Modeling investigation of geometric size effect on pervaporation dehydration through scaled-up hollow fiber NaA zeolite membranes

doi:10.1016/j.cjche.2018.01.027

Chinese Journal of Chemical Engineering ›› 2018, Vol. 26 ›› Issue (7): 1477-1484.DOI: 10.1016/j.cjche.2018.01.027

• Separation Science and Engineering • 上一篇下一篇

Modeling investigation of geometric size effect on pervaporation dehydration through scaled-up hollow fiber NaA zeolite membranes

Jiacheng Wang, Peng Ye, Xuechao Gao, Yuting Zhang, Xuehong Gu

State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, 5 Xinmofan Road, Nanjing 210009, China

收稿日期:2017-10-22 修回日期:2017-12-24 出版日期:2018-07-28 发布日期:2018-08-16
通讯作者: Xuehong Gu,E-mail address:xhgu@njtech.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China (21490585 and 21776128), the National High-tech R&D Program of China (2015AA03A602), the "Six Top Talents" and "333 Talent Project" of Jiangsu Province, and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

Modeling investigation of geometric size effect on pervaporation dehydration through scaled-up hollow fiber NaA zeolite membranes

Jiacheng Wang, Peng Ye, Xuechao Gao, Yuting Zhang, Xuehong Gu

State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, 5 Xinmofan Road, Nanjing 210009, China

Received:2017-10-22 Revised:2017-12-24 Online:2018-07-28 Published:2018-08-16
Contact: Xuehong Gu,E-mail address:xhgu@njtech.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China (21490585 and 21776128), the National High-tech R&D Program of China (2015AA03A602), the "Six Top Talents" and "333 Talent Project" of Jiangsu Province, and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

摘要/Abstract

摘要： A mass transfer model in consideration of multi-layer resistances through NaA zeolite membrane and lumen pressure drop in the permeate side was developed to describe pervaporation dehydration through scaled-up hollow fiber supported NaA zeolite membrane. It was found that the transfer resistance in the lumen of the permeate side is strongly related with geometric size of hollow fiber zeolite membrane, which could not be neglected. The effect of geometric size on pervaporation dehydration could be more significant under higher vacuum pressure in the permeate side. The transfer resistance in the lumen increases with the hollow fiber length but decreases with lumen diameter. The geometric structure could be optimized in terms of the ratio of lumen diameter to membrane length. A critical value of d_I/L (R_c) to achieve high permeation flux was empirically correlated with extraction pressure in the permeate side. Typically, for a hollow fiber supported NaA zeolite membrane with length of 0.40 m, the lumen diameter should be larger than 2.0 mm under the extraction pressure of 1500 Pa.

关键词: Pervaporation, NaA zeolite membrane, Hollow fiber, Lumen pressure drop, Geometric parameters

Abstract: A mass transfer model in consideration of multi-layer resistances through NaA zeolite membrane and lumen pressure drop in the permeate side was developed to describe pervaporation dehydration through scaled-up hollow fiber supported NaA zeolite membrane. It was found that the transfer resistance in the lumen of the permeate side is strongly related with geometric size of hollow fiber zeolite membrane, which could not be neglected. The effect of geometric size on pervaporation dehydration could be more significant under higher vacuum pressure in the permeate side. The transfer resistance in the lumen increases with the hollow fiber length but decreases with lumen diameter. The geometric structure could be optimized in terms of the ratio of lumen diameter to membrane length. A critical value of d_I/L (R_c) to achieve high permeation flux was empirically correlated with extraction pressure in the permeate side. Typically, for a hollow fiber supported NaA zeolite membrane with length of 0.40 m, the lumen diameter should be larger than 2.0 mm under the extraction pressure of 1500 Pa.

Key words: Pervaporation, NaA zeolite membrane, Hollow fiber, Lumen pressure drop, Geometric parameters

Jiacheng Wang, Peng Ye, Xuechao Gao, Yuting Zhang, Xuehong Gu. Modeling investigation of geometric size effect on pervaporation dehydration through scaled-up hollow fiber NaA zeolite membranes[J]. Chinese Journal of Chemical Engineering, 2018, 26(7): 1477-1484.

参考文献

[1] P.D. Chapman, T. Oliveira, A.G. Livingston, K. Li, Membranes for the dehydration of solvents by pervaporation, J. Membr. Sci. 318(2008) 5-37.

[2] X. Feng, R.Y.-M. Huang, Liquid separation by membrane pervaporation:A review, Ind. Eng. Chem. Res. 36(1997) 1048-1066.

[3] U. Caro, M. Noack, A. Peter, Zeolite membranes:From the laboratory scale to technical applications, Adsorption 11(2005) 215-227.

[4] Y. Morigami, M. Kondo, J. Abe, H. Kita, K. Okamoto, The first large-scale pervaporation plant using tubular-type module with zeolite NaA membrane, Sep. Purif. Technol. 25(2001) 251-260.

[5] J. Gascon, F. Kapteijn, B. Zornoza, V. Sebastian, C. Casado, J. Coronas, Practical approach to zeolitic membranes and coatings:State of the art, opportunities, barriers, and future perspectives, Chem. Mater. 24(2012) 2829-2844.

[6] N. Rangnekar, N. Mittal, B. Elyassi, J. Caro, M. Tsapatsis, Zeolite membranes - A review and comparison with MOFs, Chem. Soc. Rev. 44(2015) 7128-7154.

[7] S. Sommer, B. Klinkhammer, M. Schleger, T. Melin, Performance efficiency of tubular inorganic membrane modules for pervaporation, AIChE J. 51(2005) 162-177.

[8] Z. Wang, Q. Ge, J. Shao, Y. Yan, High performance zeolite LTA pervaporation membranes on ceramic hollow fibers by dipcoating-wiping seed deposition, J. Am. Chem. Soc. 131(2009) 6910-6911.

[9] X. Shu, X. Wang, Q. Kong, X. Gu, N. Xu, High-flux MFI zeolite membrane supported on YSZ hollow fiber for separation of ethanol/water, Ind. Eng. Chem. Res. 51(2012) 12073-12080.

[10] X. Wang, Y. Chen, C. Zhang, X. Gu, N. Xu, Preparation and characterization of highflux T-type zeolite membranes supported on YSZ hollow fibers, J. Membr. Sci. 455(2014) 294-304.

[11] Y. Liu, X. Wang, Y. Zhang, Y. He, X. Gu, Scale-up of NaA zeolite membranes on α-Al₂O₃ hollow fibers by a secondary growth method with vacuum seeding, Chin. J. Chem. Eng. 23(2015) 1114-1122.

[12] D. Liu, Y. Zhang, J. Jiang, X. Wang, C. Zhang, X. Gu, High-performance NaA zeolite membranes supported on four-channel ceramic hollow fibers for ethanol dehydration, RSC Adv. 5(2015) 95866-95871.

[13] F. Peng, F. Pan, D. Li, Z. Jiang, Pervaporation properties of PDMS membranes for removal of benzene from aqueous solution:Experimental and modeling, Chem. Eng. J. 114(2005) 123-129.

[14] S. Chaturabul, W. Srirachat, T. Wannachod, P. Ramakul, U. Pancharoen, S. Kheawhom, Separation of mercury(Ⅱ) from petroleum produced water via hollow fiber supported liquid membrane and mass transfer modeling, Chem. Eng. J. 265(2015) 34-46.

[15] M. Pera-Titus, C. Fite, V. Sebastian, E. Lorente, J. Llorens, F. Cunill, Modeling pervaporation of ethanol/water mixtures within "real" zeolite NaA membranes, Ind. Eng. Chem. Res. 47(2008) 3213-3224.

[16] N. Mittal, P. Bai, A. Kelloway, J.I. Siepmann, P. Daoutidis, M. Tsapatsis, A mathematical model for zeolite membrane module performance and its use for technoeconomic evaluation of improved energy efficiency hybrid membrane-distillation processes for butane isomer separations, J. Membr. Sci. 520(2016) 434-449.

[17] M. Weyd, H. Richter, P. PuhlfürB, I. Voigt, C. Hamel, A. Seidel-Morgenstern, Transport of binary water-ethanol mixtures through a multilayer hydrophobic zeolite membrane, J. Membr. Sci. 307(2008) 239-248.

[18] X. Gao, G. Ji, L. Peng, X. Gu, L. Chen, Pore-neck resistance to light gases in a microporous BTESE-derived silica:A comparison of membrane and xerogel powder, J. Membr. Sci. 531(2017) 36-46.

[19] P. Ye, Y. Zhang, H. Wu, X. Gu, Mass transfer simulation on pervaporation dehydration of ethanol through hollow fiber NaA zeolite membranes, AIChE J. 62(2016) 2468-2478.

[20] X. Li, J. Li, H. Wang, X. Huang, B. He, Y. Yao, J. Wang, H. Zhang, H.H. Ngo, W. Guo, A filtration model for prediction of local flux distribution and optimization of submerged hollow fiber membrane module, AIChE J. 61(2015) 4377-4386.

[21] X. Feng, R.Y.-M. Huang, Permeate pressure build-up in shellside-fed hollow fiber pervaporation membranes, Can. J. Chem. Eng. 73(1995) 833-843.

[22] C. Ronco, A. Brendolan, A. Lupi, G. Metry, N.W. Levin, Effects of a reduced inner diameter of hollow fibers in hemodialyzers, Kidney Int. 58(2000) 809-817.

[23] S.-H. Yoon, S. Lee, I.-T. Yeom, Experimental verification of pressure drop models in hollow fiber membrane, J. Membr. Sci. 310(2008) 7-12.

[24] L. Zhuang, H. Guo, P. Wang, G. Dai, Study on the flux distribution in a dead-end outside-in hollow fiber membrane module, J. Membr. Sci. 495(2015) 372-383.

[25] J.M. Thorman, S.-T. Hwang, Compressible flow in permeable capillaries under deformation, Chem. Eng. Sci. 33(1978) 15-20.

[26] J. Gilron, A. Soffer, Knudsen diffusion in microporous carbon membranes with molecular sieving character, J. Membr. Sci. 209(2002) 339-352.

[27] H. Ohashi, H. Ohya, M. Aihara, T. Takeuchi, Y. Negishi, J. Fan, S.I. Semenova, Analysis of a two-stage membrane reactor integrated with porous membrane having Knudsen diffusion characteristics for the thermal decomposition of hydrogen sulfide, J. Membr. Sci. 166(2000) 239-247.

[28] D.M. Ruthven, W.J. DeSisto, S. Higgins, Diffusion in a mesoporous silica membrane:Validity of the Knudsen diffusion model, Chem. Eng. Sci. 64(2009) 3201-3203.

[29] K. Wu, Z. Chen, X. Li, Real gas transport through nanopores of varying cross-section type and shape in shale gas reservoirs, Chem. Eng. J. 281(2015) 813-825.

[30] P.F. Zito, A. Caravella, A. Brunetti, E. Drioli, G. Barbieri, Knudsen and surface diffusion competing for gas permeation inside silicalite membranes, J. Membr. Sci. 523(2017) 456-469.

[31] J. Kuhn, R. Stemmer, F. Kapteijn, S. Kjelstrup, J. Gross, A non-equilibrium thermodynamics approach to model mass and heat transport for water pervaporation through a zeolite membrane, J. Membr. Sci. 330(2009) 388-398.

[32] S. Guo, C. Yu, X. Gu, W. Jin, J. Zhong, C.-L. Chen, Simulation of adsorption, diffusion, and permeability of water and ethanol in NaA zeolite membranes, J. Membr. Sci. 376(2011) 40-49.

[33] T. Carroll, N.A. Booker, Axial features in the fouling of hollow-fibre membranes, J. Membr. Sci. 168(2000) 203-212.

Modeling investigation of geometric size effect on pervaporation dehydration through scaled-up hollow fiber NaA zeolite membranes

Modeling investigation of geometric size effect on pervaporation dehydration through scaled-up hollow fiber NaA zeolite membranes

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