. Besides, the ligand material of ZIF-8-C and the amino group from CS are two sources of the high nitrogen content of ZCPx. The optimized sample ZCP4 shows a high nitrogen content of 6.78%, which can create more active centers and supply basic sites, thereby enhancing the CO₂ adsorption capacity. Moreover, ZCP4 composite aerogel presents a CO₂ adsorption capacity of 2.26 mmol·g^-1 (298 K, 0.1 MPa) and CO₂/N₂ selectivity (S_CO₂/N₂) can reach 20.02, and the dynamic breakthrough experiment is performed to confirm the feasibility of CO₂/N₂ actual separation performance, proving that the composite aerogel is potential candidates for CO₂ adsorption.

Key words: Chitosan, ZIF-8 derived porous carbon, Aerogel, CO₂ adsorption

摘要： It is well known that adsorbent material is the key to determine the CO₂ adsorption performance. Herein, ZIF-8 derived porous carbon (ZIF-8-C) is anchored into the framework of a novel composite aerogel (ZCPx), which utilizes chitosan (CS) and polyvinyl alcohol (PVA) as raw materials. By controlling the ratio of ZIF-8-C, the developed hierarchical porous structures combine the advantages of micropores, mesopores, and macropores. Besides, the ligand material of ZIF-8-C and the amino group from CS are two sources of the high nitrogen content of ZCPx. The optimized sample ZCP4 shows a high nitrogen content of 6.78%, which can create more active centers and supply basic sites, thereby enhancing the CO₂ adsorption capacity. Moreover, ZCP4 composite aerogel presents a CO₂ adsorption capacity of 2.26 mmol·g^-1 (298 K, 0.1 MPa) and CO₂/N₂ selectivity (S_CO₂/N₂) can reach 20.02, and the dynamic breakthrough experiment is performed to confirm the feasibility of CO₂/N₂ actual separation performance, proving that the composite aerogel is potential candidates for CO₂ adsorption.

关键词: Chitosan, ZIF-8 derived porous carbon, Aerogel, CO₂ adsorption

Xiaoqian Peng, Shaojun Liu, Jing Zhang, Xu Zhang, Xiaochan Liu, Zhipeng Yuan, Guoran Liu, Xibin Yi, Serguei Filatov. Nitrogen-doped composite aerogels from ZIF-8 derived porous carbon and chitosan for CO₂ adsorption[J]. Chinese Journal of Chemical Engineering, 2025, 82(6): 95-104.

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Nitrogen-doped composite aerogels from ZIF-8 derived porous carbon and chitosan for CO₂ adsorption

Nitrogen-doped composite aerogels from ZIF-8 derived porous carbon and chitosan for CO₂ adsorption

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