Simultaneous removal of Cr(VI), Cd, and Pb from aqueous solution by iron sulfide nanoparticles: Influencing factors and interactions of metals

doi:10.1016/j.cjche.2020.10.021

Chinese Journal of Chemical Engineering ›› 2021, Vol. 40 ›› Issue (12): 245-255.DOI: 10.1016/j.cjche.2020.10.021

Previous Articles Next Articles

Simultaneous removal of Cr(VI), Cd, and Pb from aqueous solution by iron sulfide nanoparticles: Influencing factors and interactions of metals

Qingrong Zou^1,2, Wanyu Wang³, Tong Zhang^1,2, Yuanyuan Liu^1,2

1. State Key Laboratory of Coal Mine Disaster Dynamics and Control, Chongqing University, Chongqing 400044, China;
2. Key Laboratory of the Three Gorges Reservoir Region’s Eco-Environment of Ministry of Education, Chongqing University, Chongqing 400044, China;
3. Central-Southern Safety & Environment Technology Institute Co., Ltd, Wuhan 430061, China

Received:2020-05-14 Revised:2020-10-23 Online:2022-01-14 Published:2021-12-28
Contact: Yuanyuan Liu,E-mail:Liuyuanyuan@cqu.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (51778084), the National key Research & Development program of China (2018YFC1800305), the Chongqing Ecology and Environment Bureau (2019-128), the Sichuan Science and Technology Program (2019YFSY0005) and the Large Instruments Open Foundation of Chongqing University (201903150051).

Simultaneous removal of Cr(VI), Cd, and Pb from aqueous solution by iron sulfide nanoparticles: Influencing factors and interactions of metals

Qingrong Zou^1,2, Wanyu Wang³, Tong Zhang^1,2, Yuanyuan Liu^1,2

1. State Key Laboratory of Coal Mine Disaster Dynamics and Control, Chongqing University, Chongqing 400044, China;
2. Key Laboratory of the Three Gorges Reservoir Region’s Eco-Environment of Ministry of Education, Chongqing University, Chongqing 400044, China;
3. Central-Southern Safety & Environment Technology Institute Co., Ltd, Wuhan 430061, China

通讯作者: Yuanyuan Liu,E-mail:Liuyuanyuan@cqu.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (51778084), the National key Research & Development program of China (2018YFC1800305), the Chongqing Ecology and Environment Bureau (2019-128), the Sichuan Science and Technology Program (2019YFSY0005) and the Large Instruments Open Foundation of Chongqing University (201903150051).

Abstract

Abstract: Cadmium (Cd), lead (Pb), and hexavalent chromium (Cr(VI)) are often found in soils and water affected by metal smelting, chemical manufacturing, and electroplating. In this study, synthetic iron sulfide nanoparticles (FeS NPs) were stabilized with carboxymethyl cellulose (CMC) and utilized to remove Cr(VI), Cd, and Pb from an aqueous solution. Batch experiments, a Visual MINTEQ model, scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray photoelectron spectrometer (XPS) analysis were used to determine the removal efficiencies, influencing factors, and mechanisms. The FeS NP suspension simultaneously removed Cr(VI), Cd, and Pb from an aqueous solution. The concentrations of Cr(VI), Cd, and Pb decreased from 50, 10, and 50 mg·L^-1 to 2.5, 0.1, and 0.1 mg·L^-1, respectively. The removal capacities were up to 418, 96, and 585 mg per gram of stabilized FeS NPs, respectively. The acidic conditions significantly favored the removal of aqueous Cr(VI) while the alkaline conditions favored the removal of Cd and Pb. Oxygen slightly inhibited the removal of Cr(VI), but it had no significant influence on the removal of Cd and Pb. A potential mechanism was proposed for the simultaneous removal of Cr(VI), Cd, and Pb using FeS NPs. The interactions of the three heavy metals involved a cationic bridging effect on Cr(VI) by Cd, an enhanced adsorption effect on Cd by [Cr,Fe](OH)₃, precipitation of PbCrO₄, and transformation of PbCrO₄ to PbS. Therefore, FeS NPs have a high potential for use in the simultaneous removal of Cr(VI), Cd, and Pb from contaminated aqueous solutions.

Key words: Iron sulfide, Nanoparticles, Multi-heavy metal contamination, Simultaneous removal, Environment, Remediation

摘要： Cadmium (Cd), lead (Pb), and hexavalent chromium (Cr(VI)) are often found in soils and water affected by metal smelting, chemical manufacturing, and electroplating. In this study, synthetic iron sulfide nanoparticles (FeS NPs) were stabilized with carboxymethyl cellulose (CMC) and utilized to remove Cr(VI), Cd, and Pb from an aqueous solution. Batch experiments, a Visual MINTEQ model, scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray photoelectron spectrometer (XPS) analysis were used to determine the removal efficiencies, influencing factors, and mechanisms. The FeS NP suspension simultaneously removed Cr(VI), Cd, and Pb from an aqueous solution. The concentrations of Cr(VI), Cd, and Pb decreased from 50, 10, and 50 mg·L^-1 to 2.5, 0.1, and 0.1 mg·L^-1, respectively. The removal capacities were up to 418, 96, and 585 mg per gram of stabilized FeS NPs, respectively. The acidic conditions significantly favored the removal of aqueous Cr(VI) while the alkaline conditions favored the removal of Cd and Pb. Oxygen slightly inhibited the removal of Cr(VI), but it had no significant influence on the removal of Cd and Pb. A potential mechanism was proposed for the simultaneous removal of Cr(VI), Cd, and Pb using FeS NPs. The interactions of the three heavy metals involved a cationic bridging effect on Cr(VI) by Cd, an enhanced adsorption effect on Cd by [Cr,Fe](OH)₃, precipitation of PbCrO₄, and transformation of PbCrO₄ to PbS. Therefore, FeS NPs have a high potential for use in the simultaneous removal of Cr(VI), Cd, and Pb from contaminated aqueous solutions.

关键词: Iron sulfide, Nanoparticles, Multi-heavy metal contamination, Simultaneous removal, Environment, Remediation

Qingrong Zou, Wanyu Wang, Tong Zhang, Yuanyuan Liu. Simultaneous removal of Cr(VI), Cd, and Pb from aqueous solution by iron sulfide nanoparticles: Influencing factors and interactions of metals[J]. Chinese Journal of Chemical Engineering, 2021, 40(12): 245-255.

References

[1] H. Zhang, L. Peng, A.W. Chen, Chitosan-stabilized FeS magnetic composites for chromium removal: Characterization, performance, mechanism, and stability. Carbohydr. Polym. 214 (2019) 276–285
[2] G. Gong, Y. Xiao, L. Xu, Research on Chemical Form Distribution of Soil Heavy Metals in Typical Industrial Region of Hubei Province. Resour. Environ. Eng. 30 (5) (2016) 701-703
[3] J.H. Li, H.B. Duan, P.X. Shi, Heavy metal contamination of surface soil in electronic waste dismantling area: site investigation and source-apportionment analysis. Waste Manage. Res, 29 (2011) 727-738
[4] Z.T. Li, L. Wang, J. Meng, X.M. Liu, Zeolite-supported nanoscale zero-valent iron: New findings on simultaneous adsorption of Cd(II), Pb(II), and As(III) in aqueous solution and soil. J. Hazard. Mater. 344 (2018) 1-11
[5] M. Manjuladevi, R. Anitha, S. Manonmani, Kinetic study on adsorption of Cr(VI), Ni(II), Cd(II) and Pb(II) ions from aqueous solutions using activated carbon prepared from Cucumis melo peel. Appl. Water Sci. 8 (2018) 36
[6] M. Mahmood-ul-Hassan, V. Suthar, E. Rafique, Kinetics of cadmium, chromium, and lead sorption onto chemically modified sugarcane bagasse and wheat straw. Environ. Monit. Assess. 187 (2015) 470
[7] MABA. Jabar, SKM. Al-Kamal, Determination of heavy elements (Pb, Cd, Cu and Cr) concentration in some water sources. Chem. Chem. Technol. 13 (4) (2019) 471-476
[8] Z. Rahman, V.P. Singh, The relative impact of toxic heavy metals (THMs) (arsenic (As), cadmium (Cd), chromium (Cr)(VI), mercury (Hg), and lead (Pb)) on the total environment: an overview. Environ. Monit. Assess. 191 (2019) 419
[9] I.H. Yoon, S. Bang, J.S. Chang, M.J. Kim, Effects of pH and dissolved oxygen on Cr(VI) removal in Fe(0)/H₂O systems. J. Hazard. Mater. 186 (2011) 855-862
[10] Y. Li, W. Wang, L. Zhou, Y. Liu, Z.A. Mirza, X. Lin, Remediation of hexavalent chromium spiked soil by using synthesized iron sulfide particles. Chemosphere. 169 (2017) 131-138
[11] J.K. Du, J.G. Bao, C.H. Lu, D. Werner, Reductive sequestration of chromate by hierarchical FeS@Fe0 particles. Water Res. 102 (2016) 73-81
[12] G.Y. Huang, X.J. Su, M.S. Rizwan, Chemical immobilization of Pb, Cu, and Cd by phosphate materials and calcium carbonate in contaminated soils. Environ. Sci. Pollut. Res. 23 (2016) 16845–16856
[13] A. Mahar, P. Wang, R.H. Li, Immobilization of Lead and Cadmium in Contaminated Soil Using Amendments: A Review. Pedosphere. 25 (4) (2015) 555–568
[14] M. Komarek, C.M. Koretsky, K.J. Stephen, Competitive Adsorption of Cd(II), Cr(VI), and Pb(II) onto Nanomaghemite: A Spectroscopic and Modeling Approach. Environ. Sci. Technol. 49 (2015) 12851-12859
[15] M.V. Mier, R.L. Callejas, R. Gehr, Heavy metal removal with Mexican Clinoptilolite: multi component ionic exchange. Water Res. 35 (2) (2001) 373–378
[16] D.F. Wang, G.L. Zhang, Z.Y. Dai, Sandwich-like Nanosystem for Simultaneous Removal of Cr(VI) and Cd(II) from Water and Soil. ACS Appl. Mater. Interfaces. 10 (2018) 18316-18326
[17] Z.H. Diao, J.J. Du, D. Jiang, L.J. Kong, Insights into the simultaneous removal of Cr⁶⁺ and Pb²⁺ by a novel sewage sludge-derived biochar immobilized nanoscale zero valent iron: Coexistence effect and mechanism. Sci. Total Environ. 642 (2018) 505-515
[18] G.F. Coelho, A.C. GonCalves, J.C. Novoa-Munoz, Competitive and non-competitive cadmium, copper and lead sorption/desorption on wheat straw affecting sustainability in vineyards. J. Clean. Prod. 139 (2016) 1496-1503
[19] Y. Li, Z.Q. Zhang, F.S hen, Remediation of Cd-Pb polluted water with Fe0. J. China Agr. Univ. 18 (3) (2013) 91-95
[20] A.Z. Ren, Y.B. Gao, Effects of Single and Combinative Pollutions of Lead, Cadmium and Chromium on the Germination of Brassica chinensis L. Chin. J. Ecol. 19 (1) (2000) 19-22
[21] J. Liu, P. Wu, S. Li, Synergistic deep removal of As(III) and Cd(II) by a calcined multifunctional MgZnFe-CO₃ layered double hydroxide: Photo oxidation, precipitation and adsorption. Chemosphere. 225 (2019) 115-125
[22] Y. Gong, J.C. Tang, D.Y. Zhao, Application of iron sulfide particles for groundwater and soil remediation: A review. Water Res. 89 (2016) 309-320
[23] T. Wang, Y. Liu, J. Wang, In-situ remediation of hexavalent chromium contaminated groundwater and saturated soil using stabilized iron sulfide nanoparticles. J. Environ. Manage. 231 (2019) 679-686
[24] M. Erdem, A. Ozverdi, Kinetics and thermodynamics of Cd(II) adsorption onto pyrite and synthetic iron sulphide. Sep. Purif. Technol. 51 (2006) 240-246
[25] Y. Zhao, S.T. Tian, Y. Gong, D.Y. Zhao, Efficient Removal of Lead from Water Using Stabilized Iron Sulfide Nanoparticles: Effectiveness and Effects of Stabilizer. Water Air Soil Pollut. 230 (2019) 115
[26] Y. Liu, W.Y. Xiao, J. Wang, Optimized Synthesis of FeS Nanoparticles with a High Cr(VI) Removal Capability. J. Nanomater. (2016) 1-9
[27] J.P. Gustafsson, Visual MINTEQ Version 2.30: A Computer Program for Speciation, Department of Land and Water Resources Engineering, KTH, Sweden, 2010
[28] A. Ozverdi, M. Erdem, Cu²⁺, Cd²⁺ and Pb²⁺ adsorption from aqueous solutions by pyrite and synthetic iron sulphide. J. Hazard. Mater. B137 (2006) 626-632
[29] X.Y. Jin, Y. Liu, J. Tan, Removal of Cr(VI) from aqueous solutions via reduction and absorption by green synthesized iron nanoparticles. J. Clean. Prod. 176 (2018) 929-936
[30] Y.S. Han, C.M. Lee, C.M. Chon, Enhanced oxidation resistance of NaBH₄-treated mackinawite (FeS): Application to Cr(VI) and As(III) removal. Chem. Eng. J. 353 (2018) 890–899
[31] L. Liang, X.Q. Li, Z. Lin, The removal of Cd by sulfidated nanoscale zero-valent iron: The structural, chemical bonding evolution and the reaction kinetics. Chem. Eng. J. 382 (2020) 122933
[32] Y.L. Liu, Y.D. Huang, C. Zhang, Nano-FeS incorporated into stable lignin hydrogel: A novel strategy for cadmium removal from soil. Environ. Pollut. 264 (2020) 114739
[33] S.T. Tian, Y. Gong, H.D. Jia, Efficient removal and long-term sequestration of cadmium from aqueous solution using ferrous sulfide nanoparticles: Performance, mechanisms, and long-term stability. Sci. Total Environ. 704 (2020) 135402
[34] Y.M. Su, Adeyemi S. Adeleye, Arturo A. Kellerb, Magnetic sulfide-modified nanoscale zerovalent iron (S-nZVI) for dissolved metal ion removal. Water Res. 74 (2015) 47-57
[35] S. Mustafa, D. Misbahud, Y.H. Sammad, M.I. Zaman, K. Sadullah, Sorption Mechanism of Cadmium from Aqueous Solution on Iron Sulphide. Chin. J. Chem. 28 (2010) 1153-1158
[36] Lalhmunsiama, R. Pawar, S.M. Hong, Iron-oxide modified sericite alginate beads: A sustainable adsorbent for the removal of As(V) and Pb(II) from aqueous solutions. J. Mol. Liq. 240 (2017) 497-503
[37] Y. Gong, Y. Liu, Z. Xiong, D. Kaback, D.Y. Zhao, Immobilization of mercury in field soil and sediment using carboxymethyl cellulose stabilized iron sulfide nanoparticles. Nanotechnology. 23 (2012) 294-1007
[38] H.R. Dong, Y.L. Zeng, Y.K. Xie, Single and combined removal of Cr(VI) and Cd(II) by nanoscale zero-valent iron in the absence and presence of EDDS. Water Sci. Technol. 76 (5) (2017) 1261-1271
[39] F. Van Koetsem, L. Van Havere, G. Du Laing, Impact of carboxymethyl cellulose coating on iron sulphide nanoparticles stability, transport, and mobilization potential of trace metals present in soils and sediment. J. Environ. Manage. 168 (2016) 210-218
[40] Q.P. Kong, S. Preis, L. Li, Graphene oxide-terminated hyperbranched amino polymer-carboxymethyl cellulose ternary nanocomposite for efficient removal of heavy metals from aqueous solutions. Int. J. Biol. Macromol. 149 (2020) 581-592
[41] N. Astrini, L. Anah, H.R Haryadi, Adsorption of Heavy Metal Ion from Aqueous Solution by Using Cellulose Based Hydrogel Composite. Macromol. Symp. 353 (2015) 191-197
[42] W. Wei, S. Kim, M.H. Song, Carboxymethyl cellulose fiber as a fast binding and biodegradable adsorbent of heavy metals. J. Taiwan Inst. Chem. E. 57 (2015) 104-110
[43] L. Ying, Y.H. Cao, Q.P. Song, Synthesis of Poly(acrylic acid)-Grafted Carboxymethyl Cellulose for Efficient Removal of Copper Ions. J. Renew. Mater. 7 (2019) 1403-1414
[44] Mohamed E. Mahmoud, Azza E.H. Abdou, Mostafa E. Sobhy, Engineered nano-zirconium oxide-crosslinked-nanolayer of carboxymethyl cellulose for speciation and adsorptive removal of Cr(III) and Cr(VI). Powder Technol. 321 (2017) 444-453
[45] K.C. Zhu, Y. Duan, F. Wang, P. Gao, Silane-modified halloysite/Fe₃O₄ nanocomposites: Simultaneous removal of Cr(VI) and Sb(V) and positive effects of Cr(VI) on Sb(V) adsorption. Chem. Eng. J. 311 (2017) 236-246
[46] D. Borah, K. Senapati, Adsorption of Cd(II) from aqueous solution onto pyrite. Fuel. 85 (2006) 1929-1934
[47] Y. Mu, H. Wu, Z.H. Ai, Negative impact of oxygen molecular activation on Cr(VI) removal with core–shell Fe@Fe₂O₃ nanowires. J. Hazard. Mater. 298 (2015) 1-10
[48] C. Shan, J. Chen, Z. Yang, Enhanced removal of Se(VI) from water via pre-corrosion of zerovalent iron using H₂O₂/HCl: Effect of solution chemistry and mechanism investigation. Water Res. 133 (2018) 173-181
[49] X.S. Lv, Y.J. Hu, J. Tang, Effects of co-existing ions and natural organic matter on removal of chromium(VI) from aqueous solution by nanoscale zero valent iron (nZVI)-Fe₃O₄ nanocomposites. Chem. Eng. J. 218 (2013) 55-64
[50] F. Zhu, L.W. Li, W.T. Ren, Effect of pH, temperature, humic acid and coexisting anions on reduction of Cr(VI) in the soil leachate by nZVI/Ni bimetal material. Environ. Pollut. 227 (2017) 444-450
[51] L.N. Gu, L. Cao, G.Y. Meng, Formation and transition of the phases in the Pb-Cr-O system. J. Alloys Compd. 474 (2009) 297–300
[52] I. Das, R.S. Lall, A. Pushkarna, Multiple stability and pH dependence on periodic precipitation in illuminated lead chromate system. J. Cryst. Growth. 84 (1987) 231-236
[53] R. Vitale, G. Mussoline, K. Rinehimer, Extractio of Sparingly Soluble Cromate from Soils: Evaluation of Methods and Eh-pH Effects. Environ. Sci. Technol. 31 (2) (1997) 390-394
[54] H. Genç-Fuhrman, P.S. Mikkelsen, A. Ledin, Simultaneous removal of As, Cd, Cr, Cu, Ni and Zn from stormwater using high-efficiency industrial sorbents: Effect of pH, contact time and humic acid. Sci. Total Environ. 566–567 (2016) 76–85
[55] H. Gao, P.Y. Wei, H.T. Liu, Sunlight-Mediated Lead and Chromium Release from Commercial Lead Chromate Pigments in Aqueous Phase. Environ. Sci. Technol. 53 (2019) 4931-4939
[56] J. Duan, H.D. Ji, X. Zhao, Immobilization of U(VI) by stabilized iron sulfide nanoparticles: Water chemistry effects, mechanisms, and long-term stability. Chem. Eng. J. 393 (2020) 124692
[57] H.R. Dong, F. Zhao, G.M. Zeng, Aging study on carboxymethyl cellulose-coated zero-valent iron nanoparticles in water: Chemical transformation and structural evolution. J. Hazard. Mater. 312 (2016) 234-242
[58] W.L. Wang, Y. Liu, X.H. Liu, Equilibrium adsorption study of the adsorptive removal of Cd²⁺ and Cr⁶⁺ using activated carbon. Environ. Sci. Pollut. Res. 25 (2018) 25538-25550
[59] H. Peng, J. Guo, B. Li, High-efficient recovery of chromium(VI) with lead sulfate. J. Taiwan Inst. Chem. E. 85 (2018) 149-154
[60] N. Kataria, V.K. Garg, Optimization of Pb(II) and Cd(II) adsorption onto ZnO nanoflowers using central composite design: isotherms and kinetics modelling. J. Mol. Liq. 271 (2018) 228-239
[61] V. Nahuel Montesinos, N. Quici, E. Beatriz Halac, A.G. Leyva, G. Custo, S. Bengio, G. Zampieri, M.I. Litter, Highly efficient removal of Cr(VI) from water with nanoparticulated zerovalent iron: understanding the Fe(III)–Cr(III) passive outer layer structure. Chem. Eng. J. 244 (2014) 569–575

Simultaneous removal of Cr(VI), Cd, and Pb from aqueous solution by iron sulfide nanoparticles: Influencing factors and interactions of metals

Simultaneous removal of Cr(VI), Cd, and Pb from aqueous solution by iron sulfide nanoparticles: Influencing factors and interactions of metals

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles 0

Metrics

Comments

[1]	Wenting Fan, Fang Zhao, Ming Chen, Jian Li, Xuhong Guo. An efficient microreactor with continuous serially connected micromixers for the synthesis of superparamagnetic magnetite nanoparticles [J]. Chinese Journal of Chemical Engineering, 2023, 59(7): 85-91.
[2]	Masoumeh Sheikh Hosseini Lori, Mohammad Delnavaz, Hoda Khoshvaght. Synthesizing and characterizing the magnetic EDTA/chitosan/CeZnO nanocomposite for simultaneous treating of chromium and phenol in an aqueous solution [J]. Chinese Journal of Chemical Engineering, 2023, 58(6): 76-88.
[3]	Yanli Zhang, Zhengkun Hou, Dong Yao, Xiaomin Qiu, Hongru Zhang, Peizhe Cui, Yinglong Wang, Jun Gao, Zhaoyou Zhu, Limei Zhong. Energy, exergy, economic and environmental comprehensive analysis and multi-objective optimization of a sustainable zero liquid discharge integrated process for fixed-bed coal gasification wastewater [J]. Chinese Journal of Chemical Engineering, 2023, 58(6): 341-354.
[4]	Linlin Su, Meijun Chen, Li Gong, Hua Yang, Chao Chen, Jun Wu, Ling Luo, Gang Yang, Lulu Long. Boost activation of peroxymonosulfate by iron doped K_2-xMn₈O₁₆: Mechanism and properties [J]. Chinese Journal of Chemical Engineering, 2023, 57(5): 88-97.
[5]	Jixiang Liu, Xin Zhou, Gengfei Yang, Hui Zhao, Zhibo Zhang, Xiang Feng, Hao Yan, Yibin Liu, Xiaobo Chen, Chaohe Yang. Conceptual carbon-reduction process design and quantitative sustainable assessment for concentrating high purity ethylene from wasted refinery gas [J]. Chinese Journal of Chemical Engineering, 2023, 57(5): 290-308.
[6]	Jingran Liu, Yue Wu, Jie Tang, Tao Wang, Feng Ni, Qiumin Wu, Xijiao Yang, Ayyaz Ahmad, Naveed Ramzan, Yisheng Xu. Polymeric assembled nanoparticles through kinetic stabilization by confined impingement jets dilution mixer for fluorescence switching imaging [J]. Chinese Journal of Chemical Engineering, 2023, 56(4): 89-96.
[7]	Yuhan Zhu, Jia Wei, Jun Li. Decontamination of Cr(VI) from water using sewage sludge-derived biochar: Role of environmentally persistent free radicals [J]. Chinese Journal of Chemical Engineering, 2023, 56(4): 97-103.
[8]	Iltaf Khan, Chunjuan Wang, Shoaib Khan, Jinyin Chen, Aftab Khan, Sayyar Ali Shah, Aihua Yuan, Sohail Khan, Mehwish K. Butt, Humaira Asghar. Bio-capped and green synthesis of ZnO/g-C₃N₄ nanocomposites and its improved antibiotic and photocatalytic activities: An exceptional approach towards environmental remediation [J]. Chinese Journal of Chemical Engineering, 2023, 56(4): 215-224.
[9]	Lianlian Zhao, Fufu Di, Xiaonan Wang, Sumbal Farid, Suzhen Ren. Constructing a hollow core-shell structure of RuO₂ wrapped by hierarchical porous carbon shell with Ru NPs loading for supercapacitor [J]. Chinese Journal of Chemical Engineering, 2023, 55(3): 93-100.
[10]	Xueqing Chen, Weiqun Gao, Yan Sun, Xiaoyan Dong. Multiple effects of polydopamine nanoparticles on Cu²⁺-mediated Alzheimer's β-amyloid aggregation [J]. Chinese Journal of Chemical Engineering, 2023, 54(2): 144-152.
[11]	Lijian Shi, Yaping Zhang, Yujia Tong, Wenlong Ding, Weixing Li. Plant-inspired biomimetic hybrid PVDF membrane co-deposited by tea polyphenols and 3-amino-propyl-triethoxysilane for high-efficiency oil-in-water emulsion separation [J]. Chinese Journal of Chemical Engineering, 2023, 53(1): 170-180.
[12]	Qingming Ma, Jianhong Xu. Green microfluidics in microchemical engineering for carbon neutrality [J]. Chinese Journal of Chemical Engineering, 2023, 53(1): 332-345.
[13]	Baolong Niu, Min Li, Jianhong Jia, Lixuan Ren, Xin Gang, Bin Nie, Yanying Fan, Xiaojie Lian, Wenfeng Li. Preparation and functional study of pH-sensitive amorphous calcium phosphate nanocarriers [J]. Chinese Journal of Chemical Engineering, 2022, 48(8): 244-252.
[14]	Yingmeng Zhang, Luting Liu, Qingwei Deng, Wanlin Wu, Yongliang Li, Xiangzhong Ren, Peixin Zhang, Lingna Sun. Hybrid CuO-Co₃O₄ nanosphere/RGO sandwiched composites as anode materials for lithium-ion batteries [J]. Chinese Journal of Chemical Engineering, 2022, 47(7): 185-192.
[15]	Qilong Ge, Qi Tian, Sufang Wang, Fang Zhu. Synergistic effects of phosphoric acid modified hydrochar and coal gangue-based zeolite on bioavailability and accumulation of cadmium and lead in contaminated soil [J]. Chinese Journal of Chemical Engineering, 2022, 46(6): 150-160.