Modelling-based Optimisation of the Direct Synthesis of Dimethyl Ether from Syngas in a Commercial Slurry Reactor

doi:10.1016/S1004-9541(13)60505-4

摘要/Abstract

摘要： In the present study, we developed a multi-component one-dimensional mathematical model for simulation and optimisation of a commercial catalytic slurry reactor for the direct synthesis of dimethyl ether (DME) from syngas and CO₂, operating in a churn-turbulent regime. DME productivity and CO conversion were optimised by tuning operating conditions, such as superficial gas velocity, catalyst concentration, catalyst mass over molar gas flow rate (W/F), syngas composition, pressure and temperature. Reactor modelling was accomplished utilising mass balance, global kinetic models and heterogeneous hydrodynamics. In the heterogeneous flow regime, gas was distributed into two bubble phases: small and large. Simulation results were validated using data obtained from a pilot plant. The developed model is also applicable for the design of large-scale slurry reactors.

关键词: modelling, slurry bubble column, optimisation, dimethyl ether synthesis, two-bubble phases

Abstract: In the present study, we developed a multi-component one-dimensional mathematical model for simulation and optimisation of a commercial catalytic slurry reactor for the direct synthesis of dimethyl ether (DME) from syngas and CO₂, operating in a churn-turbulent regime. DME productivity and CO conversion were optimised by tuning operating conditions, such as superficial gas velocity, catalyst concentration, catalyst mass over molar gas flow rate (W/F), syngas composition, pressure and temperature. Reactor modelling was accomplished utilising mass balance, global kinetic models and heterogeneous hydrodynamics. In the heterogeneous flow regime, gas was distributed into two bubble phases: small and large. Simulation results were validated using data obtained from a pilot plant. The developed model is also applicable for the design of large-scale slurry reactors.

Key words: modelling, slurry bubble column, optimisation, dimethyl ether synthesis, two-bubble phases

Sadegh Papari, Mohammad Kazemeini, Moslem Fattahi. Modelling-based Optimisation of the Direct Synthesis of Dimethyl Ether from Syngas in a Commercial Slurry Reactor[J]. Chinese Journal of Chemical Engineering, DOI: 10.1016/S1004-9541(13)60505-4.

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