Mass transfer performance of structured packings in a CO2 absorption tower

doi:10.1016/j.cjche.2014.10.003

Chinese Journal of Chemical Engineering ›› 2015, Vol. 23 ›› Issue (1): 42-49.DOI: 10.1016/j.cjche.2014.10.003

Mass transfer performance of structured packings in a CO₂ absorption tower

Wei Yang^1,2, Xiaodan Yu³, Jianguo Mi², Wanfu Wang³, Jian Chen¹

1 State Key laboratory of Chemical Engineering, Tsinghua University, Beijing 100084, China;
2 State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China;
3 CNPC Research Institute of Safety & Environment Technology, Beijing 102206, China

收稿日期:2013-04-09 修回日期:2013-12-12 出版日期:2015-01-28 发布日期:2015-01-24
通讯作者: Jian Chen
基金资助:
Supported by the National Natural Science Foundation of China (51134017) and PetroChina (2011E-24-09).

Mass transfer performance of structured packings in a CO₂ absorption tower

Wei Yang^1,2, Xiaodan Yu³, Jianguo Mi², Wanfu Wang³, Jian Chen¹

1 State Key laboratory of Chemical Engineering, Tsinghua University, Beijing 100084, China;
2 State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China;
3 CNPC Research Institute of Safety & Environment Technology, Beijing 102206, China

Received:2013-04-09 Revised:2013-12-12 Online:2015-01-28 Published:2015-01-24
Contact: Jian Chen
Supported by:
Supported by the National Natural Science Foundation of China (51134017) and PetroChina (2011E-24-09).

摘要/Abstract

摘要： This paper studies the mass transfer performance of structured packings in the absorption of CO₂ from air with aqueous NaOH solution. The Eight structured packings tested are sheet metal ones with corrugations of different geometry parameters. Effective mass transfer area and overall gas phase mass transfer coefficient have been measured in an absorption column of 200 mm diameter under the conditions of gas F-factor in 0.38-1.52 Pa^0.5 and aqueous NaOH solution concentration of 0.10-0.15 kmol·m^-3. The effects of gas/liquid phase flow rates and packing geometry parameters are also investigated. The results show that the effective mass transfer area changes not only with packing geometry parameters and liquid load, but also with gas F-factor. A new effective mass transfer area correlation on the gas F-factor and the liquid load was proposed, which is found to fit experiment data very well.

关键词: Separation, Absorption, Mass transfer, Packed bed, Structured packing, Carbon dioxide

Abstract: This paper studies the mass transfer performance of structured packings in the absorption of CO₂ from air with aqueous NaOH solution. The Eight structured packings tested are sheet metal ones with corrugations of different geometry parameters. Effective mass transfer area and overall gas phase mass transfer coefficient have been measured in an absorption column of 200 mm diameter under the conditions of gas F-factor in 0.38-1.52 Pa^0.5 and aqueous NaOH solution concentration of 0.10-0.15 kmol·m^-3. The effects of gas/liquid phase flow rates and packing geometry parameters are also investigated. The results show that the effective mass transfer area changes not only with packing geometry parameters and liquid load, but also with gas F-factor. A new effective mass transfer area correlation on the gas F-factor and the liquid load was proposed, which is found to fit experiment data very well.

Key words: Separation, Absorption, Mass transfer, Packed bed, Structured packing, Carbon dioxide

Wei Yang, Xiaodan Yu, Jianguo Mi, Wanfu Wang, Jian Chen. Mass transfer performance of structured packings in a CO₂ absorption tower[J]. Chinese Journal of Chemical Engineering, 2015, 23(1): 42-49.

Wei Yang, Xiaodan Yu, Jianguo Mi, Wanfu Wang, Jian Chen. Mass transfer performance of structured packings in a CO₂ absorption tower[J]. Chin.J.Chem.Eng., 2015, 23(1): 42-49.

参考文献

[1] Intergovernmental Panel on Climate Change (IPCC), 4-th assessments report, Climate Change2007. (www.ipcc.ch).

[2] N.J.Martin, J.L. Rice, Developing renewable energy supply in Queensland, Australia: a study of the barriers, targets, policies and actions, Renew. Energy 44 (2012) 119-127.

[3] D.H.W. Li, Y. Liu, J.C. Lam, Impact of climate change on energy use in the built environment in different climate zones, Energy 42 (2012) 103-112.

[4] G.T. Rochelle, Amine scrubbing for CO₂ capture, Science 325 (2009) 1652-1654.

[5] International Energy Agency (IEA), Greenhouse Gas R&D Programme (GHG). “Impact of impurities on CO₂ capture, transport and storage”, report no. PH4/32, “Improvement in Power Generation With Post-combustion Capture of CO₂”. Report No. PH_4/33, 2004.

[6] W.Y. Fei, N. Ai, J. Chen, Capture and separation of greenhouse gas CO₂—the challenge and opportunity for separation technology, Chem. Ind. Eng. Process. 24 (6) (2005) 1-4 (in Chinese).

[7] R. Lohwasser, R. Madlener, Economics of CCS for coal plants: impact of investment costs and efficiency onmarket diffusion in Europe, Energy Econ. 34 (2012) 850-863.

[8] A. Alabdulkarema, Y. Hwanga, R. Radermachera, Energy consumption reduction in CO₂ capturing and sequestration of an LNG plant through process integration and waste heat utilization, Int. J. Greenh. Gas Control 10 (2012) 215-228.

[9] R. Idem, M. Wilson, P. Tontiwachwuthikul, A. Chakma, A. Veawab, A. Aroonwilas, D. Gelowitz, Pilot plant studies of the CO₂ capture performance of aqueous MEA and mixed MEA/MDEA solvents at the University of Regina CO₂ capture technology development plant and the Boundary Dam CO₂ capture demonstration plant, Ind. Eng. Chem. Res. 45 (2006) 2414-2420.

[10] Z.G. Lei, B.F. Zhang, J.Q. Zhu,W.F. Gong, J.N. Lu, Y.S. Li, Solubility of CO₂ in methanol, 1-octyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, and their mixtures, Chin. J. Chem. Eng. 21 (2013) 310-317.

[11] C.B. Ye, G.W. Chen, Q. Yuan, Process characteristics of CO₂ absorption by aqueous monoethanolamine in amicrochannel reactor, Chin. J. Chem. Eng. 20 (2012) 111-119.

[12] A.-M. Cormos, J. Gaspar, Assessment of mass transfer and hydraulic aspects of CO₂ absorption in packed columns, Int. J. Greenh. Gas Control 6 (2012) 201-209.

[13] J. Gaspar, A.-M. Cormos, Dynamic modeling and absorption capacity assessment of CO₂ capture process, Int. J. Greenh. Gas Control 8 (2012) 45-55.

[14] A. Aroonwilas, P. Tontiwachwuthikul,Mechanisticmodel for prediction of structured packing mass transfer performance in CO₂ absorption with chemical reactions, Chem. Eng. Sci. 55 (2000) 3651-3663.

[15] A. Aroonwilas, P. Tontiwachwuthikul, A. Chakma, Effects of operating and design parameters on CO₂ absorption in columns with structured packings, Sep. Purif. Technol. 24 (2001) 403-411.

[16] P. Alix, L. Raynal, F. Abbe, M. Meyer, M. Prevost, D. Rouzineau, Mass transfer and hydrodynamic characteristics of new carbon packing: Application to CO₂ post-combustion capture, Chem. Eng. Res. Des. 89 (2011) 1658-1668.

[17] J.X. Zhang, L.J. Ji, Hydrodynamics and mass transfer performance of 250 K ripple packing, J. East China Univ. Sci. Technol. 34 (2008) 164-167 (in Chinese).

[18] L.Y. Sun, W.Y. Fei, Q.F. Guo, Study on performance of QH₂1 mini ring packings at high liquid-gas ratio, Chem. Eng. 29 (2001) 7-11 (in Chinese).

[19] S.H. Wu, S.Y. Jia, Y.L. Sun, Y.S. Gu, Y.Q. Gu, Hydrodynamic and mass transfer performance of DN50 plastic abnormity intalox packing, J. Tianjin Univ. 39 (2006) 1184-1188 (in Chinese).

[20] N. Kolev, S. Nakov, L. Ljutzkanov, D. Kolev, Effective area of a highly efficient random packing, Chem. Eng. Process. 45 (2006) 429-436.

[21] A. Aroonwilas, A. Chakma, P. Tontiwachwuthikul, A. Veawab, Mathematical modeling of mass-transfer and hydrodynamics in CO₂ absorbers packed with structured packings, Chem. Eng. Sci. 58 (2003) 4037-4053.

[22] A. Aroonwilas, P. Tontiwachwuthikul, High efficiency structured packing for CO₂ separation using 2-amino-2-methyl-1-propanol (AMP), Sep. Purif. Technol. 12 (1997) 67-69.

[23] P.V. Danckwerts, Gas Liquid Reactions, McGraw Hill Book, 1970. 276.

[24] R. Pohorecki, W. Moniuk, Kinetics of reaction between CO₂ and hydroxyl ions in aqueous electrolyte solutions, Chem. Eng. Sci. 43 (1988) 1677-1681.

[25] M. Henriques de Brito, U. von Stockar, A. Menendez Bangerter, P. Bomio, M. Laso, Effectivemass-transfer area in a pilot plant column equipped with structured packings and with ceramic rings, Ind. Eng. Chem. Res. 33 (647-656) (1994).

[26] I.D. Wilson, Gas-Li quid Contact Area of Random and Structured PackingMS Thesis University of Texas at Austin, USA, 2004.

[27] K. Onda, H. Takeuchi, Y. Okumoto, Mass transfer coefficients between gas and liquid phases in packed columns, J. Chem. Eng. Jpn 1 (1968) 56-60.

[28] Q. Zeng, Y.F. Guo, Z.Q. Liu, W.Y. Lin, Mass transfer performance of CO₂ absorption into aqueous ammonia in a packed column, CIESC. J. 62 (2011) 146-149 (in Chinese).

[29] C.-S. Tan, J.-E. Chen, Absorption of carbon dioxide with piperazine and its mixtures in a rotating packed bed, Sep. Purif. Technol. 49 (2006) 174-180.

Mass transfer performance of structured packings in a CO₂ absorption tower

Mass transfer performance of structured packings in a CO₂ absorption tower

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