SCI和EI收录∣中国化工学会会刊

Chin.J.Chem.Eng. ›› 2014, Vol. 22 ›› Issue (1): 89-97.DOI: 10.1016/S1004-9541(14)60016-1

• CHEMICAL ENGINEERING THERMODYNAMICS • Previous Articles     Next Articles

Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T

LI Jie1,2,3, LIN Xiao1,2, NING Pengge1,2, CAO Hongbin1,2, ZHANG Yi1,2, John C. Crittenden4   

  1. 1 Research Center for Process Pollution Control, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
    2 Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
    3 Graduate University of Chinese Academy of Sciences, Beijing 100049, China;
    4 Brook Byers Institute for Sustainable Systems, Georgia Institute of Technology, Atlanta, GA 30332, USA
  • Received:2012-10-26 Revised:2013-01-15 Online:2014-01-04 Published:2014-01-05
  • Contact: NING Pengge
  • Supported by:

    Supported by the National Natural Science Foundation of China (51178446, 21206168).

Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T

李杰1,2,3, 林晓1,2, 宁朋歌1,2, 曹宏斌1,2, 张懿1,2, John C. Crittenden4   

  1. 1 Research Center for Process Pollution Control, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
    2 Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
    3 Graduate University of Chinese Academy of Sciences, Beijing 100049, China;
    4 Brook Byers Institute for Sustainable Systems, Georgia Institute of Technology, Atlanta, GA 30332, USA
  • 通讯作者: NING Pengge
  • 基金资助:

    Supported by the National Natural Science Foundation of China (51178446, 21206168).

Abstract: The primary aliphatic amine Primene JM-T was investigated as a potential absorbent for H2S removal. The solubility of H2S in JM-T was measured at 298, 313, 333, 353, and 368 K with H2S partial pressures from 20 to 760 kPa and H2S loading from 0.02 to 0.8 mol H2S per mol JM-T. Relevant physical properties, such as density, viscosity and dielectric constant, of the material were measured. The thermodynamic model with two-suffix Margules equation was used to correlate the experimental vapor-liquid equilibrium data. Furthermore, the absorption mechanism in non-aqueous system is suggested and the difference between non-aqueous and aqueous absorption system is pointed out.

Key words: Primene JM-T, H2S removal, absorption, thermodynamic model

摘要: The primary aliphatic amine Primene JM-T was investigated as a potential absorbent for H2S removal. The solubility of H2S in JM-T was measured at 298, 313, 333, 353, and 368 K with H2S partial pressures from 20 to 760 kPa and H2S loading from 0.02 to 0.8 mol H2S per mol JM-T. Relevant physical properties, such as density, viscosity and dielectric constant, of the material were measured. The thermodynamic model with two-suffix Margules equation was used to correlate the experimental vapor-liquid equilibrium data. Furthermore, the absorption mechanism in non-aqueous system is suggested and the difference between non-aqueous and aqueous absorption system is pointed out.

关键词: Primene JM-T, H2S removal, absorption, thermodynamic model