Development of a pentaethylenehexamine-modified solid support adsorbent for CO2 capture from model flue gas

doi:10.1016/j.cjche.2014.11.021

›› 2015, Vol. 23 ›› Issue (2): 366-371.DOI: 10.1016/j.cjche.2014.11.021

Development of a pentaethylenehexamine-modified solid support adsorbent for CO₂ capture from model flue gas

Li Wei^1,2, Yu Jing², Zhengming Gao¹, Yundong Wang²

1 School of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China;
2 The State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

收稿日期:2013-06-03 修回日期:2013-10-24 出版日期:2015-02-28 发布日期:2015-03-01
通讯作者: Zhengming Gao, Yundong Wang
基金资助:
Supported by the National Natural Science Foundation of China (20836008, 21176132), and the Special Research Fund for the Doctoral Program of the Ministry of Education of China (20101012174).

Development of a pentaethylenehexamine-modified solid support adsorbent for CO₂ capture from model flue gas

Li Wei^1,2, Yu Jing², Zhengming Gao¹, Yundong Wang²

1 School of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China;
2 The State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Received:2013-06-03 Revised:2013-10-24 Online:2015-02-28 Published:2015-03-01
Supported by:
Supported by the National Natural Science Foundation of China (20836008, 21176132), and the Special Research Fund for the Doctoral Program of the Ministry of Education of China (20101012174).

摘要/Abstract

摘要： A novel solid support adsorbent for CO₂ capture was developed by loading pentaethylenehexamine (PEHA) on commercially available mesoporous molecular sieve MCM-41 using wet impregnation method. MCM-41 samples before and after PEHA loading were characterized by X-ray powder diffraction, N₂ adsorption/desorption, thermal gravimetric analysis and scanning electron microscope to investigate the textural and thermo-physical properties. CO₂ adsorption performance was evaluated in a fixed bed adsorption system. Results indicated that the structure of MCM-41 was preserved after loading PEHA. Surface area and total pore volume of PEHA loaded MCM-41 decreased with the increase of loading. The working adsorption capacity of CO₂ could be significantly improved at 60% of PEHA loading and 75℃. The effect of the height of adsorbent bed was investigated and the best working adsorption capacity for MCM-41-PEHA-60 reached 165 mg·(g adsorbent)^-1 at 75℃. Adsorption/desorption circle showed that the CO₂ working adsorption capacity of MCM-41-PEHA kept stable.

关键词: CO₂ adsorption, Pentaethylenehexamine, MCM-41 molecular sieve, CO₂ adsorbent

Abstract: A novel solid support adsorbent for CO₂ capture was developed by loading pentaethylenehexamine (PEHA) on commercially available mesoporous molecular sieve MCM-41 using wet impregnation method. MCM-41 samples before and after PEHA loading were characterized by X-ray powder diffraction, N₂ adsorption/desorption, thermal gravimetric analysis and scanning electron microscope to investigate the textural and thermo-physical properties. CO₂ adsorption performance was evaluated in a fixed bed adsorption system. Results indicated that the structure of MCM-41 was preserved after loading PEHA. Surface area and total pore volume of PEHA loaded MCM-41 decreased with the increase of loading. The working adsorption capacity of CO₂ could be significantly improved at 60% of PEHA loading and 75℃. The effect of the height of adsorbent bed was investigated and the best working adsorption capacity for MCM-41-PEHA-60 reached 165 mg·(g adsorbent)^-1 at 75℃. Adsorption/desorption circle showed that the CO₂ working adsorption capacity of MCM-41-PEHA kept stable.

Key words: CO₂ adsorption, Pentaethylenehexamine, MCM-41 molecular sieve, CO₂ adsorbent

Li Wei, Yu Jing, Zhengming Gao, Yundong Wang. Development of a pentaethylenehexamine-modified solid support adsorbent for CO₂ capture from model flue gas[J]. , 2015, 23(2): 366-371.

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Development of a pentaethylenehexamine-modified solid support adsorbent for CO₂ capture from model flue gas

Development of a pentaethylenehexamine-modified solid support adsorbent for CO₂ capture from model flue gas

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