Supported ionic liquid sorbents for CO2 capture from simulated flue-gas

doi:10.1016/j.cjche.2018.04.025

Chinese Journal of Chemical Engineering ›› 2018, Vol. 26 ›› Issue (11): 2377-2384.DOI: 10.1016/j.cjche.2018.04.025

• Special issue of Carbon Capture, Utilisation and Storage • 上一篇下一篇

Supported ionic liquid sorbents for CO₂ capture from simulated flue-gas

Jiajia Ren¹, Zheng Li^1,2, Yifeng Chen^1,2, Zhuhong Yang¹, Xiaohua Lu¹

1 State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, China;
2 Energy Engineering, Division of Energy Science, Lulea University of Technology, Lulea 97187, Sweden

收稿日期:2018-02-05 修回日期:2018-04-24 出版日期:2018-11-28 发布日期:2018-12-10
通讯作者: Zhuhong Yang
基金资助:
Supported by the National Basic Research Program of China (2013CB733503), the National Natural Science Foundation of China (21136001, 21136004, 21476106, 21428601, 21776123), the Top-notch Academic Programs Project of Jiangsu Higher Education Institutions (TAPP) and the Jiangsu Natural Science Foundation (BK20130062).

Supported ionic liquid sorbents for CO₂ capture from simulated flue-gas

Jiajia Ren¹, Zheng Li^1,2, Yifeng Chen^1,2, Zhuhong Yang¹, Xiaohua Lu¹

1 State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, China;
2 Energy Engineering, Division of Energy Science, Lulea University of Technology, Lulea 97187, Sweden

Received:2018-02-05 Revised:2018-04-24 Online:2018-11-28 Published:2018-12-10
Contact: Zhuhong Yang
Supported by:
Supported by the National Basic Research Program of China (2013CB733503), the National Natural Science Foundation of China (21136001, 21136004, 21476106, 21428601, 21776123), the Top-notch Academic Programs Project of Jiangsu Higher Education Institutions (TAPP) and the Jiangsu Natural Science Foundation (BK20130062).

摘要/Abstract

摘要： Supported ionic liquid (IL) sorbents for CO₂ capture were prepared by impregnating tetramethylammonium glycinate ([N₁₁₁₁] [Gly]) into four types of porous materials in this study. The CO₂ adsorption behavior was investigated in a thermogravimetric analyzer (TGA). Among them, poly(methyl methacrylate) (PMMA)-[N₁₁₁₁] [Gly] exhibits the best CO₂ adsorption properties in terms of adsorption capacity and rate. The CO₂ adsorption capacity reaches up to 2.14 mmol·g^-1 sorbent at 35℃. The fast CO₂ adsorption rate of PMMA-[N₁₁₁₁] [Gly] allows 60 min of adsorption equilibrium time at 35℃ and much shorter time of 4 min is achieved at 75℃. Further, Avrami's fractional-order kinetic model was used and fitted well with the experiment data, which shows good consistency between experimental results and theoretical model. In addition, PMMA-[N₁₁₁₁] [Gly] remained excellent durability in the continuous adsorption-desorption cycling test. Therefore, this stable PMMA-[N₁₁₁₁] [Gly] sorbent has great potential to be used for fast CO₂ adsorption from flue-gas.

关键词: CO₂ adsorption, Amino acid ionic liquid, Supported ionic liquid sorbent, Adsorption kinetics

Abstract: Supported ionic liquid (IL) sorbents for CO₂ capture were prepared by impregnating tetramethylammonium glycinate ([N₁₁₁₁] [Gly]) into four types of porous materials in this study. The CO₂ adsorption behavior was investigated in a thermogravimetric analyzer (TGA). Among them, poly(methyl methacrylate) (PMMA)-[N₁₁₁₁] [Gly] exhibits the best CO₂ adsorption properties in terms of adsorption capacity and rate. The CO₂ adsorption capacity reaches up to 2.14 mmol·g^-1 sorbent at 35℃. The fast CO₂ adsorption rate of PMMA-[N₁₁₁₁] [Gly] allows 60 min of adsorption equilibrium time at 35℃ and much shorter time of 4 min is achieved at 75℃. Further, Avrami's fractional-order kinetic model was used and fitted well with the experiment data, which shows good consistency between experimental results and theoretical model. In addition, PMMA-[N₁₁₁₁] [Gly] remained excellent durability in the continuous adsorption-desorption cycling test. Therefore, this stable PMMA-[N₁₁₁₁] [Gly] sorbent has great potential to be used for fast CO₂ adsorption from flue-gas.

Key words: CO₂ adsorption, Amino acid ionic liquid, Supported ionic liquid sorbent, Adsorption kinetics

Jiajia Ren, Zheng Li, Yifeng Chen, Zhuhong Yang, Xiaohua Lu. Supported ionic liquid sorbents for CO₂ capture from simulated flue-gas[J]. Chinese Journal of Chemical Engineering, 2018, 26(11): 2377-2384.

Jiajia Ren, Zheng Li, Yifeng Chen, Zhuhong Yang, Xiaohua Lu. Supported ionic liquid sorbents for CO₂ capture from simulated flue-gas[J]. Chin.J.Chem.Eng., 2018, 26(11): 2377-2384.

参考文献

[1] R.S. Haszeldine, Carbon capture and storage:How green can black be? Science 325(2009) 1647-1652.

[2] S. Chu, Carbon capture and sequestration, Science 325(5948) (2009) 1599.

[3] I. Sreedhar, T. Nahar, A. Venugopal, B. Srinivas, Carbon capture by absorption-Path covered and ahead, Renew. Sust. Energ. Rev. 76(2017) 1080-1107.

[4] K.Z. House, C.F. Harvey, M.J. Aziz, D.P. Schrag, The energy penalty of postcombustion CO₂ capture & storage and its implications for retrofitting the U.S. installed base, Energy Environ. Sci. 2(2) (2009) 193-205.

[5] T.J. Simons, T. Verheyen, E.I. Izgorodina, R. Vijayaraghavan, S. Young, A.K. Pearson, S.J. Pas, D.R. MacFarlane, Mechanisms of low temperature capture and regeneration of CO₂ using diamino protic ionic liquids, Phys. Chem. Chem. Phys. 18(2) (2016) 1140-1149.

[6] S.J. Zhang, X.P. Zhang, Y.S. Zhao, G.Y. Zhao, X.Q. Yao, H.W. Yao, A novel ionic liquidsbased scrubbing process for efficient CO₂ capture, Sci. China Chem. 53(7) (2010) 1549-1553.

[7] Z.J. Zhao, H.F. Dong, X.P. Zhang, The research progress of CO₂ capture with ionic liquids, Chin. J. Chem. Eng. 20(1) (2012) 120-129.

[8] E.D. Bates, R.D. Mayton, I. Ntai, J.H. Davis, CO₂ capture by a task-specific ionic liquid, J. Am. Chem. Soc. 124(6) (2002) 926-927.

[9] L.A. Blanchard, D. Hancu, E.J. Beckman, J.F. Brennecke, Green processing using ionic liquids and CO₂, Nature 399(6731) (1999) 28-29.

[10] B.H. Lv, G.H. Jing, Y.H. Qian, Z.M. Zhou, An efficient absorbent of amine-based amino acid-functionalized ionic liquids for CO₂ capture:High capacity and regeneration ability, Chem. Eng. J. 289(2016) 212-218.

[11] Y.Q. Zhang, S.J. Zhang, X.M. Lu, Q. Zhou, W. Fan, X.P. Zhang, Dual aminofunctionalised phosphonium ionic liquids for CO₂ capture, Chem. Eur. J. 15(12) (2009) 3003-3011.

[12] W.L. Xie, X.Y. Ji, X. Feng, X.H. Lu, Mass-transfer rate enhancement for CO₂ separation by ionic liquids:Theoretical study on the mechanism, AIChE J. 61(12) (2015) 4437-4444.

[13] F. Karadas, M. Atilhan, S. Aparicio, Review on the use of ionic liquids (ILs) as alternative fluids for CO₂ capture and natural gas sweetening, Energy Fuel 24(2010) 5817-5828.

[14] W.L. Xie, X.Y. Ji, X. Feng, X.H. Lu, Mass transfer rate enhancement for CO₂ separation by ionic liquids:Effect of film thickness, Ind. Eng. Chem. Res. 55(1) (2016) 366-372.

[15] J.M. Zhang, S.J. Zhang, K. Dong, Y.Q. Zhang, Y.Q. Shen, X.M. Lv, Supported absorption of CO₂ by tetrabutylphosphonium amino acid ionic liquids, Chem. Eur. J. 12(15) (2006) 4021-4026.

[16] X.F. Wang, N.G. Akhmedov, Y.H. Duan, D. Luebke, B.Y. Li, Immobilization of amino acid ionic liquids into nanoporous microspheres as robust sorbents for CO₂ capture, J. Mater. Chem. A 1(9) (2013) 2978-2982.

[17] X.F. Wang, N.G. Akhmedov, Y.H. Duan, D. Luebke, D. Hopkinson, B.Y. Li, Amino acidfunctionalized ionic liquid solid sorbents for post-combustion carbon capture, ACS Appl. Mater. Interfaces 5(17) (2013) 8670-8677.

[18] I.H. Arellano, S.H. Madani, J.H. Huang, P. Pendleton, Carbon dioxide adsorption by zinc-functionalized ionic liquid impregnated into bio-templated mesoporous silica beads, Chem. Eng. J. 283(2016) 692-702.

[19] I.H. Arellano, J.H. Huang, P. Pendleton, Synergistic enhancement of CO₂ uptake in highly ordered mesoporous silica-supported zinc-functionalized ionic liquid sorbents, Chem. Eng. J. 281(2015) 119-125.

[20] J. Ren, L.B. Wu, B.G. Li, Preparation and CO₂ sorption/desorption of N-(3-aminopropyl) aminoethyl tributylphosphonium amino acid salt ionic liquids supported into porous silica particles, Ind. Eng. Chem. Res. 51(23) (2012) 7901-7909.

[21] J. Cheng, Y.N. Li, L.Q. Hu, J.H. Zhou, K.F. Cen, CO₂ adsorption performance of ionic liquid[P₆₆₆₁₄] [2-Op] loaded onto molecular sieve MCM-41 compared to pure ionic liquid in biohythane/pure CO₂ atmospheres, Energy Fuel 30(4) (2016) 3251-3256.

[22] A. Erto, A. Silvestre-Albero, J. Silvestre-Albero, F. Rodriguez-Reinoso, M. Balsamo, A. Lancia, F. Montagnaro, Carbon-supported ionic liquids as innovative adsorbents for CO₂ separation from synthetic flue-gas, J. Colloid Interface Sci. 448(2015) 41-50.

[23] D. Fu, P. Zhang, C.L. Mi, Effects of concentration and viscosity on the absorption of CO₂ in[N₁₁₁₁] [Gly] promoted MDEA (methyldiethanolamine) aqueous solution, Energy 101(2016) 288-295.

[24] D. Fu, J.L. Xie, Absorption capacity and viscosity for CO₂ capture process using[N₁₁₁₁] [Gly] promoted K₂CO₃ aqueous solution, J. Chem. Thermodyn. 102(2016) 310-315.

[25] Y. Gao, F. Zhang, K. Huang, J.W. Ma, Y.T. Wu, Z.B. Zhang, Absorption of CO₂ in amino acid ionic liquid (AAIL) activated MDEA solutions, Int. J. Greenh. Gas Control 19(2013) 379-386.

[26] Y.Y. Jiang, G.N. Wang, Z. Zhou, Y.T. Wu, J. Geng, Z.B. Zhang, Tetraalkylammonium amino acids as functionalized ionic liquids of low viscosity, Chem. Commun. (4) (2008) 505-507.

[27] W.L. Xie, X.Y. Ji, T.T. Fan, X. Feng, X.H. Lu, CO₂ uptake behavior of supported tetraethylenepentamine sorbents, Energy Fuel 30(6) (2016) 5083-5091.

[28] Z.M. Zhang, L.B. Wu, J. Dong, B.G. Li, S.P. Zhu, Preparation and SO₂ sorption/desorption behavior of an ionic liquid supported on porous silica particles, Ind. Eng. Chem. Res. 48(4) (2009) 2142-2148.

[29] R. Mueller, H.K. Kammler, K. Wegner, S.E. Pratsinis, OH surface density of SiO₂ and TiO₂ by thermogravimetric analysis, Langmuir 19(1) (2003) 160-165.

[30] F. Zhang, K.X. Gao, Y.N. Meng, M. Qi, J. Geng, Y.T. Wu, Z.B. Zhang, Intensification of dimethyaminoethoxyethanol on CO₂ absorption in ionic liquid of amino acid, Int. J. Greenh. Gas Control 51(2016) 415-422.

[31] M.Y. Niu, H.M. Yang, X.C. Zhang, Y.T. Wang, A.D. Tang, Amine-impregnated mesoporous silica nanotube as an emerging nanocomposite for CO₂ capture, ACS Appl. Mater. Interfaces 8(27) (2016) 17312-17320.

[32] M.M. Wan, H.Y. Zhu, Y.Y. Li, J. Ma, S. Liu, J.H. Zhu, Novel CO₂-capture derived from the basic ionic liquids orientated on mesoporous materials, ACS Appl. Mater. Interfaces 6(15) (2014) 12947-12955.

[33] S. Lee, S.Y. Moon, H. Kim, J.S. Bae, E. Jeon, H.Y. Ahn, J.W. Park, Carbon dioxide absorption by hydroxyalkyl amidines impregnated into mesoporous silica:The effect of pore morphology and absorbent loading, RSC Adv. 4(4) (2014) 1543-1550.

[34] Y. Liu, J. Liu, W.Y. Yao, W.L. Cen, H.Q. Wang, X.L. Weng, Z.B. Wu, The effects of surface acidity on CO₂ adsorption over amine functionalized protonated titanate nanotubes, RSC Adv. 3(41) (2013) 18803-18810.

[35] G.E. Romanos, P.S. Schulz, M. Bahlmann, P. Wasserscheid, A. Sapalidis, F.K. Katsaros, C.P. Athanasekou, K. Beltsios, N.K. Kanellopoulos, CO₂ capture by novel supported ionic liquid phase systems consisting of silica nanoparticles encapsulating aminefunctionalized ionic liquids, J. Phys. Chem. C 118(42) (2014) 24437-24451.

[36] H. Jung, D.H. Jo, C.H. Lee, W. Chung, D. Shin, S.H. Kim, Carbon dioxide capture using poly(ethylenimine)-impregnated poly(methyl methacrylate)-supported sorbents, Energy Fuel 28(6) (2014) 3994-4001.

[37] N.A.M. Zailani, F.A. Latif, A.M.M. Ali, L.W. Zainuddin, R. Kamaruddin, M.Z.A. Yahya, Effect of ionic liquid incarceration during free radical polymerization of PMMA on its structural and electrical properties, Ionics 23(2) (2017) 295-301.

[38] Z.H. Chen, S.B. Deng, H.R. Wei, B. Wang, J. Huang, G. Yu, Polyethylenimine-impregnated resin for high CO₂ adsorption:An efficient adsorbent for CO₂ capture from simulated flue gas and ambient air, ACS Appl. Mater. Interfaces 5(15) (2013) 6937-6945.

[39] Y.J. Zhou, J.J. Liu, M. Xiao, Y.Z. Meng, L.Y. Sun, Designing supported ionic liquids (ILs) within inorganic nanosheets for CO₂ capture applications, ACS Appl. Mater. Interfaces 8(8) (2016) 5547-5555.

[40] C.F. Xue, H.Y. Zhu, X. Du, X.W. An, E.Y. Wang, D.H. Duan, L.J. Shi, X.G. Hao, B. Xiao, C.J. Peng, Unique allosteric effect-driven rapid adsorption of carbon dioxide in a newly designed ionogel[P₄₄₄₄] [2-Op]@MCM-41 with excellent cyclic stability and loadingdependent capacity, J. Mater. Chem. A 5(14) (2017) 6504-6514.

[41] R. Veneman, Z.S. Li, J.A. Hogendoorn, S.R.A. Kersten, D.W.F. Brilman, Continuous CO₂ capture in a circulating fluidized bed using supported amine sorbents, Chem. Eng. J. 207(2012) 18-26.

[42] M.L. Gray, J.S. Hoffman, D.C. Hreha, D.J. Fauth, S.W. Hedges, K.J. Champagne, H.W. Pennline, Parametric study of solid amine sorbents for the capture of carbon dioxide, Energy Fuel 23(2009) 4840-4844.

[43] X. Wang, L.L. Chen, Q.J. Guo, Development of hybrid amine-functionalized MCM-41 sorbents for CO₂ capture, Chem. Eng. J. 260(2015) 573-581.

[44] Z.Q. Zhang, K. Wang, J.D. Atkinson, X.L. Yan, X. Li, M.J. Rood, Z.F. Yan, Sustainable and hierarchical porous Enteromorpha prolifera based carbon for CO₂ capture, J. Hazard. Mater. 229(2012) 183-191.

[45] A. Samanta, A. Zhao, G.K.H. Shimizu, P. Sarkar, R. Gupta, Post-combustion CO₂ capture using solid sorbents:A review, Ind. Eng. Chem. Res. 51(4) (2012) 1438-1463.

[46] Y.F. Chen, Y.Y. Zhang, S.J. Yuan, X.Y. Ji, C. Liu, Z.H. Yang, X.H. Lu, Thermodynamic study for gas absorption in choline-2-pyrrolidine-carboxylic acid plus polyethylene glycol, J. Chem. Eng. Data 61(10) (2016) 3428-3437.

[47] L.H. Zhang, N. Zhan, Q. Jin, H.L. Liu, J. Hu, Impregnation of polyethylenimine in mesoporous multilamellar silica vesicles for CO₂ capture:A kinetic study, Ind. Eng. Chem. Res. 55(20) (2016) 5885-5891.

[48] R.W. Stevens Jr., R.V. Siriwardane, J. Logan, In situ Fourier transform infrared (FTIR) investigation of CO₂ adsorption onto zeolite materials, Energy Fuel 22(5) (2008) 3070-3079.

[49] X.S. Li, L.Q. Zhang, Y. Zheng, C.G. Zheng, SO₂ absorption performance enhancement by ionic liquid supported on mesoporous molecular sieve, Energy Fuel 29(2) (2015) 942-953.

[50] R.R. Madathingal, S.L. Wunder, Thermal degradation of poly(methyl methacrylate) on SiO₂ nanoparticles as a function of SiO₂ size and silanol density, Thermochim. Acta 526(1-2) (2011) 83-89.

Supported ionic liquid sorbents for CO₂ capture from simulated flue-gas

Supported ionic liquid sorbents for CO₂ capture from simulated flue-gas

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