SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2013, Vol. 21 ›› Issue (12): 1370-1375.DOI: 10.1016/S1004-9541(13)60640-0

• 化工热力学 • 上一篇    下一篇

Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution

马征1, 董晓霞1, 胡玉峰2, 张柏松1, 徐长英1, 刘艳升2   

  1. 1 Shandong Province Key laboratory of Plant Nutrition and Fertilizer, Agriculture Resources and Environment Institute, Shandong Academy of Agricultural Science, Jinan 250100, China;
    2 State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China
  • 收稿日期:2012-03-08 修回日期:2012-11-04 出版日期:2013-12-28 发布日期:2013-12-27
  • 通讯作者: LIU Yansheng
  • 基金资助:

    Supported by the National Natural Science Foundation of China (21176248).

Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution

MA Zheng1, DONG Xiaoxia1, Hu Yufeng2, ZHANG Bosong1, XU Changying1, LIU Yansheng2   

  1. 1 Shandong Province Key laboratory of Plant Nutrition and Fertilizer, Agriculture Resources and Environment Institute, Shandong Academy of Agricultural Science, Jinan 250100, China;
    2 State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China
  • Received:2012-03-08 Revised:2012-11-04 Online:2013-12-28 Published:2013-12-27
  • Contact: LIU Yansheng
  • Supported by:

    Supported by the National Natural Science Foundation of China (21176248).

摘要: It is important to know how ILs (ionic liquids) influence organic reaction. In this paper, activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically. Through the study on typical organic reactions happened in ILs, such as Diels-Alder, esterification and Friedel-Crafts reaction, the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions.

关键词: ionic liquid, activity coefficients at infinite dilution, organic reactions

Abstract: It is important to know how ILs (ionic liquids) influence organic reaction. In this paper, activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically. Through the study on typical organic reactions happened in ILs, such as Diels-Alder, esterification and Friedel-Crafts reaction, the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions.

Key words: ionic liquid, activity coefficients at infinite dilution, organic reactions