Recovery of Copper Ions from Wastewater by Hollow Fiber Supported Emulsion Liquid Membrane

doi:10.1016/S1004-9541(13)60547-9

Chinese Journal of Chemical Engineering ›› 2013, Vol. 21 ›› Issue (8): 827-834.DOI: 10.1016/S1004-9541(13)60547-9

Recovery of Copper Ions from Wastewater by Hollow Fiber Supported Emulsion Liquid Membrane

郑辉东, 陈晶晶, 王碧玉, 赵素英

College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China

收稿日期:2012-03-07 修回日期:2013-01-26 出版日期:2013-08-28 发布日期:2013-08-24
通讯作者: ZHENG Huidong
基金资助:
Supported by the National Natural Science Foundation of China (20676023).

Recovery of Copper Ions from Wastewater by Hollow Fiber Supported Emulsion Liquid Membrane

ZHENG Huidong, CHEN Jingjing, WANG Biyu, ZHAO Suying

College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China

Received:2012-03-07 Revised:2013-01-26 Online:2013-08-28 Published:2013-08-24
Supported by:
Supported by the National Natural Science Foundation of China (20676023).

摘要/Abstract

摘要： Recovery of copper ions from wastewater using a hollow fiber supported emulsion liquid membrane (HFSELM) was studied with LIX984N as carrier, kerosene as diluents, and sulfuric acid solution as stripping phase. Effects of compositions of feed and emulsion liquid phase, flow rates on both sides of membrane, and hollow fiber module parameters were investigated. The stability of the emulsion liquid phase without surfactant and the effect of buffer in the feed phase on the extraction rate were also evaluated. It is found that the stability of the emulsion phase without surfactant is poor. Higher flow velocity gives shorter residence time for the emulsion liquid phase on the tube side, reducing the effect of particle coalescence on the separation process. The extraction rate increases with the increase of feed phase pH, carrier concentration, hydrogen ion concentration in the stripping phase, and effective hollow fiber area. The phase ratio in the emulsion liquid phase has a negative effect on extraction rate. The flow rates on both sides have little influence on the extraction performance of the HFSELM, while buffer addition in the feed solution improves the extraction efficiency.

关键词: copper ion, supported emulsion liquid membrane, extraction rate, hollow fiber

Abstract: Recovery of copper ions from wastewater using a hollow fiber supported emulsion liquid membrane (HFSELM) was studied with LIX984N as carrier, kerosene as diluents, and sulfuric acid solution as stripping phase. Effects of compositions of feed and emulsion liquid phase, flow rates on both sides of membrane, and hollow fiber module parameters were investigated. The stability of the emulsion liquid phase without surfactant and the effect of buffer in the feed phase on the extraction rate were also evaluated. It is found that the stability of the emulsion phase without surfactant is poor. Higher flow velocity gives shorter residence time for the emulsion liquid phase on the tube side, reducing the effect of particle coalescence on the separation process. The extraction rate increases with the increase of feed phase pH, carrier concentration, hydrogen ion concentration in the stripping phase, and effective hollow fiber area. The phase ratio in the emulsion liquid phase has a negative effect on extraction rate. The flow rates on both sides have little influence on the extraction performance of the HFSELM, while buffer addition in the feed solution improves the extraction efficiency.

Key words: copper ion, supported emulsion liquid membrane, extraction rate, hollow fiber

郑辉东, 陈晶晶, 王碧玉, 赵素英. Recovery of Copper Ions from Wastewater by Hollow Fiber Supported Emulsion Liquid Membrane[J]. Chinese Journal of Chemical Engineering, 2013, 21(8): 827-834.

ZHENG Huidong, CHEN Jingjing, WANG Biyu, ZHAO Suying. Recovery of Copper Ions from Wastewater by Hollow Fiber Supported Emulsion Liquid Membrane[J]. Chin.J.Chem.Eng., 2013, 21(8): 827-834.

参考文献

1 Coelhoso, I.M., Moura, T.F., Crespo, J.P.S.G., Carrondo, M.J.T., "Transport mechanisms in liquid membranes with ion exchange carriers", J. Membr. Sci., 108, 231-244 (1995).

2 Reddy, T.R., Ramkumar, J., Chandramouleeswaran, S., Reddy, A.V.R., "Selective transport of copper across a bulk liquid membrane using 8-hydroxy quinoline as carrier", J. Membr. Sci., 351, 11-15 (2010).

3 Gameiro, M.L.F., Bento, P., Ismael, M.R.C., Reis, M.T.A., Carvalho, J.M., "Extraction of copper from ammoniacal medium by emulsion liquid membranes using LIX 54", J. Membr. Sci., 293, 151-160 (2007).

4 Chiha, M., Hamdaoui, O., Ahmedchekkat, F., Pétrier, C., "Study on ultrasonically assisted emulsification and recovery of copper(II) from wastewater using an emulsion liquid membrane process", Ultrasonics Sonochemistry, 17 (2), 318-325 (2010).

5 Yang, Q., Koeherginsky, N.M., "Copper removal from ammoniacal wastewater through a hollow fiber supported liquid membrane system: Modeling and experimental verification", J. Membr. Sci., 297, 121-129 (2007).

6 Yang, X.J., Fane, A.G., "Performance and stability of supported liquid membranes using LIX 984N for copper transport", J. Membr. Sci., 156, 251-263 (1999).

7 Dantas, T.N.C., Neto, A.A.D., Moura, M.C.P.A., Neto, E.L.B., Forte, K.R., Leite, R.H.L., "Heavy metals extraction by micro emulsions", Water Res., 37 (11), 2709-2717 (2003).

8 Zheng, H.D., Wang, B.Y., Wu, Y.X., Ren, Q.L., "Instability mechanisms of supported liquid membranes for copper (II) ion extraction", Colloids and Surfaces A: Physicochem. Eng. Aspects, 351, 38-45 (2009).

9 Raghuraman, B., Wiencek, J., "Extraction with emulsion liquid membranes in a hollow fiber contactor", AIChE J., 39, 1885-1889 (1993).

10 Wu, X., Yao, B., Fu, X., Yang, Q., "Study on transport of Co(II) by dispersion supported liquid membrane system of PC-88A-Kerosene-HCl", Journal of Xi'an University of Technology, 24 (2), 187-191 (2008).

11 Pei, L., Yao, B., Fu, X., "La(III) transport in dispersion supported liquid membrane including PC-88A as the carrier and HCl solution as the stripping solution", The Chinese Journal of Process Engineering, 8, 1041-1050 (2008).

12 Hu, S.Y.B., Li, J., Wiencek, J.M., "Feasibility of surfactant-free supported emulsion liquid membrane extraction", J. Colloid Int. Sci., 266, 430-437 (2003).

13 Hu, S.Y.B., Wiencek, J.M.. "Emulsion-liquid-membrane extraction of copper using a hollow-fiber contactor", AIChE J., 44 (3), 570-581 (1998).

14 Ho, W.S.W., "Combined supported liquid membrane/strip dispersion process for the removal and recovery of radionuclides and metals", U. S. Pat., 6328782 (2001).

15 Ho, W.S.W., "Combined supported liquid membrane/strip dispersion process for the removal and recovery of penicillin and organic acids", U. S. Pat., 6433163 (2002).

16 Ho, W.S.W., "Combined supported liquid membrane/strip dispersion process for the removal and recovery of metals", U. S. Pat., 6350419 (2002).

17 Zhao, L., Tian, Z., Wang, J., "Study on the developing system of Cu-PAN with OP", Journal of Science of Teachers' College and University, 22 (1), 32-33 (2002).

18 Valenzuela, F., Basualto, C., Tapia, C., Sapag, J., "Application of hollow-fiber supported liquid membranes technique to the selective recovery of a low content of copper from a Chilean mine water", J. Membr. Sci., 155, 163-168 (1999).

19 Zhang, W., Cui, C., Ren, Z., Dai, Y., Meng, H., "Simultaneous removal and recovery of copper(II) from acidic wastewater by hollow fiber renewal liquid membrane with LIX984N as carrier", Chem. Eng. J., 157 (1), 230-237 (2010).

20 Yang, Y., Ren, Z., Liu, J., Wang, H., Hao, Z., Zhang, W., "Transfer study of Cu(II) through hollow fiber renewal liquid membrane with LIX984N as carrier", J. Chem. Ind. Eng., 61 (7), 1777-1782 (2010).

[1]	Zhengchi Yin, Xiaoke Wu, Yanwei Yang, Huayu Zhang, Wangtao Li, Ruimin Zhu, Qiancheng Zheng, Zhengbao Wang. Fabrication of ZIF-8 membranes on dual-layer ZnO-PES/PES organic hollow fibers by in-situ crystallization[J]. 中国化学工程学报, 2023, 55(3): 101-110.
[2]	Zhihao Zhu, Ying Sun, Haijun Yu, Meng Li, Xingming Jie, Guodong Kang, Yiming Cao. Effect of polytetrafluoroethylene hollow fiber microstructure on formaldehyde carbonylation performance in membrane contactor[J]. 中国化学工程学报, 2023, 55(3): 148-155.
[3]	Ting He, Songhong Yu, Jinhui He, Dejian Chen, Jie Li, Hongjun Hu, Xingrui Zhong, Yawei Wang, Zhaohui Wang, Zhaoliang Cui. Membranes for extracorporeal membrane oxygenator (ECMO): History, preparation, modification and mass transfer[J]. 中国化学工程学报, 2022, 49(9): 46-75.
[4]	Guozhen Liu, Yanan Guo, Baochun Meng, Zhenggang Wang, Gongping Liu, Wanqin Jin. Two-dimensional MXene hollow fiber membrane for divalent ions exclusion from water[J]. 中国化学工程学报, 2022, 41(1): 260-266.
[5]	Jian Song, Claudia Li, Shao Zhang, Xiuxia Meng, Bo Meng, Jaka Sunarso. Catalyst-modified perovskite hollow fiber membrane for oxidative coupling of methane[J]. 中国化学工程学报, 2022, 41(1): 412-419.
[6]	M. Ajdar, A. Azdarpour, A. Mansourizadeh, B. Honarvar. Improvement of porous polyvinylidene fluoride-co-hexafluropropylene hollow fiber membranes for sweeping gas membrane distillation of ethylene glycol solution[J]. 中国化学工程学报, 2020, 28(12): 3002-3010.
[7]	A. Yadollahi, M. Torab-Mostaedi, K. Saberyan, A. Charkhi, F. Zahakifar. Intensification of zirconium and hafnium separation through the hollow fiber renewal liquid membrane technique using synergistic mixture of TBP and Cyanex-272 as extractant[J]. 中国化学工程学报, 2019, 27(8): 1817-1827.
[8]	Yanjie Wu, Changfa Xiao, Hailiang Liu, Qinglin Huang. Fabrication and characterization of novel foaming polyurethane hollow fiber membrane[J]. 中国化学工程学报, 2019, 27(4): 935-943.
[9]	Jie Li, Ying Labreche, Naixin Wang, Shulan Ji, Quanfu An. PDMS/ZIF-8 coating polymeric hollow fiber substrate for alcohol permselective pervaporation membranes[J]. 中国化学工程学报, 2019, 27(10): 2376-2382.
[10]	Jiacheng Wang, Peng Ye, Xuechao Gao, Yuting Zhang, Xuehong Gu. Modeling investigation of geometric size effect on pervaporation dehydration through scaled-up hollow fiber NaA zeolite membranes[J]. Chinese Journal of Chemical Engineering, 2018, 26(7): 1477-1484.
[11]	Xiaojuan Jia, Zexian Low, He Chen, Sen Xiong, Yong Wang. Atomic layer deposition of Al₂O₃ on porous polypropylene hollow fibers for enhanced membrane performances[J]. Chinese Journal of Chemical Engineering, 2018, 26(4): 695-700.
[12]	Xuehui Zhao, Yan Hu, Yun Wu, Hongwei Zhang. Effects of pre-oxidant (KMnO₄) on structure and performance of PVDF and PES membranes[J]. Chinese Journal of Chemical Engineering, 2018, 26(12): 2461-2470.
[13]	Xuerui Wang, Ji Jiang, Dezhong Liu, Youquan Xue, Chun Zhang, Xuehong Gu. Evaluation of hollow fiber T-type zeolite membrane modules for ethanol dehydration[J]. , 2017, 25(5): 581-586.
[14]	Eun-Sung Jo, Xinghai An, Pravin G. Ingole, Won-Kil Choi, Yeong-Sung Park, Hyung-Keun Lee. CO₂/CH₄ separation using inside coated thin film composite hollow fiber membranes prepared by interfacial polymerization[J]. , 2017, 25(3): 278-287.
[15]	Ehsan Salehi, Leila Bakhtiari, Mahdi Askari. Extended adsorption transport models for permeation of copper ions through nanocomposite chitosan/polyvinyl alcohol thin affinity membranes[J]. Chinese Journal of Chemical Engineering, 2016, 24(11): 1527-1532.

Recovery of Copper Ions from Wastewater by Hollow Fiber Supported Emulsion Liquid Membrane

Recovery of Copper Ions from Wastewater by Hollow Fiber Supported Emulsion Liquid Membrane

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价