SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2013, Vol. 21 ›› Issue (9): 1048-1056.DOI: 10.1016/S1004-9541(13)60561-3

• 化工热力学 • 上一篇    下一篇

Volumetric and Transport Properties of Aqueous NaB(OH)4 Solutions

周永全1,2, 房春晖1, 房艳1, 朱发岩1,2   

  1. 1 CAS Key Laboratory of Salt lake Resources and Chemistry, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Qinghai 810008, China;
    2 Graduate School of Chinese Academy of Social Sciences, Beijing 100039, China
  • 收稿日期:2012-05-07 修回日期:2012-09-13 出版日期:2013-09-28 发布日期:2013-10-01
  • 通讯作者: FANG Chunhui
  • 基金资助:

    Supported by the National Natural Science Foundation of China (20873172) and Main Direction Program of Knowledge In-novation of Chinese Academy of Sciences (KZCX2-EW-307)

Volumetric and Transport Properties of Aqueous NaB(OH)4 Solutions

ZHOU Yongquan1,2, FANG Chunhui1, FANG Yan1, ZHU Fayan1,2   

  1. 1 CAS Key Laboratory of Salt lake Resources and Chemistry, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Qinghai 810008, China;
    2 Graduate School of Chinese Academy of Social Sciences, Beijing 100039, China
  • Received:2012-05-07 Revised:2012-09-13 Online:2013-09-28 Published:2013-10-01
  • Contact: FANG Chunhui
  • Supported by:

    Supported by the National Natural Science Foundation of China (20873172) and Main Direction Program of Knowledge In-novation of Chinese Academy of Sciences (KZCX2-EW-307)

摘要: Density, pH, viscosity, conductivity and the Raman spectra of aqueous NaB(OH)4 solutions precisely measured as functions of concentration at different temperatures (293.15, 298.15, 303.15, 313.15 and 323.15 K) are presented. Polyborate distributions in aqueous NaB(OH)4 solution were calculated, covering all the concentration range, B(OH)4- is the most dominant species, other polyborate anions are less than 5.0%. The volumetric and the transport properties were discussed in detail, both of these properties indicate that B(OH)4- behaves as a structure-disordered anion.

关键词: aqueous NaB(OH)4 solution, volumetric property, transport property, polyborate distribution

Abstract: Density, pH, viscosity, conductivity and the Raman spectra of aqueous NaB(OH)4 solutions precisely measured as functions of concentration at different temperatures (293.15, 298.15, 303.15, 313.15 and 323.15 K) are presented. Polyborate distributions in aqueous NaB(OH)4 solution were calculated, covering all the concentration range, B(OH)4- is the most dominant species, other polyborate anions are less than 5.0%. The volumetric and the transport properties were discussed in detail, both of these properties indicate that B(OH)4- behaves as a structure-disordered anion.

Key words: aqueous NaB(OH)4 solution, volumetric property, transport property, polyborate distribution