Effects of ion-exchange on the pervaporation performance and microstructure of NaY zeolite membrane

doi:10.1016/j.cjche.2022.12.006

中国化学工程学报 ›› 2023, Vol. 59 ›› Issue (7): 176-181.DOI: 10.1016/j.cjche.2022.12.006

• Full Length Article • 上一篇下一篇

Effects of ion-exchange on the pervaporation performance and microstructure of NaY zeolite membrane

Meihua Zhu, Xingguo An, Tian Gui, Ting Wu, Yuqin Li, Xiangshu Chen

State-Province Joint Engineering Laboratory of Zeolite Membrane Materials, Institute of Advanced Materials, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China

收稿日期:2022-09-24 修回日期:2022-12-05 出版日期:2023-07-28 发布日期:2023-10-14
通讯作者: Meihua Zhu,E-mail:zhumeihua@jxnu.edu.cn;Xiangshu Chen,E-mail:cxs66cn@jxnu.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (21868012 and 21868013), Jiangxi Provincial Department of Science and Technology (20171BCB24005 and 20181ACH80003).

Effects of ion-exchange on the pervaporation performance and microstructure of NaY zeolite membrane

Meihua Zhu, Xingguo An, Tian Gui, Ting Wu, Yuqin Li, Xiangshu Chen

State-Province Joint Engineering Laboratory of Zeolite Membrane Materials, Institute of Advanced Materials, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China

Received:2022-09-24 Revised:2022-12-05 Online:2023-07-28 Published:2023-10-14
Contact: Meihua Zhu,E-mail:zhumeihua@jxnu.edu.cn;Xiangshu Chen,E-mail:cxs66cn@jxnu.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (21868012 and 21868013), Jiangxi Provincial Department of Science and Technology (20171BCB24005 and 20181ACH80003).

摘要/Abstract

摘要： Pervaporation performance of NaY zeolite membranes is improved by ion-exchange with di-valent nitrate salt. Different nitrate salts, including Co(NO₃)₂, Mg(NO₃)₂, Zn(NO₃)₂, Ca(NO₃)₂, Cu(NO₃)₂, KNO₃, and AgNO₃, have great effects on the channel structure and water affinity of the NaY zeolite membrane. When the concentration of nitrate salt, ion-exchange temperature and time are 0.1 mol·L^-1, 50 ℃ and 2 h, the ion-exchange degree order of NaY zeolites is Ag⁺ > K⁺ > Ca²⁺> Zn²⁺ ≫ Co²⁺ > Mg²⁺. Especially, Ag⁺ and K⁺ cation exchange degree of NaY zeolites are achieved to 96.54% and 82.77% in this work. BET surface, total pore capacity, pore size distribution and water contact angle of the ion-exchanged NaY zeolites are all disordered by mono- and di-valent cations. Di-valent nitrate salt is favor for increasing the dehydration performance of NaY zeolite membranes by ion-exchange. When the ion-exchange solution is Zn(NO₃)₂, the total flux variation and separation factor variation of the NaY membrane (M-5) are -45% and 230% for separation of 10% (mass) H₂O/EtOH mixture by pervaporation, and the ion-exchanged membranes showed good reproducibility.

关键词: NaY zeolite membrane, Ion-exchange, Pervaporation

Abstract: Pervaporation performance of NaY zeolite membranes is improved by ion-exchange with di-valent nitrate salt. Different nitrate salts, including Co(NO₃)₂, Mg(NO₃)₂, Zn(NO₃)₂, Ca(NO₃)₂, Cu(NO₃)₂, KNO₃, and AgNO₃, have great effects on the channel structure and water affinity of the NaY zeolite membrane. When the concentration of nitrate salt, ion-exchange temperature and time are 0.1 mol·L^-1, 50 ℃ and 2 h, the ion-exchange degree order of NaY zeolites is Ag⁺ > K⁺ > Ca²⁺> Zn²⁺ ≫ Co²⁺ > Mg²⁺. Especially, Ag⁺ and K⁺ cation exchange degree of NaY zeolites are achieved to 96.54% and 82.77% in this work. BET surface, total pore capacity, pore size distribution and water contact angle of the ion-exchanged NaY zeolites are all disordered by mono- and di-valent cations. Di-valent nitrate salt is favor for increasing the dehydration performance of NaY zeolite membranes by ion-exchange. When the ion-exchange solution is Zn(NO₃)₂, the total flux variation and separation factor variation of the NaY membrane (M-5) are -45% and 230% for separation of 10% (mass) H₂O/EtOH mixture by pervaporation, and the ion-exchanged membranes showed good reproducibility.

Key words: NaY zeolite membrane, Ion-exchange, Pervaporation

Meihua Zhu, Xingguo An, Tian Gui, Ting Wu, Yuqin Li, Xiangshu Chen. Effects of ion-exchange on the pervaporation performance and microstructure of NaY zeolite membrane[J]. 中国化学工程学报, 2023, 59(7): 176-181.

Meihua Zhu, Xingguo An, Tian Gui, Ting Wu, Yuqin Li, Xiangshu Chen. Effects of ion-exchange on the pervaporation performance and microstructure of NaY zeolite membrane[J]. Chinese Journal of Chemical Engineering, 2023, 59(7): 176-181.

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Effects of ion-exchange on the pervaporation performance and microstructure of NaY zeolite membrane

Effects of ion-exchange on the pervaporation performance and microstructure of NaY zeolite membrane

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